IP Library Granted Patent US 7,413,013
Granted Patent B2
US 7,413,013 · App. 11/541,085 · Granted Aug 19, 2008

Surfactant-based fluid loss control agents for surfactant gels and associated fluids and methods

Assignee: Halliburton Energy Services, Inc.
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Quick Facts
Patent No.
US 7,413,013
App. No.
11/541,085
Granted
Aug 19, 2008
Kind
B2
Abstract

Of the many methods provided, in one aspect, the present invention provides a method comprising: providing a treatment fluid comprising: an aqueous base fluid, a first surfactant, and a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid; and introducing the treatment fluid into a well bore that penetrates the subterranean formation.

Claims (43)

1. A method comprising:

providing a treatment fluid comprising:

an aqueous base fluid,

a first surfactant, and

a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid, wherein the surfactant-based fluid loss control agent comprises at least one viscoelastic gel forming surfactant selected from the group consisting of: a methyl ester sulfonate, a taurate, a behenyl quat, behenyl trimethyl ammonium chloride, and any derivative thereof; and

introducing the treatment fluid into a well bore that penetrates the subterranean formation.

2. The method of claim 1 wherein the treatment fluid is introduced into the well bore as part of a fracturing, acidizing, gravel packing, drilling, plugging, or a fluid loss control operation.

3. The method of claim 1 wherein the treatment fluid exhibits viscoelastic behavior due, at least in part, to the association of at least a portion of the surfactant into a plurality of micellar associations.

4. The method of claim 1 wherein the concentration of the first surfactant in the treatment fluid is about zero.

5. The method of claim 1 wherein the treatment fluid comprises at least one water-soluble salt or at least one anion.

6. The method of claim 1 wherein the surfactant-based fluid loss control agent comprises the taurate, wherein the taurate is chosen from the group consisting of: water-soluble substituted taurines; N-acyl N-methyl taurates; N-cetyl N-methyl taurate; N-erucyl N-methyl taurate; N-oleoyl N-methyl taurate; N-cocoyl N-methyl taurate; N-tallowyl N-methyl taurate; N-tallyl N-methyl taurate; N-soyayl N-methyl taurate; N-rapeseedyl N-methyl taurate; N-acyl taurates; N-erucyl taurate; N-oleoyl taurate; N-cocoyl taurate; N-tallowyl taurate; N-tallyl taurate; N-soyayl taurate; N-rapeseedyl taurate; and

combinations and derivatives thereof.

7. The method of claim 1 wherein the surfactant-based fluid loss control agent comprises the methyl ester sulfonate, wherein the methyl ester sulfonate is described by the following formula:

where R is an alkyl chain of from about 10 carbon atoms to about 30 carbon atoms.

8. The method of claim 1 wherein the first surfactant is a cationic, anionic, or amphoteric surfactant.

9. The method of claim 1 wherein the first surfactant comprises a surfactant chosen from the group consisting of: betaines; modified betaines; sulfosuccinates;

taurates; amine oxides; ethoxylated fatty amines; quaternary ammonium compounds; and

combinations or derivatives thereof.

10. The method of claim 1 wherein the treatment fluid is foamed or commingled with a gas.

11. The method of claim 1 wherein the treatment fluid further comprises an additive selected from the group consisting of: co-surfactants; particulates; pH adjusting agents; acids, fluid loss control additives; gases; corrosion inhibitors; scale inhibitors; catalysts; clay control agents; biocides; hydrate inhibitors; breakers; foamers; emulsifiers; nonemulsifiers;

demulsifiers; oxidizers; reducers; friction reducers; particulate scale inhibitors; surfactant solubilizers; and combinations thereof.

12. The method of claim 1 wherein the treatment fluid is prepared on the job site.

13. The method of claim 1 wherein the treatment fluid comprises a viscosifier.

14. The method of claim 1 wherein the viscoelastic gel forming surfactant comprises a powdered or solid surfactant.

15. A method of providing fluid loss to a surfactant gel comprising adding a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid to the surfactant gel, wherein the surfactant-based fluid loss control agent comprises at least one powdered or solid viscoelastic gel forming surfactant selected from the group consisting of: a methyl ester sulfonate, a taurate, a behenyl quat, behenyl trimethyl ammonium chloride, and any derivative thereof.

16. The method of claim 15 wherein the surfactant-based fluid loss control agents are included in an amount of from about 0.0 1% to about 30% based on the weight of the surfactant gel.

17. The method of claim 15 further comprising introducing the surfactant gel into a subterranean formation.

18. A method of fracturing a subterranean formation comprising:

providing a treatment fluid, the treatment fluid comprising:

an aqueous base fluid;

a first surfactant; and

a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid, wherein the surfactant-based fluid loss control agent comprises at least one powdered or solid viscoelastic gel forming surfactant selected from the group consisting of: a methyl ester sulfonate, a taurate, a behenyl quat, behenyl trimethyl ammonium chloride, and any derivative thereof; and

introducing the treatment fluid into a well bore that penetrates the subterranean formation at or above a pressure sufficient to create or enhance one or more fractures in a portion of the subterranean formation.

19. The method of claim 18 wherein the concentration of the first surfactant in the treatment fluid is about zero.

20. A method comprising:

providing a treatment fluid comprising:

an aqueous base fluid, and

a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid, wherein the surfactant-based fluid loss control agent comprises at least one powdered or solid viscoelastic gel forming surfactant selected from the group consisting of: a methyl ester sulfonate, a taurate, a behenyl quat, behenyl trimethyl ammonium chloride, and any derivative thereof; and

introducing the treatment fluid into a well bore that penetrates the subterranean formation.

21. The method of claim 20 wherein the treatment fluid comprises a viscosifier.

22. A method comprising:

providing a treatment fluid that comprises an aqueous base fluid, particulates, a first surfactant, and a surfactant-based fluid loss control agent capable of forming a viscoelastic fluid, wherein the surfactant-based fluid loss control agent comprises at least one powdered or solid viscoelastic gel forming surfactant selected from the group consisting of: a methyl ester sulfonate, a taurate, a behenyl quat, behenyl trimethyl ammonium chloride, and any derivative thereof;

introducing the treatment fluid into a well bore that penetrates a subterranean formation such that the particulates form a gravel pack in or adjacent to a portion of the subterranean formation.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2006
From: WELTON, THOMAS D.; MCMECHAN, DAVID E.; BRYANT, JASON E.
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 018371/0234 →
Continuity (1)
Related Publication 20080078546A1 · Apr 3, 2008