IP Library Granted Patent US 7,465,693
Granted Patent B2
US 7,465,693 · App. 11/520,237 · Granted Dec 16, 2008

Thermochromatic temperature marking for outdoor surfaces

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Quick Facts
Patent No.
US 7,465,693
App. No.
11/520,237
Granted
Dec 16, 2008
Kind
B2
Abstract

The present invention relates to a system, method, and composition for a thermochromatic, color indicative sheet or device that is bonded to an article such as a concrete or asphalt surface, a traffic sign, a plate of a guidepost and on which is indicated a surface temperature near or below the freezing point of water. The invention can also utilize an adhesive system including a pressure sensitive adhesive (PSA) and/or thermal sensitive adhesive sheet for adhering sheets of preformed thermoplastic with the thermochromatic color indicative sheet to concrete, asphalt, wood or composite material surfaces. The invention includes methods of applying the product allowing for immediate use in a traffic area upon completion of the application to any appropriate outdoor surface.

Claims (37)

1. A roadway marker with a thermochromatic surface comprising;

at least two preformed thermoplastic segment(s) that include top sides and bottom sides wherein said thermochromatic surface is attached to said top sides and wherein said bottom side either includes an adhesive layer or no adhesive layer on a bottom side of said thermoplastic segment(s), and wherein said sheeting is subsequently attached to a substrate.

2. The marker of claim 1 , wherein said thermochromatic surface has a visible detectable image when the temperature is near or below the freezing point of water.

3. The marker of claim 1 , wherein preformed thermochromatic road marking material is used for said thermochromatic sheet, wherein said sheet is color indicating and comprises a thermochromatic pigment with a color transition at zero degrees Celsius, therein producing a color change near or below the freezing point of water.

4. The marker of claim 3 , wherein said thermochromatic pigment is used in concentrations of 1% to 20%.

5. The marker of claim 4 , wherein said thermochromatic pigment is used at a concentration of 4%.

6. The marker of claim 1 , wherein said marker comprises more than one preformed thermoplastic segment which can be matched with at least one other preformed thermoplastic segment such that said thermochromatic surface layer provides a desired pattern.

7. A method for providing a roadway marker with a thermochromatic surface comprising;

providing at least two preformed thermoplastic segment(s) that include top sides and bottom sides wherein said thermochromatic surface is attached to said top sides and wherein said bottom side either includes an adhesive layer or no adhesive layer on a bottom side of said thermoplastic segment(s), and wherein attaching said sheeting to a substrate is accomplished by pressure, heat, or any useful form and combination of heat and or pressure.

8. The method of claim 7 , wherein a detectable image is visualized within said thermochromatic surface when the temperature is near or below the freezing point of water.

9. The method of claim 7 , wherein said thermochromatic sheet indicates a tone, hue or color and comprises a thermochromatic pigment with a color transition at zero degrees Celsius, therein producing a color change near or below the freezing point of water.

10. The method of claim 7 , wherein said thermochromatic sheet contains pigment in concentrations of 1% to 20%.

11. The method of claim 10 , wherein said thermochromatic sheet contains pigment at a concentration of 4%.

12. The method of claim 7 , wherein producing said roadway marker comprises more than one preformed thermoplastic segment(s) matching with at least one other preformed thermoplastic segment(s) thereby providing thermochromatic surface layers with a desired pattern.

13. A roadway marker with a thermochromatic adhesive backed sheeting comprising;

at least two preformed thermoplastic segments of said sheeting that includes top sides and bottom sides with an adhesive layer on said bottom sides of said thermoplastic segments;

and;

a protective sheet covering said adhesive layer on said bottom sides;

wherein said bottom sides and said protective sheets covering said adhesive layer of said bottom sides may be subsequently adhered to any suitable outdoor surface using at least pressure to provide adequate bond strength to ensure a proper permanent or semi-permanent or temporary surface covering said suitable outdoor surface and wherein the chemical composition of said adhesive is alkyl or butyl-based and wherein said top side is a thermochromatic, color indicative sheet or device that is bonded to a concrete or asphalt surface, a traffic sign, or a plate of a guidepost and upon which is indicated a surface temperature

and;

a protective sheet for pressure sensitive adhesive only that covers said adhesive layer on said bottom sides.

14. The marker of claim 13 , wherein said marker comprises a protective sheet covering and said protective sheet covering is comprised of primarily a silicone elastomer or other silicone based thermoplastic.

15. The marker of claim 13 , wherein said marker comprises more than one preformed thermoplastic segments which can be matched with at least one other preformed thermoplastic segments such that said a thermochromatic surface layer provides a desired pattern.

16. A method for providing a thermochromatic adhesive backed sheeting comprising;

providing at least two preformed thermoplastic segments of said sheeting that includes top sides and bottom sides with an adhesive layer on said bottom sides of said thermoplastic segments;

and;

a protective sheet covering said adhesive layer on said bottom sides;

wherein said bottom sides and said protective sheets covering said adhesive layer of said bottom sides may be subsequently adhered to any suitable outdoor surface using at least pressure to provide adequate bond strength to ensure a proper permanent or semi-permanent or temporary surface covering said suitable outdoor surface and wherein the chemical composition of said adhesive is alkyl or butyl-based and wherein said top side is a thermochromatic, color indicative sheet or device that is bonded to a concrete or asphalt surface, a traffic sign, or a plate of a guidepost and upon which is indicated a surface temperature.

17. The method of claim 16 , wherein said marker provided comprises a protective sheet and said protective sheet is comprised of primarily a silicone elastomer or other silicone based thermoplastic.

18. The method of claim 17 , wherein said marker comprises more than one preformed thermoplastic segment which can be matched with at least one other preformed thermoplastic segment such that said a thermochromatic surface layer provides a desired pattern.

19. A system comprising providing an adhesive backed thermochromatic sheeting comprising;

at least two preformed thermoplastic segments of said sheeting that includes top sides and bottom sides with an adhesive layer on said bottom sides of said thermoplastic segments;

and;

a protective sheet covering said adhesive layer on said bottom sides;

wherein said bottom sides and said protective sheets covering said adhesive layer of said bottom sides may be subsequently adhered to any suitable outdoor surface using at least pressure to provide adequate bond strength to ensure a proper permanent or semi-permanent or temporary surface covering said suitable outdoor surface and wherein the chemical composition of said adhesive is alkyl or butyl-based and wherein said top side is a thermochromatic, color indicative sheet or device that is bonded to a concrete or asphalt surface, a traffic sign, or a plate of a guidepost and upon which is indicated a surface temperature.

20. The system of claim 19 , wherein said thermochromatic sheeting comprises said protective sheet covering and said protective sheet covering is comprised of primarily a silicone elastomer or other silicone based thermoplastic.

21. The system of claim 19 , wherein said thermochromatic sheeting comprises more than one preformed thermoplastic segment which can be matched with at least one other preformed thermoplastic segment such that said thermochromatic sheeting provides a desired pattern.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Dec 30, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: ENNIS PAINT INC.; FLINT TRADING INC.; EBERLE DESIGN INC.; RENO A&E LLC
Reel/Frame 054896/0344 →
RELEASE OF SECURITY INTEREST Recorded Dec 27, 2020
From: ANTARES CAPITAL LP, AS ADMINISTRATIVE AGENT
To: EBERLE DESIGN, INC.; ENNIS PAINT, INC.; FLINT TRADING, INC.; RENO A&E, LLC
Reel/Frame 054864/0024 →
MERGER AND CHANGE OF NAME Recorded Nov 24, 2020
From: FLINT ACQUISITION CORP.; ENNIS-FLINT, INC.
To: ENNIS-FLINT, INC.
Reel/Frame 054510/0801 →
MERGER AND CHANGE OF NAME Recorded Nov 24, 2020
From: FLINT TRADING, INC.; FLINT ACQUISITION CORP.
To: FLINT ACQUISITION CORP.
Reel/Frame 054510/0783 →
SECURITY INTEREST Recorded Jun 23, 2016
From: ENNIS PAINT, INC.; FLINT TRADING, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039128/0732 →
TERMINATION OF SECURITY INTEREST IN PATENTS Recorded Jun 15, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: RENO A&E, LLC; EBERLE DESIGN, INC.; FLINT TRADING, INC.; ENNIS PAINT, INC.
Reel/Frame 039025/0246 →
TERMINATION OF SECURITY INTEREST IN PATENTS Recorded Jun 15, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: FLINT TRADING, INC.; ENNIS PAINT, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
Reel/Frame 039025/0196 →
SECURITY INTEREST Recorded Jun 13, 2016
From: ENNIS PAINT, INC.; FLINT TRADING, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: ANTARES CAPITAL LP
Reel/Frame 038978/0976 →
RELEASE OF SECURITY INTEREST (FIRST LIEN) Recorded Apr 2, 2014
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FLINT ACQUISITION CORP.; FLINT TRADING, INC.; PRECISION SCAN, L.L.C.; ENNIS PAINT, INC.
Reel/Frame 032591/0201 →
RELEASE OF SECURITY INTEREST (SECOND LIEN) Recorded Apr 2, 2014
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FLINT ACQUISITION CORP.; FLINT TRADING, INC.; PRECISION SCAN, L.L.C.; ENNIS PAINT, INC.
Reel/Frame 032591/0216 →
PATENT SECURITY AGREEMENT (SECOND LIEN) Recorded Apr 2, 2014
From: FLINT TRADING, INC.; ENNIS PAINT, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 032591/0239 →
PATENT SECURITY AGREEMENT (FIRST LIEN) Recorded Apr 2, 2014
From: FLINT TRADING, INC.; ENNIS PAINT, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 032591/0275 →