Direct epoxidation process using a mixed catalyst system
View Patent ↗The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of a catalyst mixture containing a titanium or vanadium zeolite and a supported catalyst comprising palladium, rhenium and a carrier. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.
1. A process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of a titanium or vanadium zeolite and a supported catalyst comprising palladium, rhenium and a carrier, wherein the carrier is not titanium or vanadium zeolite.
2. The process of claim 1 wherein the titanium zeolite is a titanium silicalite.
3. The process of claim 2 wherein the titanium zeolite is TS-1.
4. The process of claim 1 wherein the supported catalyst is comprised of from 0.01 to 10 weight percent palladium.
5. The process of claim 1 wherein the carrier is selected from the group consisting of carbons, titanias, zirconias, niobias, silicas, aluminas, silica-aluminas, tantalum oxides, molybdenum oxides, tungsten oxides, titania-silicas, zirconia-silicas, niobia-silicas, and mixtures thereof.
6. The process of claim 1 wherein the reaction is performed in the presence of a solvent.
7. The process of claim 6 wherein the solvent is an oxygenated solvent.
8. The process of claim 7 wherein the oxygenated solvent is selected from the group consisting of alcohols, ethers, esters, ketones, water, and mixtures thereof.
9. The process of claim 1 wherein the olefin is a C 2 -C 6 olefin.
10. The process of claim 9 wherein the olefin is propylene.
11. The process of claim 6 wherein the reaction is performed in the presence of a buffer.
12. A process for producing propylene oxide comprising reacting propylene, hydrogen and oxygen in an oxygenated solvent in the presence of a titanium silicalite and a supported catalyst comprising palladium, rhenium and a carrier, wherein the carrier is not a titanium or vanadium zeolite.
13. The process of claim 12 wherein the titanium silicalite is TS-1.
14. The process of claim 12 wherein the supported catalyst is comprised of from 0.01 to 10 weight percent palladium.
15. The process of claim 12 wherein the carrier is selected from the group consisting of carbons, titanias, zirconias, niobias, silicas, aluminas, silica-aluminas, tantalum oxides, molybdenum oxides, tungsten oxides, titania-silicas, zirconia-silicas, niobia-silicas, and mixtures thereof.
16. The process of claim 12 wherein the oxygenated solvent is selected from the group consisting of alcohols, ethers, esters, ketones, water, and mixtures thereof.
17. The process of claim 12 wherein the reaction is performed in the presence of a buffer.