Methods and compositions for determination of fracture geometry in subterranean formations
View Patent ↗Disclosed herein is a method comprising disposing in a formation fracture, a proppant and/or a fracturing fluid that comprises a radiation susceptible material that comprises indium and/or vanadium; irradiating the radiation susceptible material with neutrons; measuring gamma-radiation emitted from the radiation susceptible material in a single pass; wherein the single pass does not involve measuring of background radiation from previous or subsequent logging passes; and determining formation fracture height from the measured gamma-radiation.
1. A method comprising:
a) disposing in a formation fracture a proppant or a fracturing fluid that comprises a radiation susceptible material, wherein the radiation susceptible material comprises a vanadium carbon nitride powder having a particle size of about 1-15 microns, and is non-radioactive until bombarded by neutrons, and during a single logging pass:
b) irradiating the radiation susceptible material with neutrons after it is disposed in the formation fracture;
c) measuring gamma-radiation emitted from the radiation susceptible material to obtain a peak radiation emanating from the radiation susceptible material;
d) measuring a background radiation during the single logging pass, then subtracting the background radiation from the peak energy radiation; and
e) determining formation fracture height from a difference between the background radiation and the peak energy radiation.
2. The method of claim 1 , wherein the radiation susceptible material, after being irradiated, has a half-life of less than or equal to about 100 days.
3. The method of claim 1 , wherein the radiation susceptible material, after being irradiated, has a half-life of about 10 seconds to about 50 minutes.
4. The method of claim 3 further comprising repeating steps b) thru e), after the half-life of the radiation susceptible material has expired, to re-determine the formation fracture height.
5. The method of claim 1 , wherein the proppant comprises a coating that comprises the radiation susceptible material.
6. The method of claim 1 , wherein the proppant comprises a substrate that comprises the radiation susceptible material.
7. The method of claim 1 , wherein the vanadium carbon nitride powder is present in an amount of about 0.01 to 5 wt. % as vanadium metal, based on the total weight of the proppant.
8. The method of claim 1 , wherein the proppant comprises a first proppant containing the radiation susceptible material and a second proppant free of any radiation susceptible material.
9. The method of claim 1 wherein the radiation susceptible material is present in an amount of 0.01 to 5 wt. % based on the total weight of the proppant.
10. The method of claim 9 , wherein the radiation susceptible material, after being irradiated, has a half-life of about 10 seconds to about 50 minutes.
11. A method comprising:
a) disposing in a formation fracture a proppant having a coating that comprises a radiation susceptible material, wherein the radiation susceptible material comprises a vanadium carbon nitride powder having a particle size of about 1-15 microns, and is non-radioactive until bombarded by neutrons, and during a single logging pass:
b) irradiating the radiation susceptible material with neutrons after it is disposed in the formation fracture;
c) measuring gamma-radiation emitted from the radiation susceptible material to obtain a peak radiation emanating from the radiation susceptible material;
d) measuring a background radiation during the single logging pass, then subtracting the background radiation from the peak energy radiation; and
e) determining formation fracture height from a difference between the background radiation and the peak energy radiation.
12. The method of claim 11 wherein the vanadium carbon nitride powder is present in an amount of about 0.01 to 5 wt. % as vanadium metal, based on the total weight of the proppant.
13. A method comprising:
a) disposing in a formation fracture a proppant having a coating that comprises a radiation susceptible material having a half-life of up to about 30 minutes, wherein the radiation susceptible material comprises a vanadium carbon nitride powder having a particle size of about 1-15 microns, present in an amount of about 0.01 to 5 wt. % as vanadium metal, based on the total weight of the proppant, and is non-radioactive until bombarded by neutrons, and during a single logging pass:
b) irradiating the radiation susceptible material with neutrons after it is disposed in the formation fracture;
c) measuring gamma-radiation emitted from the radiation susceptible material to obtain a peak radiation emanating from the radiation susceptible material;
d) measuring a background radiation during the single logging pass, then subtracting the background radiation from the peak energy radiation; and
e) determining formation fracture height from a difference between the background radiation and the peak energy radiation.
14. The method of claim 13 further comprising repeating steps b) thru e), after the half-life of the radiation susceptible material has expired, to re-determine the formation fracture height.