Stabilized herbicidal compositions
View Patent ↗A herbicide composition includes a fenoxaprop ester and a weak acid buffer system. The buffer system maintains the herbicidal composition at a pH in the range of 4 to 8. In one non-limiting embodiment, the fenoxaprop ester is fenoxaprop ethyl. The buffer system can include an amine-containing material, such as a tertiary amine. The herbicide composition can include other herbicides, such as weak acid herbicides, for example pyrasulfotole, bromoxynil, and/or bromoxynil esters and can include one or more safeners.
1. A herbicidal composition, comprising: (a) a fenoxaprop ester herbicide; and (b) a buffer system consisting essentially of a tertiary amine and one or more weak acid herbicides comprising pyrasulfotole.
2. The herbicidal composition of claim 1 , further comprising at least one safener.
3. The herbicidal composition of claim 2 , wherein the safener comprises mefenpyr.
4. The herbicidal composition of claim 1 , wherein the buffer system maintains the composition at a pH of from 4 to 8.
5. The herbicidal composition of claim 4 , wherein the buffer system maintains the composition at a pH of from 5.8 to 7.5.
6. The herbicidal composition of claim 1 , wherein the herbicidal composition is selected from the group consisting of an emulsifiable concentrate, suspension concentrate, suspoemulsion and a solution.
7. The herbicidal composition of claim 1 , wherein the herbicidal composition further comprises at least one surfactant.
8. The herbicidal composition of claim 1 , wherein the amine is a tertiary amine or protonated tertiary amine selected from the group consisting of
a) a trialkylamine selected from triethanolamine, triisopropanolamine, triethylamine, trimethylamine, tripropylamine, triisopropylamine, 1-octaneamine-N,N-dimethyl, N,N-dimethylcyclohexanamine, N,N-dimethyl-1-hexadecylamine, 1-dodeccanamine-N,N-dimethyl, ethyldiethanolamine, hexamethylenetetramine, N,N,N″,N″-tetrakis-(2-hydroxypropyl) ethylene diamine, dicocoalkyl-methylamine, didecylmethylamine, tridodecyamine, trihexadecylamine;
b) a monoalkyldimethylamine selected from the group consisting of dodecyldimethylamine, hexadecyl-dimethylamine, octadecyl-dimethylamine, cocoalkyl-dimethylamine, soyalkyl-dimethylamine, soyaalkyl-dimethylamine, tallowalkyl-dimethylamine, hydrogenated tallowalkyl-dimethylamine, cottonseed alkyl-dimethylamine;
c) an ethoxylated alkylamine selected from the group consisting of ethoxylated (n) cocoalkylamine, ethoxylated (n) tallowalkylamine, ethoxylated (n) soyaalkylamine, ethoxylated cottonseed amine, oleyl amine ethoxylate, ethoxylated (n) octadecylamine, wherein the ethoxy group numbers of n may be from 1 to 60;
d) an ethoxylated diamine selected from the group consisting of ethoxylated(n) N-tallow-1,3-diaminopropane, ethoxylated(n) N-tallow-1,3-diaminopropane, ethoxylated(n) N-tallow-1,3-diaminopropane, N,N-bis[α-ethyl-(.omega.-hydroxypoly(oxyethylene)alkylamine wherein the poly(oxyethylene) content is an average 3 moles and the alkyl groups (C14-C18) are derived from tallow, or from soybean or cottonseed oil acids, or other crop or vegetable seeds oil acids;
e) N,N-bis(2-hydroxyethyl)alkylamine, where the alkyl groups (C8-C18) are derived from coconut, cottonseed, soya, or tallow acids or other crops or vegetable seed acids;
f) N,N-Bis 2-(.omega.-hydroxypolyoxyethylene)ethyl)alkylamine; the reaction product of 1 mole N,N-bis(2-hydroxyethyl)alkylamine and 3-60 moles of ethylene oxide, where the alkylgroup (C8-C18) is derived from coconut, cottonseed, soya, or tallow acids or other crop or vegetable seed acids;
g) N,N-Bis-2-(.omega.-hydroxypolyoxyethylene/polyoxypropylene)ethyl alkylamine; the reaction product of 1 mole of N,N-bis(2-hydroxyethyl alkylamine) and 3-60 moles of ethylene oxide and propylene oxide, where the alkyl group (C8-C18) is derived from coconut, cottonseed, soya, or tallow acids or other crop seeds or, vegetable seeds acids; and
h) N,N′-Bis,(2-hydroxyethyl)-C12-C18 alkylamine, N,N′-bis(polyoxyethylene)cetylamine, N,N′-Bis(polyoxyethylene)oleylamine, N,N′-bis(polyoxyethylene)stearylamine, N,N′-dinitropentamethylenetetramine, ethoxylated abietylamine.
9. A herbicidal composition, consisting essentially of: (a) a fenoxaprop ester herbicide; and (b) a buffer system consisting essentially of a tertiary amine and one or more weak acid herbicides comprising pyrasulfotole.
10. The herbicidal composition of claim 1 , wherein the tertiary amine is a triethanolamine.
11. The herbicidal composition of claim 1 , wherein the tertiary amine is a trialkylamine.
12. The herbicidal composition of claim 1 , wherein the tertiary amine is a monoalkyldimethylamine.
13. The herbicidal composition of claim 1 , wherein the tertiary amine is an ethoxylated alkylamine.
14. The herbicidal composition of claim 1 , wherein the tertiary amine is a an ethoxylated diamine.
15. The herbicidal composition of claim 1 , wherein the tertiary amine is a N,N-bis(2-hydroxyethyl)alkylamine.
16. The herbicidal composition of claim 1 , wherein the tertiary amine is a N,N-Bis2-(.omega.-hydroxypolyoxyethylene)ethyl)alkylamine.
17. The herbicidal composition of claim 1 , wherein the tertiary amine is a N,N-Bis-2-(.omega.-hydroxypolyoxyethylene/polyoxypropylene)ethyl alkylamine.
18. The herbicidal composition of claim 1 , wherein the tertiary amine is a N,N′-Bis,(2-hydroxyethyl)-C12-C18 alkylamine.
19. The herbicidal composition of claim 1 , wherein the buffer system consists of a tertiary amine and one or more weak acids comprising pyrasulfotole.
20. The herbicidal composition of claim 9 , wherein the buffer system consists of a tertiary amine and one or more weak acid herbicides comprising pyrasulfotole.