Method for the manufacture of pressure sensitive adhesives
View Patent ↗A method for the manufacture of an adhesive id described, comprising: (A) Providing an initial reaction product of a solution polymerization reaction, the initial reaction product comprising polymer, unreacted polymerizable reactant, non-polymerizable material, and solvent; and (B) Purifying the initial reaction product by adding an oxidizing agent and a reducing agent to the initial reaction product and allowing the unreacted polymerizable reactant in the initial reaction product to further react, thereby providing a second reaction product comprising additional polymer and a lower level of unreacted polymerizable reactant than was present in the initial reaction product. Optionally, the method of the invention may further comprise: Precipitating the polymer from the second reaction product to provide a precipitated polymer, and separating the precipitated polymer from the remainder of the second reaction product, the precipitated polymer comprising a lower level of non-polymerizable material or unreacted polymerizable reactant or both non-polymerizable material and unreacted polymerizable reactant than was present in the second reaction product.
1. A method for the manufacture of a pressure sensitive adhesive, comprising:
(A) Providing an initial reaction product of a solution polymerization reaction, the initial reaction product comprising a pressure sensitive adhesive polymer, unreacted polymerizable reactant, non-polymerizable material, and solvent; and
(B) Purifying the initial reaction product by adding an oxidizing agent and a reducing agent to the initial reaction product and allowing the unreacted polymerizable reactant in the initial reaction product to further react, thereby providing a second reaction product comprising additional pressure sensitive adhesive polymer and a lower level of unreacted polymerizable reactant than was present in the initial reaction product, with the proviso that the level of unreacted polymerizable reactant in the second reaction product is less than about 100 ppm.
2. The method as defined in claim 1 wherein step (A) of providing an initial reaction product of a solution polymerization reaction comprises polymerizing a primary acrylate monomer comprising a C 4 to C 12 alkyl acrylate.
3. The method as defined in claim 1 wherein step (A) of providing an initial reaction product of a solution polymerization reaction comprises polymerizing a primary acrylate monomer comprising an alkyl acrylate and a polar monomer.
4. The method as defined in claim 3 wherein the primary acrylate monomer is selected from the group consisting of isooctyl acrylate, 2-ethylhexyl acrylate, 2-methyl butyl acrylate, butyl acrylate and combinations of two or more of the foregoing.
5. The method as defined in claim 4 wherein the polar monomer is selected from the group consisting of acrylamide, methacrylamide, N-vinyl-2-pyrrolidone, 2-hydroxyethylacrylate, hydroxypropylacrylate, acrylic acid, methacrylic acid, pyrrolidonyl ethyl acrylate, 2-carboxyethylacrylate, and combinations of two or more of the foregoing.
6. The method as defined in claim 1 wherein a free radical is generated by reaction of the oxidizing agent with the reducing agent.
7. The method as defined in claim 1 wherein the oxidizing agent is an alkyl hydroperoxide selected from the group consisting of tertiary amyl hydroperoxide, tertiary butyl hydroperoxide and combinations of two or more of the foregoing.
8. The method as defined in claim 1 wherein the reducing agent is selected from the group consisting of alkylamines, sodium formaldehydesulfoxide, Vitamin C and combinations of two or more of the foregoing.
9. The method as defined in claim 1 wherein step (B) of purifying the initial reaction product further comprises adding a promoter to the initial reaction product.
10. The method as defined in claim 9 wherein the promoter comprises a transition metal salt selected from the group consisting of vanadyl sulfate hydrate, ferrous sulfate and combinations of two or more of the foregoing.
11. The method as defined in claim 1 , further comprising the steps of
Precipitating the polymer from the second reaction product to provide a precipitated polymer; and
Separating the precipitated polymer from the remainder of the second reaction product, the precipitated polymer comprising a lower level of non-polymerizable material or unreacted polymerizable reactant or both non-polymerizable material and unreacted polymerizable reactant than was present in the second reaction product.
12. The method as defined in claim 11 wherein precipitating the polymer from the second reaction product comprises modifying the polarity of the solvent until the polymer is no longer soluble therein.
13. The method as defined in claim 11 wherein the precipitated polymer comprises a level of unreacted polymerizable reactant of less than about 50 ppm.
14. A method for the manufacture of a pressure sensitive adhesive copolymer, comprising:
(A) Providing an initial reaction product of a solution polymerization reaction, the initial reaction product comprising a pressure sensitive adhesive copolymer of isooctyl acrylate and acrylamide, unreacted polymerizable reactant, non-polymerizable material, and solvent;
(B) Purifying the initial reaction product by adding an oxidizing agent and a reducing agent to the initial reaction product and allowing the unreacted polymerizable reactant in the initial reaction product to further react, thereby providing a second reaction product comprising additional pressure sensitive adhesive copolymer and a lower level of unreacted polymerizable reactant than was present in the initial reaction product; and
(C) Precipitating the non-polymerizable material from the reaction product to provide a purified pressure sensitive adhesive copolymer of isooctyl acrylate and acrylamide comprising less than about 100 ppm of unreacted isooctyl acrylate or acrylamide.