IP Library Granted Patent US 7,642,031
Granted Patent B2
US 7,642,031 · App. 11/491,146 · Granted Jan 5, 2010

Electrophotographic toner and electrophotographic developer and image forming method

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Quick Facts
Patent No.
US 7,642,031
App. No.
11/491,146
Granted
Jan 5, 2010
Kind
B2
Abstract

An electrophotographic toner that includes a colorant, a release agent, a non-crystalline resin and a crystalline resin, wherein the crystalline resin is a polyalkyl acrylate or polyalkyl methacrylate having an alkyl group of approximately 18 or more carbon atoms, and is produced by copolymerization with approximately 10 mol % or more, but no more than approximately 50 mol %, of a vinyl monomer having a carboxyl group.

Claims (21)

1. An electrophotographic toner, comprising a colorant, a release agent, a non-crystalline resin and a crystalline resin, wherein

the crystalline resin is a polyalkyl acrylate or polyalkyl methacrylate having an alkyl group of approximately 18 or more carbon atoms, and is produced by copolymerization with approximately 10 mol % or more, but no more than approximately 50 mol %, of a vinyl monomer having a carboxyl group.

2. The electrophotographic toner according to claim 1 , wherein the non-crystalline resin is a resin comprising a styrene-based resin.

3. The electrophotographic toner according to claim 1 , wherein a weight average molecular weight (Mw) of a tetrahydrofuran (THF) soluble fraction of the non-crystalline resin, measured using gel permeation chromatography (GPC), is within a range from approximately 5,000 to 50,000.

4. The electrophotographic toner according to claim 1 , wherein an acid value of the crystalline resin is within a range from approximately 20 to 120 mgKOH/g.

5. The electrophotographic toner according to claim 1 , wherein a weight average molecular weight of the crystalline resin, measured by a molecular weight measurement method, is within a range from approximately 3,000 to 70,000.

6. The electrophotographic toner according to claim 1 , wherein the non-crystalline resin is a polyester-based resin.

7. The electrophotographic toner according to claim 1 , wherein the toner is prepared using an aggregation method.

8. The electrophotographic toner according to claim 1 , wherein the toner comprises a coating layer, and a thickness of the coating layer is approximately 0.05 μm or greater but no more than approximately 0.5 μm.

9. The electrophotographic toner according to claim 1 , wherein the toner comprises a coating layer.

10. The electrophotographic toner according to claim 9 , wherein the coating layer comprises a non-crystalline polyester, and comprises alkyl groups of 6 or more carbon atoms as side chains.

11. The electrophotographic toner according to claim 1 , wherein a ratio between the non-crystalline resin and the crystalline resin is within a range from approximately 60/40 to approximately 95/5.

12. The electrophotographic toner according to claim 1 , wherein a quantity added of the release agent is within a range from approximately 0.5 to 50% by weight relative to a total weight of the toner.

13. An electrophotographic developer, comprising:

an electrophotographic toner, comprising a colorant, a release agent, a non-crystalline resin and a crystalline resin, wherein the crystalline resin is a polyalkyl acrylate or polyalkyl methacrylate having an alkyl group of approximately 18 or more carbon atoms, and is produced by copolymerization with approximately 10 mol % or more, but no more than approximately 50 mol %, of a vinyl monomer having a carboxyl group; and

a carrier.

14. The electrophotographic developer according to claim 13 , wherein a volume average particle size of core particles of the carrier is within a range from approximately 30 to 200 μm.

15. The electrophotographic developer according to claim 13 , wherein the non-crystalline resin within the electrophotographic toner is a resin comprising a styrene-based resin.

16. The electrophotographic developer according to claim 13 , wherein a weight average molecular weight (Mw) of a tetrahydrofuran (THF) soluble fraction of the non-crystalline resin within the electrophotographic toner, measured using gel permeation chromatography (GPC), is within a range from approximately 5,000 to 50,000.

17. The electrophotographic developer according to claim 13 , wherein an acid value of the crystalline resin within the electrophotographic toner is within a range from approximately 20 to 120 mgKOH/g.

18. An electrophotographic developer that uses the electrophotographic developer according to claim 13 .

Assignments (3)
CHANGE OF NAME Recorded Aug 12, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 058287/0056 →
RECORD TO CORRECT ASSIGNEE ADDRESS AND INVENTORSHI Recorded Oct 24, 2006
From: DAIMON, KATSUMI; TSURUMI, YOSUKE; IKEDA, YUSUKE; TANAKA, HIROYUKI; YOSHIDA, SATOSHI; MIZUTANI, NORIYUKI; TAKAGI, SHINPEI; MAEHATA, HIDEO; KITAGAWA, SOICHIRO; TAKAHASHI,MASARU; YOSHINO, SUSUMU
To: FUJI XEROX CO., LTD.
Reel/Frame 018431/0403 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 24, 2006
From: DAIMON, KATSUMI; TSURUMI, YOSUKE; IKEDA, YUSUKE; TANAKA, HIROYUKI; YOSHIDA, SATOSHI; MIZUTANI, NORIYUKI; TAKAGI, SHINPEI; MAEHATA, HIDEO; KITAGAWA, SOICHIRO; YOSHINO, SUSUMU
To: FUJI XEROX CO., LTD.
Reel/Frame 018088/0864 →