Branched polysiloxane composition
View Patent ↗The invention relates to branched polysiloxane compositions resulting from copolymerizing under hydrosilylation conditions a component mixture comprising (a) one or more organosilicon compounds containing at least two unsaturated hydrocarbon functional groups per molecule, and (b) one or more silylhydride-containing compounds containing at least two silylhydride functional groups per molecule, with the provision that (i) at least one component (a) or (b) contains at least three functional groups per molecule; (ii) a component (a) or (b) having a higher number of functional groups per molecule is present in a molar amount equal to or lower than a molar amount of the other component (a) or (b) having a lower number of functional groups per molecule; and (iii) unsaturated hydrocarbon compounds are excluded from the component mixture.
1. A branched polysiloxane composition resulting from copolymerizing under hydrosilylation conditions a component mixture comprising:
(a) one or more organosilicon compounds containing at least two unsaturated hydrocarbon functional groups per molecule, said unsaturated hydrocarbon functional groups capable of undergoing a hydrosilylation reaction with a silylhydride-containing compound under hydrosilylation conditions, provided that when said component (a) is a polysiloxane, it contains at least one D or T silicone unit that contains at least one unsaturated hydrocarbon functional group; and
(b) one or more silylhydride-containing compounds containing at least two silylhydride functional groups per molecule;
provided that (i) at least one component (a) or (b) contains at least three functional groups per molecule; (ii) one component (a) or (b) has a higher number of functional groups per molecule and is in a lower molar amount than another component (a) or (b) having a lower number of functional groups per molecule; and (iii) unsaturated hydrocarbon compounds are excluded from the component mixture.
2. The composition of claim 1 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.25−s):1 or 1:(1+t) where s represents a number equal to or greater than 0 and less than 3.25, and t represents a number greater than 0 and equal to or less than 3.25.
3. The composition of claim 1 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.6−s):1 where s represents a number greater than 0 and less than 3.6.
4. The composition of claim 1 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range of about 4.5:1 to about 2:1.
5. The composition of claim 1 , wherein one component (a) or (b) has at least four functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having two or three functional groups per molecule.
6. The composition of claim 1 , wherein one component (a) or (b) has at least six functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having two or three functional groups per molecule.
7. A branched polysiloxane composition resulting from copolymerizing under hydrosilylation conditions a component mixture comprising:
(a) one or more organosilicon compounds containing at least two unsaturated hydrocarbon functional groups per molecule, said unsaturated hydrocarbon functional groups capable of undergoing a hydrosilylation reaction with a silylhydride-containing compound under hydrosilylation conditions, provided that when said component (a) is a polysiloxane, it contains at least one D or T silicone unit that contains at least one unsaturated hydrocarbon functional group; and
(b) one or more silylhydride-containing compounds containing at least two silylhydride functional groups per molecule;
provided that (i) at least one component (a) or (b) contains at least three functional groups per molecule; (ii) unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range of about (6−s):1 or about 1:(1+t) where s represents a number equal to or greater than 0 and less than 5, and t represents a number greater than 0 and equal to or less than 5; (iii) one component (a) or (b) has a higher number of functional groups per molecule and is in a lower molar amount than another component (a) or (b) having a lower number of functional groups per molecule; (iv) unsaturated hydrocarbon compounds are excluded from the component mixture.
8. The composition of claim 7 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.6−s):1 or 1:(1+s) where s represents a number greater than 0 and less than 3.6.
9. The composition of claim 7 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.25−s):1 or 1:(1+t) where s represents a number equal to or greater than 0 and less than 3.25, and t represents a number greater than 0 and equal to or less than 3.25.
10. The composition of claim 7 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.6−s):1 where s represents a number greater than 0 and less than 3.6.
11. The composition of claim 7 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range of about 4.5:1 to about 2:1.
12. The composition of claim 7 , wherein one component (a) or (b) has at least four functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having a two or three functional groups per molecule.
13. The composition of claim 7 , wherein one component (a) or (b) has at least six functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having two or three functional groups per molecule.
14. A branched polysiloxane composition resulting from copolymerizing under hydrosilylation conditions a component mixture comprising:
(a) one or more organosilicon compounds containing at least two unsaturated hydrocarbon functional groups per molecule, said unsaturated hydrocarbon functional groups capable of undergoing a hydrosilylation reaction with a silylhydride-containing compound under hydrosilylation conditions, provided that when said component (a) is a polysiloxane, it contains at least one D or T silicone unit that contains at least one unsaturated hydrocarbon functional group; and
(b) one or more silylhydride-containing compounds containing at least two silylhydride functional groups per molecule;
provided that (i) at least one component (a) or (b) contains at least three functional groups per molecule; (ii) unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.6−s):1 or 1:(1+s) where s represents a number greater than 0 and less than 3.6; (iii) one component (a) or (b) has a higher number of functional groups per molecule and is in a lower molar amount than another component (a) or (b) having a lower number of functional groups per molecule; (iv) unsaturated hydrocarbon compounds are excluded from the component mixture.
15. The composition of claim 14 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.25−s):1 or 1:(1+t) where s represents a number equal to or greater than 0 and less than 3.25, and t represents a number greater than 0 and equal to or less than 3.25.
16. The composition of claim 14 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range according to a formula (4.6−s):1 where s represents a number greater than 0 and less than 3.6.
17. The composition of claim 14 , wherein the unsaturated hydrocarbon functional groups of component (a) are in a molar ratio to silylhydride functional groups of component (b) within a range of about 4.5:1 to about 2:1.
18. The composition of claim 7 , wherein one component (a) or (b) has at least four functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having two or three functional groups per molecule.
19. The composition of claim 14 , wherein one component (a) or (b) has at least six functional groups per molecule and is in a lower molar amount than the other component (a) or (b) having two or three functional groups per molecule.