INDIUM-TIN MIXED OXIDE POWDER
Indium-tin mixed oxide powder which consists of primary particle aggregates and contains 50 to 90% by weight indium oxide, calculated as In 2 O 3 , and 10 to 50% by weight tin oxide, calculated as SnO 2 . It is produced by atomising a solution of an inorganic indium compound and an organic tin compound and burning it in a flame. It may be used for the production of electrically conductive paints and coatings, solar cells and IR and UV absorbers and in medical technology.
1 - 10 . (canceled)
11 . An indium-tin mixed oxide powder, characterised in that it consists of primary particle aggregates and contains 50 to 90° by weight indium oxide, calculated as In 2 O 3 , and 10 to 50% by weight tin oxide, calculated as SnO 2 .
12 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it contains 60 to 85% by weight indium oxide, calculated as In 2 O 3 , and 5 to 40% by weight tin oxide, calculated as SnO 2 .
13 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it contains less than 0.3% by weight carbon.
14 . The indium-tin mixed oxide powder according to claim 12 , characterised in that it contains less than 0.3% by weight carbon.
15 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it contains up to 3% by weight, based on the total amount of powder, of one or more or metals and/or metal oxides as doping component.
16 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it has an average aggregate area of 1500 to 4500 nm 2 , an average equivalent diameter (ECD) of 30 to 70 nm and an average aggregate diameter of 200 to 600 nm.
17 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it has an average minimum diameter of 30 to 70 nm and average maximum diameter of 60 to 120 nm.
18 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it has a BET specific surface area of 30 to 70 m 2 /g.
19 . The indium-tin mixed oxide powder according to claim 11 , characterised in that it shows only one indium oxide phase in X-ray analysis.
20 . A process for producing the indium-tin mixed oxide powder according to claim 11 , characterised in that, as the indium oxide precursor, an inorganic indium compound, which contains no Chlorine atoms, dissolved in a mixture of water and a solvent selected from the group consisting of C 1 to C 6 alcohols, C 1 to C 6 diols and/or C 1 to C 6 glycolmonoalkylethers, wherein the pH of the solution is optionally adjusted to a value of 3≧pH≧1 using an acid, and, as the tin oxide precursor, an organic tin compound, dissolved in at least one solvent selected from the group consisting of C 1 to C 6 alcohols, C 1 to C 6 diols, C 1 to C 6 glycolmonoalkylethers and/or C t C t carboxylic acid, said process comprising the steps of:
combining said indium oxide precursor and said tin oxide precursor to form a precursor solution, the respective precursor content in the combined solution being not more than 20% by weight of indium and tin, based on In 2 O 3 and SnO 2 , and the precursor content corresponding to the subsequently desired ratio of mixed oxide components,
atomizing said precursor solution with air or an inert carrier gas, using a nozzle,
mixing the atomized precursor solution with a fuel gas and air (primary air),
burning the mixture of fuel gas, air (primary air) and atomized precursor solution in a flame in a reaction pipe, and
cooling the hot gases and the solid products and subsequently separating the solid products from the gases,
wherein
the proportion of precursor solution in the total quantity of gas consisting of atomising gas, air (primary air) and fuel gas is from 10 to 100 g solution/Nm 3 gas,
lambda, defined as the ratio of oxygen present from the air used for combustion of the fuel gas to oxygen required for combustion of the fuel gas, is 2 to 4.5
the precursors remain in the flame for a residence time of 5 to 30 milliseconds and
the temperature of the reaction mixture 0.5 m below the flame is 700 to 800° C.
21 . A method of using the indium-tin mixed oxide powder according to claim 11 for producing electrically conductive paints and coatings, solar cells and IR and UV absorbers and in medical technology.