Method for improving metals recovery using high temperature pressure leaching
View Patent ↗The present invention is directed to a system for recovering metal values from metal-bearing materials. During a reactive process, a seeding agent is introduced to provide a nucleation site for the crystallization and/or growth of solid species which otherwise tend to passivate the reactive process or otherwise encapsulate the metal value, thereby reducing the amount of desired metal values partially or completely encapsulated by such material. The seeding agent may be generated in a number of ways, including the recycling of residue or the introduction of foreign substances. Systems embodying aspects of the present invention may be beneficial for recovering a variety of metals such as copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals from any metal-bearing material, such as ores and concentrates.
1. A process for recovering a metal value comprising:
subjecting a metal-bearing material to a reactive process;
incorporating at least one seeding agent into said reactive process at a temperature greater than about 120° C.;
obtaining a product from said reactive process wherein at least one metal value is present in said product and wherein said metal value comprises at least one of copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metal, and platinum group metal; and
extracting said at least one metal value from said product using electrowinning.
2. A process for recovering a metal value according to claim 1 , wherein said at least one seeding agent comprises hematite.
3. A process for recovering a metal value according to claim 1 , wherein said seeding agent comprises at least a portion of a residue from said reactive process.
4. A process for recovering a metal value according to claim 3 , further comprising the step of recovering at least one metal present in said residue from said reactive process before using said residue as said seeding agent.
5. A process for recovering a metal value according to claim 4 , wherein said metal present in said residue is selected from the group consisting of copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals.
6. A process for recovering a metal value according to claim 1 , wherein said step of subjecting a metal-bearing material to a reactive process produces acid, and further comprising the step of utilizing at least a portion of the acid produced by said reactive process in a heap leaching operation or an agitated leaching operation.
7. A process for recovering a metal value according to claim 1 , wherein said step of extracting at least one metal value from said product comprises extracting at least one precious metal from said product.
8. A process for recovering a metal value according to claim 1 , wherein said step of extracting at least one metal value from said product comprises extracting gold from said product.
9. A process for recovering a metal value according to claim 1 , wherein said step of incorporating a seeding agent into said reactive process comprises incorporating a seeding agent into said reactive process at a temperature from about 170° C. to about 235° C.
10. A process for recovering a metal value according to claim 1 , wherein said step of subjecting a metal-bearing material to a reactive process comprises subjecting the metal-bearing material to leaching.
11. A process for recovering a metal value according to claim 1 , wherein said leaching process is accomplished with at least one of elevated pressure, elevated temperature, and acid addition.
12. A process for recovering a metal value comprising:
subjecting a metal-bearing material to a conditioning process;
subjecting said conditioning process product to a reactive process to liberate a metal value;
incorporating at least one seeding agent into said reactive process, wherein said seeding agent provides a nucleation site; and
extracting at least one metal value from said reactive process product using electrowinning.
13. A process for recovering a metal value according to claim 12 , wherein said step of subjecting a metal-bearing material to a conditioning process comprises subjecting the metal-bearing material to at least one of comminution, flotation, blending and slurry formation.
14. A process for recovering a metal value according to claim 12 , wherein said step of incorporating at least one seeding agent into said reactive process comprises the incorporation of a seeding agent, which nucleates a species other than the metal value.
15. A process for recovering a metal value according to claim 12 , wherein said step of incorporating at least one seeding agent into said reactive process comprises the incorporation of a seeding agent, which nucleates the metal value.
16. A process for recovering a metal value comprising:
subjecting a metal-bearing material to a separation process;
subjecting said separation process product to a reactive process to liberate a metal value;
incorporating at least one seeding agent into the reactive process wherein said seeding agent provides a nucleation site; and
extracting at least one metal value from said reactive process product using electrowinning.
17. A process for recovering a metal value according to claim 16 , wherein said step of subjecting a metal-bearing material to a separation process comprises subjecting the metal-bearing material to at least one of flash distillation, filtration, counter-current decantation circuits (CCD) and centrifuges.
18. A process for recovering a metal value according to claim 16 , wherein said step of incorporating at least one seeding agent into said reactive process comprises the incorporation of a seeding agent, which nucleates a species other than the metal value.
19. A process for recovering a metal value according to claim 16 , wherein said step of incorporating at least one seeding agent into said reactive process comprises the incorporation of a seeding agent, which nucleates the metal value.