Polyester process using a pipe reactor
View Patent ↗The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.
1. An esterification system comprising: a pressure decreasing device operable to reduce the pressure of a fluid, wherein said pressure decreasing device defines a solids opening configured to provide direct access to said fluid; an esterification pipe reactor coupled in fluid communication with said pressure decreasing device; and a vapor removing device defining a fluid inlet, a liquid outlet, and a vapor outlet, wherein said fluid inlet is coupled in fluid communication with said esterification pipe reactor, wherein said liquid and vapor outlets are horizontally spaced from said fluid inlet, wherein said vapor outlet is located at a higher elevation than said liquid outlet.
2. The system of claim 1 , wherein said pressure decreasing device defines diverging and expanding zones.
3. The system of claim 1 , wherein said pressure decreasing device comprises an eductor.
4. The system of claim 3 , wherein said eductor defines a throat, wherein said solids opening is located proximate said throat.
5. The system of claim 1 , further comprising a feeding conduit presenting a discharge end and a receiving end, wherein said discharge end is in fluid communication with said solids opening.
6. The system of claim 5 , further comprising a solid reactant storage device couple in fluid communication with said receiving end of said feeding conduit.
7. The system of claim 1 , further comprising a recirculation pump operable to pump a liquid from said liquid outlet of said vapor removing device toward said pressure decreasing device.
8. The system of claim 1 , further comprising a distillation column coupled in fluid communication with said vapor outlet of said vapor removing device.
9. The system of claim 1 , wherein said vapor removing device is substantially horizontally oriented.
10. The system of claim 1 , wherein the cross-sectional area of said vapor removing device is substantially greater than the cross-sectional area of said esterification pipe reactor.
11. The system of claim 1 , wherein said esterification pipe reactor comprises a heat exchanger.
12. The system of claim 11 , wherein said heat exchanger includes at least one substantially horizontal pipe section.
13. The system of claim 11 , wherein said heat exchanger includes a plurality of substantially horizontal pipe sections that are vertically spaced from one another.