UV curable compositions
View Patent ↗The present invention provides a UV curable composition comprising an acrylate component, comprising an acrylate-functionalized hydrogenated polybutadiene, and at least one mono-functional acrylate, and a photoinitiator combination triggered upon exposure to radiation at 365 nm of the electromagnetic spectrum comprising a bisacyl phosphine oxide and benzophenone, where when dispensed at a thickness of about 1 mm and exposed to UV radiation generated at a wavelength of 365 nm the composition cures through the thickness of the dispensed composition at a speed between 40 mm/sec to 100 mm/sec.
1. A UV curable composition comprising:
a acrylate component, comprising an acrylate-functionalized hydrogenated polybutadiene and at least one mono-functional (meth)acrylate,
a combination of bisacyl phosphine oxide present in an amount between about 1.5 and about 4 weight percent and benzophenone present in an amount between about 0.01 and about 1 weight percent, wherein when dispensed at a thickness of about 1 mm and exposed to radiation at a wavelength of 365 nm at an intensity of between about 120 to about 130 mW/cm 2 the composition cures through the thickness of the dispensed composition at a speed between 40 mm/sec to 100 mm/sec.
2. The composition of claim 1 , wherein the amount of benzophenone relative to bisacyl phosphine oxide is in the range of 0.005 to 0.25.
3. The composition of claim 2 , wherein the cure speed is 40 mm/sec.
4. The composition of claim 1 , wherein the amount of benzophenone relative to bisacyl phosphine oxide is in the range of 0.025 to 0.5.
5. The composition of claim 4 , wherein the cure speed is 100 mm/sec.
6. The composition of claim 1 , wherein the acrylate-functionalized hydrogenated polybutadiene has a molecular weight of about 3,000.
7. The composition of claim 1 , wherein the mono-functional (meth)acrylate is selected from the group consisting of 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, pentaerythritol triacrylate, 4-hydroxybutyl acrylate, isobornyl acrylate, cyclohexyl acrylate, tetrahydrofurfuryl acrylate, t-butylaminoethyl acrylate, cyanoethylacrylate, chloroethyl (meth)acrylate and lauryl acrylate and their corresponding mono-functional (meth)acrylates.
8. A method of curing at 365 nm at an intensity of between about 120 to about 130 mW/cm 2 using an LED a UV curable composition at cure speeds within the range of about 40 mm/sec to about 100 mm/sec, comprising the steps of:
a) dispensing onto a substrate a UV curable composition comprising an acrylate component, comprising an acrylate-functionalized hydrogenated polybutadiene and at least one mono-functional (meth)acrylate, bisacyl phosphine oxide and benzophenone, wherein the bisacyl phosphine oxide is present in an amount between about 1.5 and about 4 weight percent and the benzophenone is present in an amount between about 0.01 and about 1 weight percent; and
b) exposing the UV curable composition to UV radiation at a wavelength of 365 nm at an intensity of between about 120 to about 130 mW/cm 2 using an LED, such that the UV curable composition cures at cure speeds within the range of about 40 mm/sec to about 100 mm/sec.