Use of polyalkyl (meth)acrylates in lubricating oil compositions
View Patent ↗The invention relates to the use of polyalkyl ester for reducing the temperature in a lubricating oil composition. The polyalkyl ester has a specific viscosity η sp/c of between 5 and 30 ml/g, measured in chloroform at 25° C.
1. A method of reducing the temperature in a lubricant oil composition, comprising:
adding 4.9 to 27 wt % of at least one polyalkyl ester having a specific viscosity η sp/c , measured at 25° C. in chloroform, of between 17 and 25 ml/g, to a lubricant oil composition,
wherein said lubricant oil composition is a class ISO 46 or ISO 68 fluid;
wherein the at least one polyalkyl ester is prepared by polymerization of a monomer composition which consists of
a) from 13 to 25% by weight of methylmethacrylate, based on the weight of the monomer composition, and
b) from 75 to 87% by weight of a C 12 -C 18 alkyl methacrylate, based on the weight of the monomer composition,
wherein the lubricant oil composition, by virtue of addition of said at least one polyalkyl ester, has a hydraulic performance P a at a temperature T 1 +x, where T 1 is greater than or equal to 20° C. and x is greater than or equal to 5° C., which is at least as high as the performance of the hydraulic line P b of the hydraulic fluid without addition of polyalkyl ester at the temperature T 1 ,
wherein said hydraulic performance P a is measured at temperatures of between 65 and 85° C.
2. A lubricant oil composition, comprising:
4.9 to 27 wt % of at least one polyalkyl ester prepared by polymerization of a monomer composition which consists of:
a) from 13 to 25% by weight of methylmethacrylate, based on the weight of the monomer composition,
b) from 75 to 87% by weight of a C 12 -C 18 alkyl methacrylate, based on the weight of the monomer,
the polyalkyl ester having a specific viscosity η sp/c , measured at 25° C. in chloroform, of between 17 and 25 ml/g,
wherein said lubricant oil composition is a class ISO 46 or ISO 68 fluid;
wherein the lubricant oil composition, by virtue of addition of said at least one polyalkyl ester, has a hydraulic performance P a at a temperature T 1 +x, where T 1 is greater than or equal to 20° C. and x is greater than or equal to 5° C., which is at least as high as the performance of the hydraulic line P b of the hydraulic fluid without addition of polyalkyl ester at the temperature T 1 ,
wherein said hydraulic performance P a is measured at temperatures of between 65 and 85° C.,
the temperature-dependent performance decline d(P a )/dT of the lubricant oil composition comprising said at least one polyalkyl ester being smaller than the temperature-dependent performance decline d(P b )/dT of the lubricant oil composition without polyalkyl ester.
3. The method of claim 1 , wherein the polyalkyl ester leads to an improvement in the hydraulic performance at elevated temperature.
4. The method of claim 3 , wherein the temperature is at least 60° C.
5. The method of claim 1 , wherein the polyalkyl ester delays overheating of the lubricant oil composition during elevated hydraulic performance.
6. The method of claim 1 , wherein the lubricant oil composition is a hydraulic fluid.
7. The method of claim 1 , wherein the lubricant oil composition has a kinematic viscosity, measured at 40° C., in the range from 10 to 120 mm 2 /s.
8. The method of claim 1 , wherein the lubricant oil composition has a viscosity index in the range from 120 to 350.
9. The method of claim 1 , wherein the lubricant oil composition comprises from 2 to 40% by weight of polyalkyl esters.
10. The method of claim 1 , wherein the lubricant oil composition comprises one or more additives selected from the group consisting of antioxidants, corrosion inhibitors, antifoams, antiwear components, dyes, dye stabilizers, detergents, pour point depressants and DI additives.
11. The method of claim 1 , wherein the lubricant oil composition is used in a vane pump, a gear pump, radial piston pump or an axial piston pump.
12. The method of claim 1 , wherein the lubricant oil composition is used at a pressure of from 150 to 320 bar.
13. The lubricant oil composition of claim 2 , wherein T 1 is in the range from 50 to 120° C.
14. The lubricant oil composition of claim 2 , wherein x is in the range from 10 to 90° C.
15. The lubricant oil composition of claim 2 , wherein the polyalkyl ester has a polydispersity M W /M n in the range from 1.2 to 4.0.
16. The lubricant oil composition of claim 2 , which is a hydraulic fluid.