Semiconductive polymer composition
View Patent ↗The invention relates to a semiconductive polymer composition for use in power cables. The composition comprises a multimodal ethylene homo- or copolymer produced in a polymerization process comprising a single site catalyst whereby the polymer composition has a density of 870 to 930 kg/m3, a MFR2 of 1 to 30 g/10 min and a Mw/Mn of less than or equal to 10.
1. A semiconductive polymer composition comprising:
a multimodal ethylene homo- or copolymer, produced in a polymerisation process comprising a single site catalyst; and
10 to 40 wt % acetylene black based on the total composition;
wherein the polymer composition has a density of 870 to 930 kg/m 3 , a MFR 2 of 1 to 30 g/10 min and a Mw/Mn of 2.5 to 10, and wherein the ranges given are measured without additives.
2. A polymer composition according to claim 1 , wherein the composition has a Mw/Mn of greater than or equal to 3.0.
3. A polymer composition according to claim 1 , wherein the multimodal ethylene homo- or copolymer is a bimodal ethylene homo- or copolymer.
4. A polymer composition according to claim 1 , wherein the copolymer comprises at least one C 3 -C 8 alpha-olefin.
5. A polymer composition according to claim 1 , wherein the acetylene black is present in an amount of less than or equal to 35 wt % of the total composition.
6. A polymer composition according to claim 1 , wherein the acetylene black is present in an amount of 10 to 35 wt % of the total composition.
7. A polymer composition according to claim 1 , wherein the composition is partially cross-linked.
8. A polymer composition according to claim 1 , wherein the polymer composition is extrudable at a temperature of less than 120° C.
9. The polymer composition according to claim 1 , wherein the composition further comprises up to 10 wt % polar copolymer.
10. A polymer composition according to claim 9 , wherein the polar copolymer is a high pressure copolymer.
11. A polymer composition according to claim 10 , wherein the high pressure copolymer is selected from the group consisting of ethylene-butyl-acrylate, ethylene-ethyl-acrylate, ethylene-methyl-acrylate, and ethylene-vinyl-acetate.
12. A polymer according to claim 9 , wherein the polar copolymer contains 5-30 wt % of polar comonomers.
13. A polymer composition according to claim 9 , wherein the copolymer is a vinyl-silane-copolymer.
14. An insulated electric DC-cable comprising a conductor, an inner semiconductive layer, an insulating layer and an outer semiconductive layer whereby at least one of the two semiconductive layers comprises a composition according to claim 1 .
15. An insulated electric cable according to claim 14 , wherein the insulating layer comprises a multimodal ethylene polymer produced in a process comprising a single site catalyst.
16. An insulated electric AC-cable comprising a conductor, an inner semiconductive layer, an insulating layer and an outer semiconductive layer whereby at least one of the two semiconductive layers comprises a composition according to claim 1 .
17. An insulated electric cable according to claim 16 , wherein the insulating layer comprises the multimodal ethylene polymer produced in a process comprising a single site catalyst.
18. A process for producing a polymer in accordance with claim 1 , wherein in a first stage a first fraction is produced, and in a second stage a second fraction is produced in the presence of a single site catalyst.
19. A process according to claim 18 , wherein in the first stage a loop reactor is used, and in the second stage a gas phase reactor is used.