LED with improved light emission profile
View Patent ↗An LED includes a substrate, a first electrode layer and a thin colloidal layer located between the substrate and the first electrode layer. A smoothening layer or particles located within or on the colloidal layer is provided so that the roughness of the outer surface of the colloidal layer which is facing towards the first electrode layer is R a ≦30 nm and R a ≧1 nm.
1. A light emitting diode (LED) comprising:
a substrate;
an electrode layer;
a colloidal layer located between the substrate and the electrode layer, the colloidal layer including colloidal particles; and
smoothing means including smoothing particles located between the colloidal particles and in contact with the substrate and between the colloidal layer and the electrode layer so that an outer surface of the colloidal layer facing the electrode layer has a roughness R a ≦30 nm and R a ≧1 nm, wherein the smoothing particles are smaller than the colloidal particles.
2. The LED as claimed in claim 1 , wherein the smoothing means has a refractive index of ≧1.1 and ≦3.0.
3. The LED as claimed in claim 1 , wherein the smoothing means comprise at least one smoothing layer which is located on the colloidal layer, and wherein a ratio between the thickness of the smoothing layer and the thickness of the colloidal layer is ≧0.9:1 and ≦5:1.
4. The LED as claimed in claim 1 , wherein the smoothing layer is provided on the colloidal layer by means of chemical vapor deposition (CVD).
5. The LED as claimed in claim 1 , wherein the smoothing layer comprises a material chosen from the group comprising TiO 2 , TiC, TiN, Ti(C,N), SiO 2 , B 2 O 3 , Al 2 O 3 , GeO 2 , Rb 2 O, Ga 2 O 3 , HfO 2 , Ta 2 O 5 , ZrO 2 , SiN x or mixtures thereof.
6. The LED as claimed in claim 1 , wherein the smoothing means comprises smoothing particles which are located at least one of within the colloidal layer and between the colloidal layer and the electrode layer, the smoothing particles being preferably produced by means of sol-gel methods, preferably starting with reactive metal organic compounds.
7. The LED as claimed in claim 1 , wherein the smoothing particles have an average particle size of ≧5 nm and ≦50 nm.
8. The LED as claimed in claim 1 , wherein the smoothing means comprise smoothing particles which have a refractive index which is different from a refractive index of particles in the colloidal layer, preferably a difference of ≧|0.3| and ≦|3|.
9. The LED as claimed in claim 1 , wherein the smoothing means comprise smoothing particles which comprise a metal oxide material chosen from the group comprising TiO 2 , TiC, TiN, ZrO 2 , ZnO, SbSnO, InSnO, Sb 2 O 5 , Al 2 O 3 or mixtures thereof, and/or an organic material.
10. A system comprising a LED as claimed in claim 1 , for use in:
household applications,
shop lighting,
home lighting,
accent lighting,
spot lighting,
theater lighting,
fiber-optics applications,
projection lighting,
self-lit displays,
pixel displays,
segmented displays,
warning signs,
medical lighting applications,
indicator signs, and
decorative lighting.
11. The LED of claim 1 , wherein the smoothing particles have an average particle size of 10 nm, and the colloidal particles having an average particle size of 200 nm.
12. The LED of claim 1 , wherein an average particle size of the colloidal particles is 20 times larger than an average particle size of the smoothing particles of the smoothing means.
13. The LED of claim 1 , wherein the smoothing means has a refractive index which is equal to or higher than a refractive index of a luminescent layer of the LED.
14. The LED of claim 13 , wherein the refractive index of the smoothing particles is different from the refractive index of the luminescent layer by a difference of ≧|0.5| and ≦|2.5|.
15. The LED of claim 1 , wherein the smoothing means reduce a half-width of an emission band of the LED.
16. The LED of claim 1 , wherein the smoothing means reduce a half-width of an emission band of the LED by 10 nm to 30 nm.
17. A light emitting diode (LED) comprising:
a substrate;
an electrode layer;
a colloidal layer located between the substrate and the electrode layer, the colloidal layer including colloidal particles; and
smoothing particles located within the colloidal layer and between the colloidal particles and in contact with the substrate so that an outer surface of the colloidal layer facing the electrode layer has a roughness R a ≦30 nm and
R a ≧1 nm, wherein the smoothing particles are smaller than the colloidal particles.
18. The LED of claim 17 , wherein the smoothing particles form a smoothing layer which is located on the colloidal layer, and wherein a ratio between a thickness of the smoothing layer and a thickness of the colloidal layer is ≧0.9:1 and ≦5:1, and a ratio between an average particle size of the smoothening particles and an average particle size of the colloidal particles is ≧1:20 and ≦1:10.
19. The LED of claim 17 , wherein an average particle size of the colloidal particles is 20 times larger than an average particle size of the smoothing particles.
20. The LED of claim 17 , wherein a ratio between an average particle size of the smoothening particles and an average particle size of the colloidal particles is ≧1:30 and ≦1:2.