IP Library Granted Patent US 7,658,903
Granted Patent B2
US 7,658,903 · App. 11/531,078 · Granted Feb 9, 2010

High purity nuclear graphite

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Quick Facts
Patent No.
US 7,658,903
App. No.
11/531,078
Granted
Feb 9, 2010
Kind
B2
Abstract

A highly isotropic graphite useful for, inter alia, nuclear applications is disclosed, which has a ash content of less than 300 ppm and a boron equivalence of less than about 2 ppm without requiring a post graphitization purification step.

Claims (14)

1. A method of producing a graphite article comprising:

a. mixing raw needle coke having a coefficient of thermal expansion less than 0.4 ppm/° C. measured between 30° C. and 100° C. and which has been milled such that 95% by weight passes through a screen having mesh size of about 100 microns with binder pitch to form a coke mixture;

b. milling the coke mixture to create a molding powder such that 95% by weight passes through a screen having mesh size of about 150 microns;

c. isostatically molding the molding powder to form a green article; and

d. graphitizing the processed carbonaceous article to obtain a graphite article having an isotropy ratio of no greater than about 1.5, where isotropy ratio is defined as the ratio of coefficient of thermal expansion in two directions, with less than about 300 parts per million ash and less than about 2 parts per million boron equivalence without a post-graphite purification treatment.

2. The method of claim 1 wherein the needle coke is petroleum coke.

3. The method of claim 1 wherein the powdered needle coke has a particle size of passing about 75 microns.

4. The method of claim 3 wherein about 95% of the powered needle coke has a particle size of passing about 44 microns.

5. The method of claim 1 wherein the molding powder of step b) has an average particle size of passing about 100 microns.

6. The method of claim 1 wherein the graphite article has an average density of from about 1.5 g/cc to about 1.8 g/cc.

7. The method of claim 1 wherein the graphite article has a flexural strength of from about 25 MPa to about 40 MPa.

8. The method of claim 1 wherein the graphite article has a thermal conductivity greater than about 85 W/mK.

9. The method of claim 1 wherein the graphite article has an isotropy ratio of less than about 1.15.

10. The method of claim 1 wherein the graphite article has a coefficient of thermal expansion of from about 3 ppm/° C. to about 6 ppm/° C. at temperatures of from 30° C. to 100° C.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2017
From: GRAFTECH ADVANCED GRAPHITE MATERIALS LLC
To: GT ACQUISITION HOLDINGS, LLC
Reel/Frame 043943/0939 →
RELEASE OF SECURITY INTEREST Recorded Oct 4, 2017
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: GRAFTECH ADVANCED GRAPHITE MATERIALS LLC
Reel/Frame 043777/0325 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 21, 2016
From: GRAFTECH INTERNATIONAL HOLDINGS INC.
To: GRAFTECH ADVANCED GRAPHITE MATERIALS LLC
Reel/Frame 040384/0248 →
SECURITY AGREEMENT Recorded Jul 14, 2010
From: GRAFTECH INTERNATIONAL HOLDINGS INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024678/0830 →
CHANGE OF NAME Recorded Oct 15, 2007
From: UCAR CARBON COMPANY INC.
To: GRAFTECH INTERNATIONAL HOLDINGS INC.
Reel/Frame 019961/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 27, 2006
From: MILLER, DOUGLAS J.; BALL, DAVID R.
To: UCAR CARBON COMPANY INC.
Reel/Frame 018600/0083 →