Polycarbonate-polyester blends, methods of manufacture, and methods of use
View Patent ↗A composition comprising a blend of: from 1 to 99 weight percent of a polycarbonate comprising from 10 to 90 mole percent of one or more arylate carbonate units of the formula wherein each R f is independently a C 1-12 hydrocarbon, halogen, or halogen-substituted C 1-12 hydrocarbon, and u is 0 to 4; and from 10 to 90 mole percent of different carbonate units of the formula wherein at least 60% of the R 1 groups are C 6-30 aromatic groups, and from 1 to 99 weight percent of a polyester comprising units of the formula wherein T is a residue derived from a C 5 -C 7 cycloaliphatic or C 7 -C 12 aromatic dicarboxylic acid or a chemical equivalent thereof, and D is a residue derived from a C 6 -C 12 aromatic or C 2 -C 12 aliphatic diol or a chemical equivalent thereof, provided that at least 50 mole percent of D is derived from 1,4-cyclohexanedimethanol or a chemical equivalent thereof; and wherein the weight percent of the polycarbonate and the polyester are each based on the total weight of the polycarbonate and the polyester.
1. A composition comprising a blend of:
from 1 to 99 weight percent of a polycarbonate comprising
from 10 to 90 mole percent of one or more arylate carbonate units of the formula
wherein each R f is independently a halogen atom, a C 1-10 hydrocarbon or a halogen-substituted C 1-10 hydrocarbon and u is 0 to 4, and
from 10 to 90 mole percent of different carbonate units of the formula
wherein at least 60% of the R 1 groups are C 6-30 aromatic groups, and
from 1 to 99 weight percent of a polyester comprising units of the formula
wherein T is a residue derived from a C 5 -C 7 cycloaliphatic or C 7 -C 12 aromatic dicarboxylic acid or a chemical equivalent thereof, and D is a residue derived from a C 6 -C 12 aromatic or C 2 -C 12 aliphatic diol or a chemical equivalent thereof, provided that at least 50 mole percent of D is derived from 1,4-cyclohexanedimethanol or a chemical equivalent thereof; and wherein
the weight percent of the polycarbonate and the polyester are each based on the total weight of the polycarbonate and the polyester.
2. The composition of claim 1 , wherein a sample having a thickness of 2.5 mm has a luminous transmittance which exceeds 60%, measured in accordance with ASTM D 1003.
3. The composition of claim 1 , wherein the blend has an improved Notched Izod impact value compared to the Notched Izod value of the polycarbonate and the polyester alone, each measured in accordance with ISO 180 at 23° C.
4. The composition of claim 1 , wherein the polycarbonate comprises from 20 to 80 mole percent of the carbonate units of the formula
wherein R 1 is derived from a bisphenol of the formula
wherein R a and R b are each independently a halogen or a C 1-12 alkyl, X a is a C 1-18 alkylene, a C 1-8 alkylidene, a C 3-18 cycloalkylidene, or a C 9-18 fused cycloalkylidene-aromatic group, and p and q are each independently 0 to 4.
5. The composition of claim 1 , wherein the polycarbonate is a terpolymer that consists essentially of 10 to 40 mole percent of arylate carbonate units wherein u is 0; from 10 to 40 mole percent of arylate carbonate units wherein R f is methyl and u is one; and from 20 to 40 mole percent mole percent of the carbonate units of the formula
wherein R 1 is derived from a bisphenol of the formula
wherein R a and R b are each independently a halogen or a C 1-12 alkyl, X a is a C 1-18 alkylene, a C 1-18 alkylidene, a C 3-18 cycloalkylidene, or a C 9-18 fused cycloalkylidene-aromatic group, and p and q are each independently 0 to 4.
6. The composition of claim 5 , wherein X a is isopropylidene and p and q is each zero.
7. The composition of claim 1 , wherein T is a residue derived from a cycloaliphatic dicarboxylic acid, and wherein the blend has an improved Notched Izod impact value, measured in accordance with ISO-180 at 23° C., as compared to a Notched Izod impact value of the polycarbonate or the polyester alone.
8. The composition of claim 5 , comprising 20 to 60 weight percent of the polyester, wherein T is a residue derived from a cycloaliphatic dicarboxylic acid, and wherein the blend retains at least 50% of its Notched Izod value, measured in accordance with ISO-180 at 23° C., after heat aging at 90° C. for 15 hours.
9. The composition of claim 5 , comprising 35 to 45 weight percent of the polyester, wherein T is a residue derived from a cycloaliphatic dicarboxylic acid, and wherein the blend retains at least 50% of its Notched Izod value, measured in accordance with ISO-180 at 23° C., after heat aging at 90° C. for 15 hours.
10. The composition of claim 1 , wherein T is a residue derived from an aromatic dicarboxylic acid, optionally in combination with a different aliphatic or aromatic dicarboxylic acid or equivalent thereof, and D further comprises a residue derived from a C 2-4 diol, and wherein the blend has an improved Notched Izod impact value compared to the Notched Izod value of the polycarbonate and the polyester alone, each measured in accordance with ISO-180 at 23° C.
11. The composition of claim 5 , comprising 15 to 35 weight percent of the polyester, wherein T is a residue derived from an aromatic dicarboxylic acid, optionally in combination with a different aliphatic or aromatic dicarboxylic acid or equivalent thereof, and D further comprises a residue derived from a C 2-4 diol, and wherein the blend retains at least 50% of its Notched Izod value, measured in accordance with ISO-180 at 23° C., after heat aging at 90° C. for 15 hours.
12. The composition of claim 1 , wherein T is a residue derived from an aromatic dicarboxylic acid, and wherein the blend has an improved Notched Izod value as compared to the Notched Izod value of the polycarbonate and the polyester alone, each measured in accordance with ISO-180 at 23° C.
13. The composition of claim 5 , comprising 15 to 50 weight percent of the polyester, wherein T is a residue derived from an aromatic dicarboxylic acid, and wherein the blend retains at least 50% of its Notched Izod value, measured in accordance with ISO-180 at 23° C., after heat aging at 90° C. for 15 hours.
14. The composition of claim 5 , wherein T is a residue derived from an aromatic dicarboxylic acid or equivalent thereof, and wherein the blend has a Notched Izod impact value of 20 or greater, measured in accordance with ISO 180 at 0° C.
15. The composition of claim 1 , wherein T is derived from cyclohexane dicarboxylic acid and D is derived from 1,4-cyclohexanedimethanol.
16. The composition of claim 1 , wherein T is derived from a mixture of terephthalic acid and isophthalic acid and D is derived from 1,4-cyclohexanedimethanol.
17. The composition of claim 1 , wherein T is derived from a mixture of terephthalic acid and isophthalic acid and D further comprises up to 50 mole percent of a residue derived a C 2-4 diol.
18. The composition of claim 1 , wherein u is zero.
19. The composition of claim 1 , wherein u is 1 and R f is a methyl.
20. The composition of claim 1 , comprising arylate units wherein u is 1 and R f is a methyl, and arylate units wherein u is zero.
21. The composition of claim 1 , wherein the arylate unit linkages are para to one another.
22. The composition of claim 1 , wherein the arylate carbonate units are derived from 5-methyl resorcinol, 5-ethyl resorcinol, 5-propyl resorcinol, 5-butyl resorcinol, 5-t-butyl resorcinol, 5-phenyl resorcinol, 5-cumyl resorcinol, 2,4,5,6-tetrafluoro resorcinol, 2,4,5,6-tetrabromo resorcinol, catechol, hydroquinone; 2-methyl hydroquinone, 2-ethyl hydroquinone, 2-propyl hydroquinone, 2-butyl hydroquinone, 2-t-butyl hydroquinone, 2-phenyl hydroquinone, 2-cumyl hydroquinone, 2,5-di-t-butylhydroquinone, 2,3,5-trimethylhydroquinone, 2,3,5,6-tetramethyl hydroquinone, 2,3,5,6-tetra-t-butyl hydroquinone, 2,3,5,6-tetrafluoro hydroquinone, 2,3,5,6-tetrabromo hydroquinone, or a combination comprising at least one of the foregoing compounds.
23. The composition of claim 1 , further comprising an antioxidant, a thermal stabilizer, a light stabilizers, an ultraviolet light absorbing additive, a quencher, a plasticizer, a lubricant, a mold release agent, an antistatic agents, a dye, a pigment, a filler, a light effect additive, a flame retardant, an anti-drip agent, a radiation stabilizer, or a combination comprising at least one of the foregoing additives.
24. The composition of claim 1 , further comprising of 2 to 30 weight percent of an impact modifier, based on the total weight of the composition.
25. The composition of claim 24 , wherein the impact modifier is a natural rubber, a low-density polyethylene, a high-density polyethylene, a polypropylene, a polystyrene, a polybutadiene, a styrene-butadiene copolymer, a styrene-butadiene-styrene (SBS), styrene-butadiene rubber (SBR), styrene-ethylene-butadiene-styrene (SEBS), acrylonitrile-butadiene-styrene (ABS), acrylonitrile-ethylene-propylene-diene-styrene (AES), styrene-isoprene-styrene (SIS), methyl methacrylate-butadiene-styrene (MBS), a styrene-acrylonitrile (SAN), an ethylene-propylene copolymer, an ethylene-propylene-diene terpolymer, an ethylene-methyl acrylate copolymer, an ethylene-ethyl acrylate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-glycidyl methacrylate copolymer, a polyethylene terephthalate-poly(tetramethyleneoxide)glycol block copolymer, a polyethylene terephthalate/isophthalate-poly(tetramethyleneoxide)glycol block copolymer, a silicone rubber, or a combination comprising at least one of the foregoing impact modifiers.
26. An article comprising the composition of claim 1 .
27. The article of claim 26 , wherein the article is an extruded or injection molded article.
28. The article of claim 26 , in the form of a component of a household appliance.
29. A method of forming an article, comprising shaping, extruding, blow molding, or injection molding the composition of claim 1 to form the article.
30. A method of forming a composition, comprising blending the components of the composition of claim 1 .
31. A composition comprising a blend of:
from 20 to 80 weight percent of a polycarbonate consisting of
from 20 to 80 mole percent of one or more arylate carbonate units of the formula
wherein each R f is independently methyl, and u is 0 to 2; and
from 20 to 80 mole percent of different carbonate units of the formula
wherein R 1 is derived from bisphenol A; and
from 20 to 80 weight percent of poly(1,4-cyclohexane-dimethanol-1,4-dicarboxylate), poly(cyclohexanedimethylene terephthalate)-co-poly(ethylene terephthalate) wherein greater than 50 mol % of the ester groups are derived from 1,4-cyclohexanedimethanol, or poly(cyclohexanedimethanol terephthalate); wherein
the weight percent of the polycarbonate and the polyester are each based on the total weight of the polycarbonate and the polyester; and wherein
the blend has an improved Notched Izod impact value compared to the Notched Izod value of the polycarbonate and the polyester alone, each measured in accordance with ISO-180 at 23° C.
32. A composition comprising a blend of:
from 20 to 80 weight percent of a polycarbonate consisting of
from 20 to 40 mole percent of one or more arylate carbonate units of the formula
wherein R f is methyl and u is 1,
from 20 to 40 mole percent of arylate carbonate units of the formula
wherein u is 0, and
from 20 to 80 mole percent of different carbonate units of the formula
wherein R 1 is derived from bisphenol A; and
from 20 to 80 weight percent of poly(1,4-cyclohexane-dimethanol-1,4-dicarboxylate), poly(cyclohexanedimethylene terephthalate)-co-poly(ethylene terephthalate) wherein greater than 50 mol % of the ester groups are derived from 1,4-cyclohexanedimethanol, or poly(cyclohexanedimethanol terephthalate; wherein
the weight percent of the polycarbonate and the polyester are each based on the total weight of the polycarbonate and the polyester; and wherein
the blend has an improved Notched Izod impact value compared to the Notched Izod value of the polycarbonate and the polyester alone, each measured in accordance with ISO-180 at 23° C.