Method for the purification of (meth)acrylic acid
View Patent ↗The present invention relates to a process for production of (meth)acrylic acid, whereby first a crude (meth)acrylic acid is produced and this crude (meth)acrylic acid is then continuously purified, whereby the continuous purification of the crude (meth)acrylic acid comprises the following process steps: a) in a composition comprising (meth)acrylic acid and impurities, precipitating the impurities in crystalline form from the composition; and b) separating the crystalline impurities precipitated from the composition. The invention also relates to the (meth)acrylic acid obtainable by this process, a device for production of (meth)acrylic acid, the use of the device or of a purification device for production of (meth)acrylic acid, (meth)acrylic acid, water-absorbing polymers, the use of water-absorbing polymers as well as fibers, sheets, foams and composites.
1. A process for production of (meth)acrylic acid, whereby first a crude (meth)acrylic acid is produced and this crude (meth)acrylic acid is then continuously purified, wherein the continuous purification of the crude (meth)acrylic acid comprises the following process steps:
a) in a composition comprising (meth)acrylic acid and impurities, precipitating the impurities from the composition in crystalline form wherein the impurity comprises maleic acid anhydride, and wherein the maleic acid anhydride is hydrolyzed to a portion of at least about 50 mol %, based on the total amount of the maleic acid anhydride comprised in the composition before the staff of the hydrolysis, with formation of maleic acid and/or fumaric acid, wherein maleic acid and/or fumaric acid precipitate in crystalline form from the composition;
b) separating the crystalline maleic acid and/or fumaric acid precipitated from the composition.
2. The process according to claim 1 , wherein the hydrolysis of the maleic acid anhydride in process step a) occurs over a time period in a range from about 1 to about 250 hours at a temperature in a range from about 70 to about 130° C.
3. The process according to claim 1 , wherein the composition is (meth)acrylic acid crystals in at least partially melted form or the mother liquor, which are obtained in step B or in step D of a process which comprises the following process steps:
A) crystallization of (meth)acrylic acid from an impure crude (meth)acrylic acid stream from a process for production of (meth)acrylic acid with formation of a crystal suspension by means of a first suspension generator;
B) separation of the (meth)acrylic acid crystals from the crystal suspension by means of a first separating device, whereby a mother liquor is retained; as well as optionally
C) renewed crystallization of (meth)acrylic acid from the first mother liquor obtained from step B) with formation of a second crystal suspension by means of a second suspension generator;
D) separation of the (meth)acrylic acid crystals obtained in step C) from the second crystal suspension by means of a further separating device, whereby a second mother liquor is retained.
4. The process according to claim 1 , wherein the composition is crystal suspension in at least partially melted form which is obtained in process step A or step C of a process which comprises the following process steps:
A) crystallization of (meth)acrylic acid from an impure crude (meth)acrylic acid stream from a process for production of (meth)acrylic acid with formation of a crystal suspension by means of a first suspension generator;
B) separation of the (meth)acrylic acid crystals from the crystal suspension by means of a first separating device, whereby a mother liquor is retained; as well as optionally
C) renewed crystallization of (meth)acrylic acid from the first mother liquor obtained from step B) with formation of a second crystal suspension by means of a second suspension generator;
D) separation of the (meth)acrylic acid crystals obtained in step C) from the second crystal suspension by means of a further separating device, whereby a second mother liquor is retained.