MONOAXIALLY ORIENTED POLYPROPYLENE FILM WITH HIGH TRANSVERSE TEAR PROPAGATION RESISTANCE
Backing film which comprises at least one polypropylene and has been longitudinally monoaxially oriented, characterized in that at least one nucleating agent has been inhomogeneously distributed in the backing film.
1 . Backing film, which comprises at least one polypropylene and which is longitudinally monoaxially oriented, and wherein at least one nucleating agent is inhomogeneously distributed in the backing film.
2 . Backing film, according to claim 1 , wherein the haze of the backing film is at least 40%, or its gloss is less than 60%, or wherein its haze is at least 40% and its gloss is less than 60%.
3 . Backing film according to claim 1 wherein the backing film has been longitudinally oriented with a stretching ratio of at least 1:8.
4 . Backing film according to claim 1 , wherein the longitudinal tensile strength of the backing film is at least 300 N/mm 2 or its transverse tear propagation resistance, based on the film thickness, is at least 450 N/mm 2 , or wherein the backing film has both said tensile strength and said tear propagation resistance.
5 . Backing film according to claim 1 , wherein the value for longitudinal tensile stress at 1% tensile strain of the backing film is at least 20 N/mm 2 or its value for longitudinal tensile stress at 10% tensile strain is at least 250 N/mm 2 or both.
6 . Backing film according to claim 1 , wherein the thickness of the backing film is from 25 to 200 μm.
7 . Backing film according to claim 1 , wherein the backing film comprises a polypropylene whose melt index is from 0.3 to 15 g/10 min or whose flexural modulus is at least 1000 MPa or which has both said melt index and said flexural modulus.
8 . Backing film according to claim 1 , wherein the structure of the polypropylene is mainly isotactic.
9 . Backing film according to claim 1 , wherein the backing film is composed of a mixture of a nucleated and a non-nucleated polypropylene.
10 . Backing film according to claim 1 , wherein the nucleating agent is selected from the group consisting of magnesium hydroxide, talc, kaolin, titanium dioxide and silica gel, or is an organic nucleating agent, or is a semicrystalline branched or coupled polymeric nucleating agent.
11 . Process for producing the backing film of claim 1 , comprising the following steps:
polymers and additives are mixed and, in an extruder, introduced into a flat-film die, the extruder providing non-homogeneous mixing of the nucleating agent with the polypropylene,
the melt film is then subjected to controlled cooling on a chill roll,
before the film is introduced into the stretching unit, it is heated by way of temperature-controlled rolls,
the film is oriented in a narrow-gap system in the machine direction.
12 . An adhesive tape having single- or double-side adhesion and the backing film of claim 1 .
13 . A method for reinforcement of cartons, which comprises reinforcing said cartons with a backing film of claim 1 .
14 . The backing film of claim 2 , wherein said haze is at least 45% and said gloss is less than 40%.
15 . The backing film of claim 3 , wherein said stretching ratio is at least 1:9.5.
16 . The backing film of claim 4 , wherein said longitudinal tensile strength is at least 350 N/mm 2 .
17 . The backing film of claim 5 , wherein said longitudinal tensile stress at 1% tensile strain of the backing film is at least 40 N/mm 2 and said value for longitudinal tensile stress at 10% tensile strain is at least 300 N/mm 2 .
18 . The backing film of claim 6 , wherein said thickness is from 50 to 90 μm.
19 . The backing film of claim 7 , wherein said melt index is from 0.8 to 5 g/10 min and said flexural modulus is at least 2000 MPa.
20 . The backing film of claim 10 , wherein said nucleating agent is an organic nucleating agent, and said organic nucleating agent is a benzoate, phosphate, or a sorbitol derivative.