Method for preparing electroconductive mayenite type compound
View Patent ↗To provide a method for preparing a mayenite type compound having electroconductivity imparted. A method for preparing an electroconductive mayenite type compound, which comprises melting a raw material containing Al and at least one element selected from the group consisting of Ca and Sr, holding the melt in a low oxygen partial pressure atmosphere having an oxygen partial pressure of not higher than 10 Pa, followed by cooling or annealing in a low oxygen partial pressure atmosphere or in atmospheric air for solidification, thereby to replace oxygen present in cages by electrons in a high concentration.
1. A method for preparing an electroconductive mayenite type compound, comprising:
melting a raw material containing Al and at least one element selected from the group consisting of Ca and Sr;
holding the melt in a low oxygen partial pressure atmosphere; and
cooling for solidification; wherein
an oxygen partial pressure of the low oxygen partial pressure atmosphere is not higher than 10 Pa, and
a direct current conductivity of the electroconductive mayenite type compound is at least 10 −4 S/cm.
2. The method for preparing an electroconductive mayenite type compound according to claim 1 , wherein the cooling for solidification is in a low oxygen partial pressure atmosphere.
3. The method for preparing an electroconductive mayenite type compound according to claim 1 , wherein the cooling for solidification is in atmospheric air.
4. The method for preparing an electroconductive mayenite type compound according to claim 1 , wherein the cooling for solidification is annealing.
5. The method for preparing an electroconductive mayenite type compound according to claim 4 , wherein a cooling rate of annealing is at least 200° C./hr and at most 500° C./hr.
6. The method for preparing an electroconductive mayenite type compound according to claim 1 , wherein prior to the cooling for solidification the melt is discharged from a crucible.
7. The method for preparing an electroconductive mayenite type compound according to claim 6 , wherein a cooling rate is more than 500° C./hr and at most 1,000° C./hr.
8. The method for preparing an electroconductive mayenite type compound according to claim 1 , wherein the raw material comprises, as represented by mol % and as calculated as the following oxides, from 15 to 66% of at least one member selected from the group consisting of CaO and SrO, from 14 to 63% of Al 2 O 3 , from 0 to 38% of SiO 2 , from 0 to 38% of GeO 2 , from 0 to 38% of B 2 O 3 , from 0 to 5% of Li 2 O, from 0 to 5% of Na 2 O, from 0 to 5% of K 2 O, from 0 to 10% of MgO, from 0 to 10% of BaO, from 0 to 8% of Fe 2O 3 and from 0 to 8% of TiO 2 , and the total of molar ratios of CaO, SrO and Al 2 O 3 is at least 25%.
9. The method for preparing an electroconductive mayenite type compound according to claim 1 , further comprising holding the prepared electroconductive mayenite type compound in air at a temperature of at least 500° C. and not more than the melting point of the compound to adjust the electroconductivity.
10. The method for preparing an electroconductive mayenite type compound according to claim 9 , wherein the electroconductivity of the prepared electroconductive mayenite type compound is adjusted to be at least 10 −10 S and at most 10 3 S/cm.