Imageable printing plate for on-press development
View Patent ↗A novel coating for lithographic printing plates can be imagewise exposed to radiation and then directly processed with only water to remove the non-exposed regions of the coating. The coating comprises a polymer, a monomer and/or oligomer, polymerization or cross link initiator, stabilizer, and dye or pigment, such that after imaging, the non-imaged resin areas are removable from the planar surface by penetration of water through the non-imaged coating without dissolution of the resin components of the coating, to form a lithographic printing plate with clearly defined image and non-image areas. The stabilizer is a solvent soluble, partially water soluble, non-polymerizable organic component that enables the coating to be removable by water in the non-cross linked areas.
1. An organic composition for photopolymer coating an anodized, hydrophilic substrate to form a radiation imageable lithographic printing plate comprising:
a non-aqueous solution of (a) a polymer selected from the group consisting of acrylates, siloxanes, and styrene maleic anhydrides, and one or both of a monomer that is selected form the group consisting of multifunctional acrylates and an oligomer, capable of radically cross-linking with each other when the coating is exposed to imaging radiation, (b) a non-polymerizable organic compound selected from the group consisting of N,N′-diallyltartardiamide (an allyl amide derived from tartaric acid) and tetra methyl tartaramide, and (c) a water-insoluble initiator capable of generating free radicals sufficient to initiate a polymerization reaction upon exposure to imaging radiation;
wherein the non-polymerizable organic compound is also partially soluble in water such that after imaging of the dried coating as deposited on an anodized, hydrophilic substrate, only the non-imaged coating areas are removable as dislodged material from the substrate surface by penetration of water through the non-imaged coating areas without dissolution of the as-deposited and the cross linked polymer, monomer, and/or oligomer of the coating, to form a lithographic printing plate with clearly defined image areas of cross linked coating and non-image areas of substrate surface.
2. The organic composition of claim 1 , wherein the non-polymerizable organic compound has a measurable solubility in water greater than zero and less than 15%.
3. The organic composition of claim 1 , wherein the wt % ratio of monomer to polymer is in the range of about 1:1 to 5:1.
4. The organic composition of claim 1 , further including a release agent present in the coating at a lower wt % than the non-polymerizable organic compound, and having a higher water solubility than the non-polymerizable organic compound.
5. The organic composition of claim 4 , wherein the release agent is 4-hydroxybenzene sulfonic acid, 4-hydroxy benzoic acid, or sodium benzoate.
6. The organic composition of claim 1 , wherein the polymer is reactive to imaging radiation.
7. The organic composition of claim 1 , wherein the polymer is not reactive to imaging radiation.
8. The organic composition of claim 1 , including a cross-linking initiator selected from triazine or an onium salt.
9. The organic composition of claim 1 , including a plurality of different cross linking agents.
10. The organic composition of claim 9 , wherein one of the cross linking agents is an organo-borate compound.