Process for producing metal-containing particles having their surface coated with at least two dispersants different in vaporization temperature
View Patent ↗To provide metal-containing fine particles having good dispersion stability, which have their surface coated with dispersants vaporizable even during firing at low temperatures, a fine particle dispersion having the above metal-containing fine particles dispersed therein, and an electroconductive metal-containing material having an excellent volume resistivity formed by using the fine particle dispersion. Metal-containing fine particles with their surface coated with at least two dispersants having different vaporization temperatures.
1. A process for producing an electroconductive metal-containing material, the process comprising
a step of adding water to a water-soluble metal-containing compound to obtain an aqueous solution containing metal ions;
a step of adding to the aqueous solution a water-insoluble organic liquid having at least two dispersants different in vaporization temperature dissolved therein;
then a step of adding to the aqueous solution a reducing agent with stirring to reduce the metal ions, produce metal-containing particles having their surface coated with the at least two dispersants different in vaporization temperature, and produce a particle dispersion by dispersing in the water-insoluble organic liquid the metal-containing particles having their surface coated with the at least two dispersants different in vaporization temperature;
separating the particle dispersion from the aqueous solution;
coating an object with a coating containing particles from the particle dispersion;
firing the coating at a temperature between the highest vaporization temperature and the lowest vaporization temperature among the vaporization temperatures of the at least two dispersants to produce an electroductive metal-containing material having a volume resistivity of at most 60 μΩcm.
2. A process for producing an electroconductive metal-containing material, the process comprising
a step of obtaining an aqueous solution containing citric ions and ferric ions;
a step of addition to the aqueous solution containing citric ions and ferric ions an aqueous solution containing ions of at least one metal selected from the group consisting of gold, silver, platinum, palladium, tungsten, tantalum, bismuth, lead, indium, tin, titanium and aluminum, with stirring, to reduce the ions of at least one metal to obtain a liquid containing metal-containing particles;
a step of adding to the liquid containing the metal-containing particles a water-insoluble organic liquid having at least two dispersants different in vaporization temperature dissolved therein, with stirring, to produce metal-containing particles having their surface coated with the at least two dispersants different in vaporization temperature, and produce a particle dispersion by dispersing in the water-insoluble organic liquid the metal-containing particles having their surface coated with the at least two dispersants different in vaporization temperature;
separating the particle dispersion from the aqueous solution;
coating an object with a coating containing particles from the particle dispersion; and
firing the coating at a temperature between the highest vaporization temperature and the lowest vaporization temperature among the vaporization temperatures of the at least two dispersants to produce an electroductive metal-containing material having a volume resistivity of at most 60 μΩcm.
3. The process according to claim 1 , wherein the at least two dispersants are independently selected from the group consisting of organic compounds containing, as a substituent which can be coordinated to a metal element, at least one nitrogen atom, oxygen atom or sulfur atom.
4. The process according to claim 2 , wherein the at least two dispersants are independently selected from the group consisting of organic compounds containing, as a substituent which can be coordinated to a metal element, at least one nitrogen atom, oxygen atom or sulfur atom.
5. The process according to claim 1 , wherein the at least two dispersants independently contain from 4 to 25 carbon atoms.
6. The process according to claim 2 , wherein the at least two dispersants independently contain from 4 to 25 carbon atoms.
7. The process according to claim 1 , wherein the firing is at a temperature that is different than the vaporization temperature of each of the at least two dispersants by no more than 25° C.
8. The process according to claim 2 , wherein the firing is at a temperature that is different than the vaporization temperature of each of the at least two dispersants by no more than 25° C.