Two-part borate, silicate and zinc compositions, and methods for treating wood products
View Patent ↗Systems and methods are provided for treating products containing wood fibers to provide protection against wood destroying organisms and fire, and resistance against leaching of the preservative from the wood by water in exposed environments such as exterior applications. The methods involve applying to a substrate a first aqueous composition containing a boron compound, a source of zinc, and ammonia, followed by application of a second aqueous composition containing an alkali metal silicate. The compositions may be applied by vacuum and/or pressure treatment or dip treatment under atmospheric pressure.
1. A preservative system comprising:
(a) a first aqueous composition comprising a source of zinc selected from the group consisting of zinc oxide and soluble zinc salts; a source of borate selected from the group consisting of zinc borate, boric acid, boric oxide and water soluble borate salts; a source of ammonia; and water; wherein the composition comprises at least 50 wt % water; and
(b) a second aqueous composition, separate from the first composition, comprising an alkali metal silicate and water.
2. The preservative system according to claim 1 , wherein the first and second compositions are essentially chloride ion free.
3. The preservative system according to claim 1 , wherein the first and second compositions are essentially copper-free.
4. The preservative system according to claim 1 , wherein the source of ammonia is ammonium hydroxide, the source of zinc is zinc chloride, the source of borate is sodium borate, and the alkali metal silicate is sodium silicate.
5. The preservative system according to claim 1 , wherein the source of borate is disodium octaborate tetrahydrate and the alkali metal silicate is sodium silicate having an SiO 2 :Na 2 O weight ratio greater than 3:1.
6. The preservative system according to claim 1 , wherein the first aqueous composition comprises from about 0.1 to about 1.0 weight percent boron, from about 0.2 to about 2.5 weight percent zinc, and from about 1 to about 5 weight percent ammonia, and wherein the second aqueous composition comprises between about 1 and about 10 wt % SiO 2 .
7. The preservative system according to claim 1 , wherein zinc and boron are present in the first aqueous composition in a mole ratio Zn:B between about 0.4:1 and 5:1.
8. The preservative system according to claim 1 , wherein zinc and boron are present in the first aqueous composition in a mole ratio Zn:B between about 1:1 and 3:1.
9. The preservative system according to claim 1 , wherein zinc and boron are present in the first aqueous composition in a mole ratio Zn:B between about 1.5:1 and 2:1.
10. The preservative system according to claim 1 , wherein silicon in the second aqueous composition and boron in the first aqueous composition are present in a mole ratio Si:B between about 0.2:1 and 0.3:1.
11. The preservative system according to claim 1 , wherein ammonia and zinc are present in the first aqueous composition in a mole ratio NH 3 :Zn between about 7:1 and 33:1.
12. A preservative system consisting of:
(a) a first aqueous composition consisting essentially of a source of zinc selected from the group consisting of zinc oxide and soluble zinc salts; a source of borate selected from the group consisting of zinc borate, boric acid, boric oxide and water soluble borate salts; a source of ammonia; and water; wherein the composition is essentially copper-free and comprises at least 50 wt % water; and
(b) a second aqueous composition, separate from the first composition, consisting essentially of an alkali metal silicate and water.
13. The preservative system of claim 12 , wherein the first and second compositions are essentially copper-free.