Enhanced boron nitride composition and compositions made therewith
View Patent ↗A boron nitride composition having its surface treated with a coating layer comprising at least an organosilicon compound. In one embodiment, the boron nitride powder surface is first treated by either a calcination process, or by coating with at least an inorganic compound for the surface to have a plurality of reactive sites containing at least a functional group that is reactive to at least one functional group of the organosilicon compound.
1. A boron nitride composition comprising boron nitride powder, the boron nitride powder having its surface treated with at least an organosilicon compound having a formula selected from:
a. (RR′SiO—)n, where R, R′ are the same or different and selected from the group of H, alkyl, aryl and substituted aryl; n has a value ranging from 3-16 for cyclic compounds and 1 to 2 million for linear compounds; and
b. NH n (SiR 1 R 2 R 3 ) 3-n where R 1 , R 2 , R 3 is a hydrocarbyl group or H, n is 1 or 2.
2. The boron nitride composition of claim 1 , wherein the organosilicon compound is selected from the group of hexamethylcyclotrisiloxane (D 3 ), trimethylcyclotrisiloxane ((D 3 H ), octamethylcyclotetrasiloxane (D 4 ), tetramethylcyclotetrasiloxane (D 4 H ), decamethylcyclopentasiloxane (D 5 ), pentamethylcyclopentasiloxane (D 5 H ).
3. The boron nitride composition of claim 1 , wherein the organosilicon comprises NH n (SiR 1 R 2 R 3 ) 3-n where R 1 , R 2 , R 3 is a hydrocarbyl group or H, n is 1 or 2.
4. The boron nitride composition of claim 1 , wherein the boron nitride powder surface is first treated for the surface to have a plurality of reactive sites containing at least a functional group that is reactive to at least one functional group of the organosilicon compound.
5. The boron nitride composition of claim 1 , wherein the boron nitride powder is first treated by a calcination process.
6. The boron nitride composition of claim 1 , wherein the boron nitride powder is first treated by coating the boron nitride powder with an inorganic compound.
7. The boron nitride composition of claim 6 , wherein the boron nitride powder is first treated by coating the boron nitride powder with at least one of a metal oxide and hydroxide.
8. The boron nitride composition of claim 7 , wherein the boron nitride powder is first treated by coating the boron nitride powder with at least one of alumina, silica, zirconia, boria, titania, ceria, germania, tantalum oxide, cesium oxide, yttrium oxide, colloidal yttria, magnesia, thoria, phosphate, and mixtures thereof.
9. The boron nitride composition of claim 7 , wherein boron nitride powder is first treated by coating the boron nitride powder with 0.5 to about 10 wt. % of an inorganic compound selected from the group of metal oxides and hydroxides.
10. The boron nitride composition of claim 1 , wherein the boron nitride powder has an average particle size of at least 50 microns.
11. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises spherically shaped agglomerates of irregular non-spherical particles bound together by a binder and subsequently spray-dried.
12. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an aspect ratio of from about 50 to about 300.
13. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an average diameter of from about 2 μm to about 20 μm.
14. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises irregularly shaped agglomerates of hexagonal boron nitride platelets, having an average particle size of above 10 microns.
15. An article comprising the boron nitride composition of claim 1 .
16. A polymer composite comprising a polymer matrix selected from the group consisting of melt-processable polymers and cured polymers, and a filler material comprising particles of boron nitride, the boron nitride having its surface treated with at least an organosilicon compound selected from the group consisting of siloxanes and silazanes.
17. The polymer composite of claim 16 , wherein the polymer matrix is selected from the group of phenolics and epoxies.
18. The polymer composite of claim 16 , wherein the polymer matrix comprises a silicone resin.
19. The polymer composite of claim 16 , wherein the polymer matrix comprises at least one of a liquid crystal polymer; a polyester polyethylene terephthalate, polybutylene terephthalate; a polyamide; a polyimide; a polyphthalamide; a polyphenylene sulfide; a polycarbonate; a polyetheretherketone; apolyaryletherketone; a polyphenylene oxide; and a mixture thereof.
20. A method for producing boron nitride powder, comprising the steps of:
a. introducing a plurality of reactive sites on at least a portion of the boron nitride; and
b. coating the boron nitride with at least an organosilicon compound selected from the group of siloxanes and silazanes, wherein the organosilicon compound has at least a functional group that is reactive to at least one reactive site on the boron nitride.