CMC with multiple matrix phases separated by diffusion barrier
View Patent ↗A ceramic matrix composite (CMC) material ( 10 ) with increased interlaminar strength is obtained without a corresponding debit in other mechanical properties. This is achieved by infusing a diffusion barrier layer ( 20 ) into an existing porous matrix CMC to coat the exposed first matrix phase ( 19 ) and fibers ( 12 ), and then densifying the matrix with repeated infiltration cycles of a second matrix phase ( 22 ). The diffusion barrier prevents undesirable sintering between the matrix phases and between the second matrix phase and the fibers during subsequent final firing and use of the resulting component ( 30 ) in a high temperature environment.
1. A ceramic matrix composite material comprising ceramic fibers disposed within a porous ceramic matrix, the porous ceramic matrix comprising a first sinterable bisque fired phase separated from a second sinterable phase by a diffusion barrier material infused into the first sinterable bisque fired phase, the diffusion barrier material being effective to prevent sintering between the first and second sinterable phases, the second sinterable phase being effective to densify the porous ceramic matrix.
2. The material of claim 1 , wherein the diffusion barrier material is further disposed between one of the sinterable phases and the ceramic fibers.
3. The material of claim 1 , wherein each of the first and second sinterable phases comprises alumina and the diffusion barrier material comprising a monazite.
4. The material of claim 1 , wherein the diffusion barrier material comprises lanthanum phosphate.
5. The material of claim 1 , wherein the ceramic matrix comprises a third sinterable phase separated from the second sinterable phase by a second diffusion barrier.
6. A gas turbine component comprising the material of claim 1 .
7. The material of claim 1 , further comprising:
the first sinterable phase comprises particles of mullite interconnected by an alumina binder; and
the diffusion barrier material comprises one of the group of monazites, xenotimes, germinates, tungstates, vanadates, zirconia and hafnates.
8. The material of claim 7 wherein the diffusion barrier material comprises a monazite.
9. A ceramic matrix composite material comprising:
a plurality of oxide fibers disposed in a porous oxide matrix, the porous oxide matrix further comprising:
a first oxide bisque fired phase in contact with the oxide fibers;
a layer of diffusion barrier material disposed over the first oxide bisque fired phase and over the oxide fibers, the diffusion barrier material being infused into the first oxide bisque fired phase; and
a second oxide phase effective to densify the porous oxide matrix;
wherein the layer of diffusion barrier material is effective to limit sintering between the first and second oxide phases.
10. The material of claim 9 , wherein the first oxide phase comprises a porous matrix of dimensionally stable mullite particles, and binder particles comprising alumina, the second oxide phase comprises alumina, and the diffusion barrier material comprises one of the group of monazites, xenotimes, germinates, tungstates, vanadates, zirconia and hafnates.
11. The material of claim 9 , wherein the diffusion barrier material comprises lanthanum phosphate.
12. The material of claim 9 , further comprising a third oxide phase separated from the second oxide phase by a second layer of diffusion barrier.
13. A gas turbine component comprising the material of claim 9 .