Article comprising oxygen permeable layer
View Patent ↗Disclosed are rigid or semi-rigid multilayer structures that provide high oxygen permeability values comprising metallocene polyethylene, ethylene/vinyl acetate copolymers or highly neutralized blends of ethylene acid copolymers, organic acid salts and optionally one or more ethylene-containing polymers or silicon-containing polymers. Such structures have improved oxygen permeability and are useful in packaging food products such as case ready meat, fish, sausage, fresh produce, and the like that require breathable packages.
1. An article comprising a multilayer film or sheet which comprises a structure layer, an oxygen permeable layer, and optionally an additional polymer layer wherein
the article is permeable to oxygen;
the structure layer is a rigid or semi-rigid layer and the oxygen permeable layer comprises or is produced from one or more E/X/Y copolymers or ionomers of the E/X/Y copolymers, one or more organic acids, and optionally one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof;
E is derived from ethylene, X is derived from at least one C 3 to C 8 α, β-ethylenically unsaturated carboxylic acid, and Y is an optional comonomer and is derived from a softening comonomer including alkyl acrylate, alkyl methacrylate, or combinations thereof; the alkyl group has from 1 to 8 carbon atoms;
the organic acid is an aliphatic acid or salt thereof each having fewer than 36 carbon atoms;
the acid moieties in the E/X/Y copolymer and organic acid are nominally neutralized;
the structure layer includes cellulose, cellulose derivative, polymer resin, or combinations of two or more thereof;
the cellulose derivative is in the form of paper, paperboard, cardboard, pulp-molded shape, or combinations of two or more thereof; and
the polymer resin is in the form of an open-cell foam, melt bonded non-woven porous sheet, or combinations of two or more thereof.
2. The article of claim 1 wherein the structure layer is in contact with the oxygen permeable layer and the oxygen permeable layer has an oxygen permeation value greater than 10,000 mil-cc/m 2 -day.
3. The article of claim 2 wherein the oxygen permeable layer further comprises a metallocene-catalyzed polyethylene, an ethylene/vinyl acetate copolymer, ethylene alkyl (meth)acrylate copolymer, or combinations of two or more thereof.
4. The article of claim 2 wherein the article further comprises at least one additional polymer layer including one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof.
5. The article of claim 1 wherein the article comprises at least two oxygen permeable layers in which (1 ) the oxygen permeable layers are on each side of the structure layer, (2 ) at least one of the oxygen permeable layers is part of the structure layer, or both (1 ) and (2 ).
6. The article of claim 4 further comprising the additional polymer layer, which comprises one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof.
7. The article of claim 5 wherein the article further comprises the additional polymer layer, which comprises an ethylene-containing polymer selected from the group consisting of ethylene homopolymers and copolymers; metallocene polyethylene; ethylene propylene copolymers; ethylene/propylene/diene monomer terpolymers; or ethylene copolymers derived from copolymerization of ethylene and at least one comonomer selected from the group consisting of alkyl (meth)acrylate, vinyl acetate, CO, and combinations of two or more thereof.
8. The article of claim 6 wherein the article or the oxygen permeable layer comprises the ethylene-containing polymer including ethylene vinyl acetate copolymer, metallocene polyethylene, an ethylene alkyl (meth)acrylate copolymer, or combinations of two or more thereof.
9. The article of claim 5 wherein the article is a monolithic membrane and the article comprises the silicon-containing polymer selected from the group consisting of ethylene vinyl silane copolymers, polysiloxane, silicone rubber, and combinations of two or more thereof.
10. An article comprising a structure layer, an oxygen permeable layer, and optionally at least one other polymer layer wherein
the structure layer is melt-bonded to the oxygen permeable layer;
the structure layer is a semi-rigid or rigid structure;
the oxygen permeable layer has an oxygen permeation value greater than 10,000 mil-cc/m 2 -day; and
the structure layer comprises a cellulose derivative, polymeric resin, or combinations thereof; cellulose derivative is in the form of paper, paperboard, cardboard, pulp-molded shape, or combinations of two or more thereof; and the polymeric resin is in the form of an open-cell foam, a melt bonded non-woven porous sheet, or combinations of two or more thereof.
11. The article of claim 10 wherein
the article is permeable to CO 2 ;
the permeable layer comprises or is produced from one or more E/X/Y copolymers or ionomers of the E/X/Y copolymers, at least one organic acid , and optionally one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof;
E is derived from ethylene, X is derived from at least one C 3 to C 8 α, β- ethylenically unsaturated carboxylic acid, and Y is an optional comonomer and is derived from a softening comonomer including alkyl acrylate, alkyl methacrylate, or combinations thereof; the alkyl group has from 1 to 8 carbon atoms;
the organic acid is an aliphatic acid or salt thereof each having fewer than 36 carbon atoms;
the acid moieties in the E/X/Y copolymer and organic acid are nominally neutralized;
the structure layer includes cellulose, cellulose derivative, polymer resin, or combinations of two or more thereof.
12. The article of claim 11 wherein the article or the oxygen permeable layer further comprises an ethylene vinyl acetate copolymer, a metallocene polyethylene, an ethylene alkyl (meth)acrylate copolymer, or combinations of two or more thereof.
13. The article of claim 11 wherein the article further comprises at least one additional polymer layer including one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof.
14. The article of claim 13 further comprising the additional polymer layer, which is the ethylene-containing polymer selected from the group consisting of ethylene homopolymers and copolymers; metallocene polyethylene; ethylene propylene copolymers; ethylene/propylene/diene monomer terpolymers; or ethylene copolymers derived from copolymerization of ethylene and at least one comonomer selected from the group consisting of alkyl (meth)acrylate, vinyl acetate, CO, and combinations of two or more thereof.
15. The article of claim 14 wherein the ethylene-containing polymer is an ethylene vinyl acetate copolymer, metallocene polyethylene, an ethylene alkyl (meth)acrylate copolymer, or combinations of two or more thereof.
16. The article of claim 13 wherein the polymer in the additional polymer layer is the silicon-containing polymer including ethylene vinyl silane copolymers, polysiloxane, silicone rubber, or combinations of two or more thereof.
17. A package comprising the article as recited in claim 10 and the package or the article optionally comprises a gas permeable film.
18. The package of claim 17 wherein the gas permeable film comprises or is produced from one or more E/X/Y copolymers or ionomers of the E/X/Y copolymers, one or more organic acids, and optionally one or more ethylene-containing polymers, one or more silicon-containing polymers, or combinations of two or more thereof;
E is derived from ethylene, X is derived from at least one C 3 to C 8 α,β-ethylenically unsaturated carboxylic acid, and Y is an optional comonomer and is derived from a softening comonomer including alkyl acrylate, alkyl methacrylate, or combinations thereof; the alkyl group has from 1 to 8 carbon atoms;
the organic acid is an aliphatic acid or salt thereof each having fewer than 36 carbon atoms;
the acid moieties in the E/X/Y copolymer and organic acid are nominally neutralized;
the structural layer includes cellulose, cellulose derivative, polymer resin, or combinations of two or more thereof.
19. The package of claim 17 wherein the package or the article comprises the gas permeable film comprising or produced from metallocene polyethylene, ethylene vinyl acetate copolymer, ethylene alkyl (meth)acrylate copolymer, or combinations of two or more thereof.
20. The package of claim 17 including a vacuum skin package.
21. The package of claim 17 further comprising one or more food products including a food requiring an oxygen atmosphere or food requiring removal of CO 2 wherein the food requiring an oxygen atmosphere includes case ready meat, fish, or sausage and the food requiring removal of CO 2 includes fresh produce and fruits.