Superabsorbent particles containing carboxyalkyl cellulose and temporary metal crosslinks
View Patent ↗Particles comprising a combination of a carboxyalkyl cellulose and a galactomannan polymer or a glucomannan polymer, wherein the particles comprise a plurality of non-permanent metal crosslinks.
1. Particles comprising a combination of a carboxyalkyl cellulose and a galactomannan polymer or a glucomannan polymer, wherein the particles comprise a plurality of non-permanent metal crosslinks and wherein the particles do not have permanent crosslinks.
2. The particles of claim 1 , wherein the carboxyalkyl cellulose has a degree of carboxyl group substitution of from about 0.3 to about 2.5.
3. The particles of claim 1 , wherein the carboxyalkyl cellulose is carboxymethyl cellulose.
4. The particles of claim 1 , wherein the galactomannan polymer is selected from the group consisting of guar gum, locust bean gum, and tarn gum.
5. The particles of claim 1 , wherein the glucomannan polymer is konjac gum.
6. The particles of claim 1 , wherein the galactomannan polymer or glucomannan polymer is present in an amount from about 1 to about 20 percent by weight based on the total weight of the particles.
7. The particles of claim 1 , wherein the carboxyalkyl cellulose is present in an amount from about 60 to about 99 percent based on the total weight of particles.
8. The particles of claim 1 , wherein the non-permanent metal crosslinks comprise multi-valent metal ion crosslinks.
9. The particles of claim 1 , wherein the non-permanent metal crosslinks comprise one or more metal ions selected from the group consisting of aluminum, boron, bismuth, titanium, and zirconium, and mixtures thereof.
10. The particles of claim 1 having a free swell capacity of from about 30 to about 60 g/g for 0.9% saline solution.
11. The particles of claim 1 having a centrifuge retention capacity of from about 15 to about 35 g/g for 0.9% saline solution.
12. The particles of claim 1 having an absorbency under load capacity of from about 15 to about 30 g/g for 0.9% saline solution.
13. The particles of claim 1 having a size less than about 800 μm.