Crystallized pellet/liquid separator
View Patent ↗A process and apparatus which reduces the fines in a liquid discharge stream and/or increases the dryness of a solids discharge stream while under a pressure equal to or greater than the vapor pressure of the liquid. There is provided a process for separating particles such as polyethylene terephthalate or polyethylene naphthalate from a liquid in a slurry comprising feeding a slurry comprising solid particles and a liquid into a separation zone maintained at a pressure equal to or greater than the vapor pressure of the liquid; contacting the slurry in the separation zone with a porous filter; and separating liquid from the particles, wherein the liquid flows through the filter into an outer annulus defined as a space between a wall of the separation device and the filter, said porous filter having a terminal point beyond which the separated liquid does not pass from the outer annulus back through the filter; accumulating no liquid in the outer annulus or accumulating liquid in the outer annulus at a level below the terminal point, and continuously discharging the separated liquid form the outer annulus through a liquid outlet; and decoupling the particles from the separation zone through an outlet at a low pressure below the vapor pressure of the liquid at the liquid temperature within the separation zone, while maintaining a pressure on the particles prior to decoupling at or above the vapor pressure of the liquid within the separation zone.
1. A process for separating particles from a liquid in a slurry comprising:
a. feeding a slurry comprising solid particles and a liquid to an inlet of a separation device maintained at a pressure equal to or greater than the vapor pressure of the liquid, wherein the particles have a number average particle size having a smallest dimension in the range of 0.1 mm to 24 mm, and wherein the separation device contains a porous filter dividing the separation device into an outer annulus defined as a space between the wall of the separation device and the porous filter and an inner annulus defined as a space within the porous filter, and wherein the slurry falls through the inner annulus;
b. contacting the slurry in the separation device with the porous filter and separating the liquid from the particles, wherein a portion of the liquid flows through the porous filter into the outer annulus, and wherein the porous filter has a terminal point beyond which the separated liquid does not pass from the outer annulus back through the porous filter to the inner annulus;
c. accumulating none of the separated liquid in the outer annulus or accumulating the separated liquid in the outer annulus at a level below the terminal point, and continuously discharging the separated liquid from the outer annulus through a liquid outlet; and
d. decoupling the particles from the separation device through a solids outlet using a decoupling device to a low pressure below the vapor pressure of the liquid at the liquid temperature within the separation device while maintaining a pressure on the particles prior to the decoupling at or above the vapor pressure of the liquid within the separation device, wherein the particles form a particle bed in the inner annulus and the solid volume of the particle bed feeding the decoupling device is at least 97%.
2. The process of claim 1 , wherein the particles are spheroidal in shape.
3. The process of claim 1 , wherein the number average particle size has the smallest dimension ranging from 1 mm to 10 mm.
4. The process of claim 1 , wherein the volume percent of the particles in the slurry ranges from 5 vol. % to 60 vol. %.
5. The process of claim 1 , wherein the liquid comprises water in an amount of at least 50 wt. % based on the weight of the liquid.
6. The process of claim 1 , wherein the particles comprise polyester polymer particles partially crystallized to a degree of crystallinity of at least 30%.
7. The process of claim 6 , wherein the liquid comprises water, and the particles are obtained by cutting a polyester polymer melt underwater and feeding the resulting slurry directly or indirectly to the separation device.
8. The process of claim 1 , wherein the particles comprise polyester polymers containing alkylene terephthalate or alkylene naphthalate units.
9. The process of claim 8 , wherein the particles have an It.V. of at least 0.7 dL/g.
10. The process of claim 9 , wherein the particles are not solid state polymerized.
11. The process of claim 1 , wherein the liquid temperature is at or exceeds the normal boiling point of the liquid at 1 atm.
12. The process of claim 11 , wherein the liquid temperature exceeds 100° C.
13. The process of claim 1 , wherein the pressure within the separation device is greater than 14.7 psia and less than 500 psia.
14. The process of claim 1 , wherein the shape of the outer annulus is in the form of a cylinder.
15. The process of claim 1 , wherein the porous filter is configured with V wedges.
16. The process of claim 1 , wherein a particle flow vector of the particles flowing through the inner annulus is at an angle greater than 45° to a flow vector of the liquid flowing through the porous filter.
17. The process of claim 1 , wherein the particles are continuously discharged through the solids outlet.
18. The process of claim 17 , wherein the particle bed height is at a constant value.
19. The process of claim 17 , wherein the particle bed height is 30% to 60% of the separation device height.
20. The process of claim 1 , wherein at least 95 vol. % of the liquid in the slurry fed to the separation device is discharged through the liquid outlet.
21. The process of claim 1 , wherein less than 20% of the outer annulus volume is filled with the separated liquid.
22. The process of claim 1 , wherein the decoupling device comprises one or more rotary air lock valves, ball valves, knife gate valves, cup valves, or butterfly valves.
23. The process of claim 1 , wherein the decoupling device is located in an enclosed inner annulus, wherein the liquid does not flow from the outer annulus.
24. The process of claim 1 , wherein the liquid volume of the particle bed feeding the decoupling device is 0.5 volume % or less.
25. The process of claim 1 , wherein the porous filter comprises pores and the slurry is fed through the inlet in a direction parallel to the pores.
26. The process of claim 1 , wherein the particles comprise polymers containing ethylene terephthalate units.
27. The process of claim 26 , wherein the It.V. of the particles prior to the decoupling is at least 0.70 dL/g without advancing the particle molecular weight in the solid state.
28. A separation device comprising:
a. an inlet for continuously receiving a feed of slurry comprising solid particles and a liquid;
b. a porous filter disposed within the separation device to form an outer annulus receiving a portion of the liquid separated from the particles, the outer annulus defined as a space between the wall of the separation device and the porous filter and an inner annulus defined as a space within the porous filter, the porous filter having a terminal point beyond which the separated liquid does not pass from the outer annulus back through the porous filter to the inner annulus;
c. a liquid outlet located on the separation device for discharging at least a portion of the separated liquid from the outer annulus, wherein the terminal point is located above the liquid outlet;
d. a solids outlet for discharging the particles, and
e. a decoupling device sealed to the solids outlet through which the particles are discharged and under which a pressurized environment within the separation device is maintained at or above the vapor pressure of the liquid.
29. The device of claim 28 , wherein the porous filter is cylindrical.
30. The device of claim 28 , wherein the porous filter is oriented such that a particle flow through the inlet will have a particle flow vector at an angle greater than 45° to a flow vector of the liquid through the porous filter.
31. The device of claim 28 , wherein the decoupling device comprises rotary air lock valves, ball valves, knife gate valves, cup valves, or butterfly valves.
32. The device of claim 28 , wherein the decoupling device is located in an enclosed inner annulus into which the liquid does not flow from the outer annulus.
33. The device of claim 28 , wherein the inlet is on the side of the separation device.
34. A separation device comprising:
a. an inlet for continuously receiving a feed of slurry comprising solid particles and a liquid;
b. a porous cross-flow filter comprising a microfilter, nanofilter, ultrafilter, or reverse osmosis filter, wherein the cross-flow filter comprises pore openings having an average pore size, disposed within the separation device to form an outer annulus, defined as a space between the wall of the separation device and the cross-flow filter to receive the liquid separated from the particles, and an inner annulus, defined as a space within the cross-flow filter, the inlet and the cross-flow filter oriented such that the particles entering the separation device through the inlet flow tangentially to the pore openings of at least a portion of the cross-flow filter, wherein the average pore size is smaller than a number average solid particle size of the particles in its smallest dimension, and wherein the cross-flow filter has a terminal point beyond which the separated liquid does not pass from the outer annulus back through the cross-flow filter to the inner annulus;
c. a liquid outlet located on the separation device for discharging at least a portion of the separated liquid from the outer annulus;
d. a solids outlet for discharging the particles, and
e. a decoupling device through which the particles are discharged synchronous to the motion of the gate, the decoupling device providing a seal to maintain a pressurized environment within the separation device above the vapor pressure of the liquid.
35. The device of claim 34 , wherein the cross-flow filter contains a thin film polymeric membrane filter media, ceramic filter media, hollow fiber media, or sintered metal filter media.
36. The device of claim 34 , wherein the cross-flow filter is cylindrical.
37. The device of claim 34 , wherein the cross-flow filter is oriented such that the particles flow through the inlet having a particle flow vector at an angle greater than 45° to a flow vector of the liquid through the cross-flow filter.
38. The device of claim 34 , wherein the decoupling device comprises rotary air lock valves, ball valves, knife gate valves, cup valves, or butterfly valves.
39. The device of claim 34 , wherein the decoupling device is located in an enclosed inner annulus into which the liquid does not flow from the outer annulus.
40. The device of claim 34 , wherein the inlet is on the side of the separation device.
41. The device of claim 34 , wherein the average pore size is 1 micron or less.
42. A process for separating particles from a liquid comprising:
a. feeding a slurry, comprising solid particles and a liquid, at a liquid temperature at or above the normal boiling point of the liquid and under a pressure of greater than the vapor pressure of the liquid through an inlet of a separation device into the separation device maintained at a pressure greater than the vapor pressure of the liquid, wherein the particles have a number average particle size having a smallest dimension in the range of 0.1 mm to 24 mm, and wherein the separation device contains a cross-flow filter dividing the separation device into an outer annulus defined as a space between the wall of the separation device and the cross-flow filter and an inner annulus defined as a space within the cross-flow filter, and wherein the slurry falls through the inner annulus;
b. contacting the slurry against the cross-flow filter comprising a microfilter, nanofilter, ultrafilter, or reverse osmosis filter, disposed within the separation device to separate the liquid from the solid particles, wherein the solid particles move in a direction tangential to the flow of the liquid across the cross-flow filter, wherein the separated liquid flows into the outer annulus, the cross-flow filter having a pore size which is smaller than the number average solid particle size in its smallest dimension, and wherein the cross-flow filter has a terminal point beyond which the separated liquid does not pass from the outer annulus back through the cross-flow filter to the inner annulus;
c. discharging the separated liquid from the outer annulus through a liquid outlet;
d. discharging the solid particles from the separation device using a decoupling device while maintaining a pressurized environment within the separation device, and wherein the particles form a particle bed in the inner annulus and the solid volume of the particle bed feeding the decoupling device is at least 97%.
43. The process of claim 42 , wherein the particles are spheroidal in shape.
44. The process of claim 42 , wherein the number average particle size has the smallest dimension ranging from 1 mm to 10 mm, the volume percent of solids in the slurry ranges from 5 vol. % to 60 vol. %, the liquid comprises water in an amount of at least 50 wt. % based on the weight of the liquid, and the solid particles fed to the separation device comprise thermoplastic polymers.
45. The process of claim 42 , wherein the solid particles comprise polyester polymers.
46. The process of claim 42 , wherein the solid particles comprise polyester polymers containing alkylene terephthalate or alkylene naphthalate units.
47. The process of claim 42 , wherein the solid particles have an It.V. of at least 0.7 dL/g.
48. The process of claim 42 , wherein the molecular weight of the solid particles is not advanced in the solid state prior to the discharging of the solid particles.
49. The process of claim 42 , wherein the liquid temperature exceeds 100° C.
50. The process of claim 42 , wherein the pressure within the separation device is 50 psia or more.
51. The process of claim 42 , wherein the shape of the outer annulus is in the form of a cylinder.
52. The process of claim 42 , wherein a flow vector of the solid particles is at an angle greater than 45° to a flow vector of the liquid through the cross-flow filter.
53. The process of claim 42 , wherein the solid particles are continuously discharged through the decoupling device.
54. The process of claim 42 , wherein at least 95 vol. % of the liquid fed to the separation device is discharged through the liquid outlet.
55. The process of claim 42 , wherein less than 20% of the outer annulus volume is filled with the separated liquid.
56. The process of claim 42 , wherein the decoupling device comprises-a rotary air lock valves, ball valves, knife gate valves, cup valves, or butterfly valves.
57. The process of claim 42 , wherein the solid particles comprise polyester polymer particles partially crystallized to a degree of crystallinity of at least 30%.
58. The process of claim 57 , wherein the liquid comprises water, and the solid particles are obtained by cutting a polyester polymer melt underwater to produce the slurry, wherein the slurry is fed directly or indirectly to the separation device.