Weatherable resinous compositions with low heat storage and method
View Patent ↗Disclosed are resinous compositions comprising a colorant combination comprising at least one inorganic infrared reflecting pigment and at least one organic colorant, wherein the combination of inorganic pigment and organic colorant results in a molded part with an L* value of less than about 30 with specular component included, and a heating build-up (HBU) as measured according to ASTM D4803-89 of less than about 34° C. A method to make such compositions is also an embodiment of the invention as are articles made from such compositions.
1. A weatherable composition comprising: (i) at least one resin selected from the group consisting of (i-a1) an acrylonitrile-styrene-acrylate (ASA) graft copolymer, (i-a2) an acrylate-modified ASA, (i-b1) a copolymer comprising carbonate structural units derived from bisphenol A and ester structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol, (i-b2) a copolymer comprising carbonate structural units derived from bisphenol A and dimethyl siloxane structural units, (i-c1) a blend comprising a bisphenol-A polycarbonate and a polyester selected from the group consisting of poly(butylene terephthalate), poly(ethylene terephthalate), poly(cyclohexanedimethanol-ethylene glycol terephthalate), poly(cyclohexylenedimethylene-cyclohexanedicarboxylate), and a polyester with structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol; and (i-c2) a blend comprising a bisphenol-A polycarbonate and a rubber modified thermoplastic resin selected from the group consisting of ABS, ASA, and MMA-ASA; and
(ii) a colorant combination consisting of an inorganic infrared reflecting pigment and at least two organic colorants, wherein the inorganic infrared reflecting pigment is selected from the group consisting of a chromium iron oxide, a black spinel, and chrome iron nickel black spinel, and is present in an amount greater than or equal to about 0.02 parts per hundred parts resinous components by weight (phr),
and wherein the organic colorants consist of Solvent Green 3, Solvent Red 135, and optionally at least one colorant selected from the group consisting of Solvent Violet 13, Pigment Blue 15:4, Pigment Black 31, and Disperse Violet 31/26, wherein the organic colorants are present in a total amount greater than or equal to about 0.002 phr;
and wherein the combination of the inorganic pigment and organic colorant results in a molded part with a heating build-up (HBU) as measured according to ASTM D4803-89 of less than or equal to about 34° C. and an L* value of less than about 30 with specular component included or less than about 20 with specular component excluded.
2. The composition of claim 1 , wherein the composition containing the ASA or acrylate-modified ASA resin further contains a copolymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate.
3. The composition of claim 1 , further comprising an additive selected from the group consisting of lubricants, neutralizers, stabilizers, heat stabilizers, light stabilizers, antioxidants, UV screeners, UV absorbers, and mixtures thereof.
4. An article made from the composition of claim 1 .
5. A method for preparing a weatherable article comprising at least one resin selected from the group consisting of (i-a1) an acrylonitrile-styrene-acrylate (ASA) graft copolymer, (i-a2) an acrylate-modified ASA, (i-b1) a copolymer comprising carbonate structural units derived from bisphenol A and ester structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol, (i-b2) a copolymer comprising carbonate structural units derived from bisphenol A and dimethyl siloxane structural units, (i-c1) a blend comprising a bisphenol-A polycarbonate and a polyester selected from the group consisting of poly(butylene terephthalate), poly(ethylene terephthalate), poly(cyclohexanedimethanol-ethylene glycol terephthalate), poly(cyclohexylenedimethylene-cyclohexanedicarboxylate) , and a polyester with structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol; and (i-c2) a blend comprising a bisphenol-A polycarbonate and a rubber modified thermoplastic resin selected from the group consisting of ABS, ASA, and MMA-ASA, wherein the article has a heating build-up (HBU) as measured according to ASTM D4803-89 of less than or equal to about 34° C. and an L* value of less than about 30 with specular component included or less than about 20 with specular component excluded;
which method comprises the step of combining the resin with a colorant combination consisting of an inorganic infrared reflecting pigment and at least two organic colorants, wherein the inorganic infrared reflecting pigment is selected from the group consisting of a chromium iron oxide, a black spinel, and chrome iron nickel black spinel, and is present in an amount greater than or equal to about 0.02 phr;
and wherein the organic colorants consist of Solvent Green 3, Solvent Red 135, and optionally at least one colorant selected from the group consisting of Solvent Violet 13, Pigment Blue 15:4, Pigment Black 31, and Disperse Violet 31/26, wherein the organic colorants are present in a total amount greater than or equal to about 0.002 phr.
6. The method of claim 5 , wherein the composition containing the ASA or acrylate-modified ASA resin further contains a copolymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate.
7. The method of claim 5 , further comprising an additive selected from the group consisting of lubricants, neutralizers, stabilizers, heat stabilizers, light stabilizers, antioxidants, UV screeners, UV absorbers, and mixtures thereof
8. The composition of claim 2 , wherein the copolymer comprises structural units derived from alpha-methyl styrene.
9. The method of claim 6 , wherein the copolymer comprises structural units derived from alpha-methyl styrene.
10. A weatherable composition consisting essentially of: (i) at least one resin selected from the group consisting of (i-a1) an acrylonitrile-styrene-acrylate (ASA) graft copolymer, (i-a2) an acrylate-modified ASA, (i-b1) a copolymer comprising carbonate structural units derived from bisphenol A and ester structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol, (i-b2) a copolymer comprising carbonate structural units derived from bisphenol A and dimethyl siloxane structural units, (i-c1) a blend comprising a bisphenol-A polycarbonate and a polyester selected from the group consisting of poly(butylene terephthalate), poly(ethylene terephthalate), poly(cyclohexanedimethanol-ethylene glycol terephthalate), poly(cyclohexylenedimethylene-cyclohexanedicarboxylate) , and a polyester with structural units derived from a mixture of isophthalic acid, terephthalic acid, and resorcinol; and (i-c2) a blend comprising a bisphenol-A polycarbonate and a rubber modified thermoplastic resin selected from the group consisting of ABS, ASA, and MMA-ASA;
(ii) a colorant combination consisting of an inorganic infrared reflecting pigment and at least two organic colorants, wherein the inorganic infrared reflecting pigment is selected from the group consisting of a chromium iron oxide, a black spinel, and chrome iron nickel black spinel, and is present in an amount greater than or equal to about 0.02 parts per hundred parts resinous components by weight (phr), and wherein the organic colorants consist of Solvent Green 3, Solvent Red 135, and optionally at least one colorant selected from the group consisting of Solvent Violet 13, Pigment Blue 15:4, Pigment Black 31, and Disperse Violet 31/26, wherein the organic colorants are present in a total amount greater than or equal to about 0.002 phr;
and wherein the combination of the inorganic pigment and organic colorant results in a molded part with a heating build-up (HBU) as measured according to ASTM D4803-89 of less than or equal to about 34° C. and an L* value of less than about 30 with specular component included or less than about 20 with specular component excluded; and
(iii) an additive selected from the group consisting of lubricants, neutralizers, stabilizers, heat stabilizers, light stabilizers, antioxidants, UV screeners, UV absorbers, and mixtures thereof;
wherein any composition containing the ASA or acrylate-modified ASA resin may optionally further contain (iv) a copolymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate.
11. The composition of claim 1 , wherein the total amount of organic colorant present is in a range of 0.002-2.5 phr.
12. The method of claim 5 , wherein the total amount of organic colorant present is in a range of 0.002-2.5 phr.
13. The composition of claim 10 , wherein the total amount of organic colorant present is in a range of 0.002-2.5 phr.
14. The composition of claim 1 , wherein the total amount of IRR pigment present is in a range of 0.04-4.0 phr
15. The method of claim 5 , wherein the total amount of IRR pigment present is in a range of 0.04-4.0 phr.
16. The composition of claim 10 , wherein the total amount of IRR pigment present is in a range of 0.04-4.0 phr.