Photothermographic material
The present invention provides a photothermographic material having, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a first reducing agent for silver ions, and a first binder, and a non-photosensitive outermost layer which is disposed on the same side of the support as the side having thereon the image forming layer, wherein the photothermographic material further has a non-photosensitive intermediate layer A between the image forming layer and the outermost layer, and the non-photosensitive intermediate layer A includes at least a second reducing agent for silver ions and a second binder. A photothermographic material which gives an image with high image quality and has improved film physical properties is provided.
1 . A photothermographic material comprising, on at least one side of a support, an image forming layer comprising at least a photosensitive silver halide, a non-photosensitive organic silver salt, a first reducing agent for silver ions, and a first binder, and a non-photosensitive outermost layer which is disposed on the same side of the support as the side having thereon the image forming layer, wherein the photothermographic material further comprises a non-photosensitive intermediate layer A between the image forming layer and the outermost layer, and the non-photosensitive intermediate layer A comprises at least a second reducing agent for silver ions and a second binder.
2 . The photothermographic material according to claim 1 , wherein a ratio (a/b) is from 0.3 to 3.0, wherein (a) is a mass ratio of an amount of the first reducing agent for silver ions relative to an amount of the first binder, and (b) is a mass ratio of an amount of the second reducing agent for silver ions relative to an amount of the second binder.
3 . The photothermographic material according to claim 1 , wherein the non-photosensitive intermediate layer A is disposed adjacent to the image forming layer.
4 . The photothermographic material according to claim 1 , wherein 50% by weight or more of both the first binder and the second binder is polymer latex.
5 . The photothermographic material according to claim 4 , wherein the first reducing agent for silver ions and the second reducing agent for silver ions are both in the form of a solid dispersion having a mean particle size of 0.1 μm to 5.0 μm.
6 . The photothermographic material according to claim 4 , wherein the polymer latex is a polymer latex in which a monomer component represented by the following formula (M) is copolymerized in an amount of from 10% by weight to 70% by weight:
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 each independently represent one selected from a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.
7 . The photothermographic material according to claim 6 , wherein, in formula (M), both of R 01 and R 02 are a hydrogen atom, or one of R 01 or R 02 is a hydrogen atom and the other is a methyl group.
8 . The photothermographic material according to claim 1 , wherein the photothermographic material further comprises a non-photosensitive intermediate layer B which is disposed between the non-photosensitive intermediate layer A and the outermost layer, and 50% by weight or more of a binder in at least one of the outermost layer and the non-photosensitive intermediate layer B is a hydrophilic polymer derived from animal protein.
9 . The photothermographic material according to claim 8 , wherein 50% by weight or more of the binder in the outermost layer is a hydrophilic polymer derived from animal protein.
10 . The photothermographic material according to claim 8 , wherein 50% by weight or more of the binder in the outermost layer is a hydrophobic polymer, and 50% by weight or more of the binder in the non-photosensitive intermediate layer B is a hydrophilic polymer derived from animal protein.
11 . The photothermographic material according to claim 8 , wherein the non-photosensitive intermediate layer B comprises two or more layers, wherein the non-photosensitive intermediate layer B on the side nearest to the non-photosensitive intermediate layer A comprises a hydrophilic polymer that is not derived from animal protein in an amount of 50% by weight or more, and the non-photosensitive intermediate layer B on the side nearest to the outermost layer comprises a hydrophilic polymer derived from animal protein in an amount of 50% by weight or more.
12 . The photothermographic material according to claim 8 , wherein the hydrophilic polymer derived from animal protein comprises gelatin.
13 . The photothermographic material according to claim 1 , wherein a silver development ratio is 90% or higher.
14 . The photothermographic material according to claim 1 , wherein an amount of coated silver is from 0.5 g/m 2 to 1.2 g/m 2 .