Superabrasive elements, methods of manufacturing, and drill bits including same
View Patent ↗Methods of manufacturing a superabrasive element are disclosed. In one embodiment, a substrate and a preformed superabrasive volume may be at least partially surrounded by an enclosure and the enclosure may be sealed in an inert environment. Further, the enclosure may be exposed to an elevated pressure and preformed superabrasive volume may be affixed to the substrate. Polycrystalline diamond elements are disclosed. In one embodiment, a polycrystalline diamond element may comprise a preformed polycrystalline diamond volume bonded to a substrate by a braze material. Optionally, such a polycrystalline diamond element may exhibit a compressive stress. Rotary drill bit for drilling a subterranean formation and including at least one superabrasive element are also disclosed.
1. A superabrasive compact, comprising:
a substrate;
a preformed polycrystalline diamond table; and
a braze material bonding the substrate to the preformed polycrystalline diamond table, wherein at least a majority of the braze material comprises an iron-nickel-based alloy, wherein the braze material is depleted from a selected region of the preformed polycrystalline diamond table;
wherein the preformed polycrystalline diamond table is brazed to the substrate with the braze material according to a process comprising:
disposing the braze material between the substrate and the preformed polycrystalline diamond table; and
subjecting the braze material, the substrate, and the preformed polycrystalline diamond table to a high-pressure/high-temperature brazing process having a pressure of at least about 20 kilobar and a temperature of at least about 800° Celsius;
wherein the preformed polycrystalline diamond table exhibits a compressive residual stress field characteristic of the preformed polycrystalline diamond table being brazed to the substrate with the braze material in the high-pressure/high-temperature brazing process.
2. The superabrasive compact of claim 1 , wherein subjecting the braze material, the substrate, and the preformed polycrystalline diamond table to a high-pressure/high-temperature brazing process having a pressure of at least about 20 kilobar and a temperature of at least about 800° Celsius comprises subjecting the braze material, the substrate, and the preformed polycrystalline diamond table to a pressure of at least about 60 kilobar and a temperature of at least about 1350° Celsius.
3. The superabrasive compact of claim 1 , wherein subjecting the braze material, the substrate, and the preformed polycrystalline diamond table to a high-pressure/high-temperature brazing process having a pressure of at least about 20 kilobar and a temperature of at least about 800° Celsius comprises subjecting the braze material, the substrate, and the preformed polycrystalline diamond table to a pressure of about 20 kilobar to about 60 kilobar.
4. The superabrasive compact of claim 1 , wherein the substrate comprises cobalt-cemented tungsten carbide.
5. The superabrasive compact of claim 1 , wherein the preformed polycrystalline diamond table comprises a catalyst.
6. The superabrasive compact of claim 1 , wherein the performed polycrystalline diamond volume was initially formed with a catalyst and a portion of the catalyst is removed from the preformed polycrystalline diamond table.
7. The superabrasive compact of claim 1 , wherein the performed polycrystalline diamond volume was initially formed with a catalyst and substantially all of the catalyst is removed from the preformed polycrystalline diamond table.
8. The superabrasive compact of claim 1 , wherein the iron-nickel alloy comprises about 64% iron and 36% nickel.
9. A superabrasive compact, comprising:
a substrate;
a preformed polycrystalline diamond table comprising a polycrystalline diamond matrix, the preformed polycrystalline diamond table brazed to the substrate with an iron-nickel-based braze alloy;
wherein the iron-nickel-based braze alloy is at least partially infiltrated into the preformed polycrystalline diamond table and bonds the substrate to the preformed polycrystalline diamond table; and
wherein the iron-nickel-based braze alloy is depleted from a selected region of the preformed polycrystalline diamond table.
10. The superabrasive compact of claim 9 , wherein at least a majority of the iron-nickel-based braze alloy comprises iron.
11. The superabrasive compact of claim 9 , wherein the iron-nickel-based braze alloy is an Invar-type alloy.
12. The superabrasive compact of claim 9 , wherein the iron-nickel-based braze alloy comprises about 64% iron and about 36% nickel.
13. The superabrasive compact of claim 9 , wherein the performed polycrystalline diamond volume was initially formed with a catalyst and substantially all of the catalyst has been removed from the preformed polycrystalline diamond table.
14. The superabrasive compact of claim 9 , wherein the substrate comprises cobalt-cemented tungsten carbide.
15. The superabrasive compact of claim 9 , wherein the substrate is brazed to the preformed polycrystalline diamond table with the iron-nickel-based braze alloy in a high-pressure/high-temperature brazing process having a pressure of at least about 20 kilobar and a temperature of at least about 800° Celsius.
16. A polycrystalline diamond compact, comprising:
a substrate; and
a preformed polycrystalline diamond body bonded to the substrate, the preformed polycrystalline diamond body including an exterior surface, an interfacial surface located at least proximate to the substrate, and a plurality of bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond body further including,
a first region extending inwardly from the interfacial surface and including a metallic infiltrant disposed in at least a portion of the interstitial regions of the first region, the metallic infiltrant including at least one material selected from the group consisting of iron, nickel, and cobalt; and
a leached second region from which the metallic infiltrant has been leached, the leached second region extending inwardly from the exterior surface to a selected depth.
17. A polycrystalline diamond compact, comprising:
a substrate; and
a preformed polycrystalline diamond body bonded to the substrate, the preformed polycrystalline diamond body including an exterior surface, an interfacial surface located at least proximate to the substrate, and a plurality of bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond body further including,
a first region extending inwardly from the interfacial surface and including a metallic infiltrant disposed in at least a portion of the interstitial regions of the first region, the metallic infiltrant including at least one material selected from the group consisting of iron, nickel, and cobalt; and
a second region depleted of the metallic infiltrant, the second region extending inwardly from the exterior surface to a selected depth.
18. A polycrystalline diamond compact, comprising:
a cobalt-cemented carbide substrate; and
a preformed polycrystalline diamond table brazed directly to the cobalt-cemented carbide substrate by an iron-nickel-based braze alloy, the preformed polycrystalline diamond table including a first region including the iron-nickel-based braze alloy infiltrated therein and a second region depleted of the iron-nickel-based braze alloy.