Wetness indicating composition
View Patent ↗A wetness indicating composition is disclosed that changes color in response to a change in pH. The composition comprises a water-insoluble, thermoplastic polymer composition, a superabsorbent polymer, a wetness indicator, and surfactant. The wetness indicating composition is useful in disposable absorbent articles, e.g., disposable diapers, feminine napkins, medical dressings and beddings for humans and animals.
1. A wetness indicating composition comprising:
(a) at least one water insoluble, thermoplastic polymer composition;
(b) at least one surfactant;
(c) at least one wetness indicator comprising an indicating agent and a pH modifier; and
(d) at least one superabsorbent polymer.
2. The wetness indicating composition of claim 1 wherein the indicating agent changes color in response to a change in the pH of the wetness indicating composition.
3. The wetness indicating composition of claim 1 wherein the wetness indicator comprises from about 0.01% by weight to about 60% by weight of the wetness indicating composition.
4. The wetness indicating composition of claim 3 wherein the wetness indicator comprises from about 5% by weight to about 50% by weight of the wetness indicating composition of a pH modifier and from about 0.01% by weight to about 5% by weight of the wetness indicating composition of a wetness indicator.
5. The wetness indicating composition according to claim 1 comprising from about 5% by weight to about 80% by weight of the water insoluble, thermoplastic polymer composition; from about 0.5% by weight to about 50% by weight of the surfactant; from about 0.01% by weight to about 60% by weight of the wetness indicator, and from about 2% by weight to about 50% by weight of the super absorbent polymer.
6. The wetness indicating composition of claim 1 wherein the water insoluble, thermoplastic polymer composition further comprises at least one material selected form the group consisting of tackifying agents and plasticizers.
7. The wetness indicating composition according to claim 6 wherein at least one of the tackifying agent and the plasticizer is polar.
8. The wetness indicating composition of claim 6 comprising from about 5% by weight to about 50% by weight of the tackifying agent and from about 5% by weight to about 50% by weight of the plasticizer.
9. The wetness indicating composition of claim 1 wherein the super absorbent polymer has a particle size of from about 1 μm to about 400 μm.
10. A disposable absorbent article comprising the composition of claim 1 applied to at least a portion of a surface of a substrate.
11. The disposable absorbent article according to claim 10 selected from the group consisting of a diaper, a feminine napkin, a medical dressing and beddings for humans and animals.
12. A wetness indicating composition comprising at least one superabsorbent polymer and a wetness indicator, said wetness indicator comprising an indicating agent and a pH modifier.
13. A wetness indicating composition comprising:
(a) at least one water insoluble, thermoplastic hot melt polymer composition;
(b) at least one surfactant;
(c) at least one wetness indicator comprising an indicating agent and a pH modifier; and
(d) at least one superabsorbent polymer.
14. A method of making a wetness indicating composition according to claim 1 , the method comprising the steps of:
(a) combining the water insoluble, thermoplastic polymer, the superabsorbent polymer in a suitable mixing device and heating until the combination has become molten;
(b) adding the surfactant, and optionally a nanoclay powder, to the molten mixture and mixing until a uniform molten mixture is obtained;
(c) subsequently adding the wetness indicator to the uniform molten mixture and mixing for a time to provide a uniform molten mixture of the wetness indicating composition; and
(d) optionally, solidifying the mixture of step (c).
15. The wetness indicating composition according to claim 1 further comprising a nanoclay powder.
16. The wetness indicating composition according to claim 15 wherein the nanoclay powder is selected from the group consisting of kaolinites, montmorillonite/smectites, illites, chlorites and combinations thereof.
17. The wetness indicating composition according to claim 15 wherein the surface of the nanoclay powder comprises a quaternary ammonium salt that has a cation selected from the group consisting of (a) dimethyl, benzyl, hydrogenated tallow quaternary ammonium (2 MBHT), (b) dimethyl, dihydrogenated tallow, quaternary ammonium (2M2HT), (c) dimethyl, hydrogenated tallow, 2-ethylhexyl quaternary ammonium (2 MHTL8), (d) methyl, tallow, bis-2-hydroxyethyl, quaternary ammonium (MT2EtOH), and (f) combinations thereof.
18. The wetness indicating according to claim 15 wherein the nanoclay powder comprises from about 0.3% by weight to about 5% by weight of wetness indicating composition.
19. The wetness indicating composition according to claim 15 wherein the nanoclay powder comprises platelets.
20. The wetness indicating composition according to claim 19 wherein the individual platelets of the nanoclay powder have an aspect ratio of at least 50.
21. The wetness indicating composition according to claim 15 wherein the nanoclay powder has a dry particle size of less than 15 micrometers by volume.
22. The wetness indicating composition according to claim 1 , further comprising nanoclay powder free from quaternary ammonium salt on its surface.