Inorganic separator-electrode-unit for lithium-ion batteries, method for the production thereof and use thereof in lithium batteries

1. A separator-electrode assembly, comprising:

a current collector;

a porous electrode on the current collector; and

a separator layer applied to the porous electrode;

wherein the separator layer is an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size, and

active mass particles of the porous electrode are bonded together and to the current collector by an inorganic, electroconductive adhesive, and

the separator-electrode assembly comprises no organic polymer binder.

2. The separator-electrode assembly according to claim 1 , wherein the separator layer comprises the at least two fractions of metal oxides comprises:

metal oxide particles having an average particle size (D g ) greater or smaller than the average pore size (d) of the pores of the porous electrode; and

metal oxide particles having a particle size (D k ) smaller than the pores of the porous electrode,

wherein

the metal oxide particles having an average particle size (D g ) are adhered together by the metal oxide particles having a particle size (D k ),

the separator layer penetrates less than 20 D g into the pores of the electrode.

3. The separator-electrode assembly according to claim 1 , wherein a thickness of the separator layer is less than 100 D g and not less than 1.5 D g .

4. The separator-electrode assembly according to claim 1 , wherein the porous electrode is a porous positive electrode and the metal oxide particles having an average particle size (D g ) greater or smaller than the average pore size (d) of the pores of the porous positive electrode are Al 2 O 3 and/or ZrO 2 particles.

5. The separator-electrode assembly according to claim 1 , wherein the metal oxide particles having an average particle size (D k ) smaller than the average pore size (d) of the pores of the porous electrode are SiO 2 and/or ZrO 2 particles.

6. The separator-electrode assembly according to claim 1 , wherein the metal oxide particles having an average particle size (D g ) greater or smaller than the average pore size (d) of the pores of the porous electrode have an average particle size (D g ) of less than 10 μm.

7. The separator-electrode assembly according to claim 1 , wherein the separator layer with a further coating comprising shutdown particles which melt at a desired shutdown temperature.

8. The separator-electrode assembly according to claim 1 , wherein a porosity of the separator layer is from 30 to 70%.

9. The separator-electrode assembly according to claim 1 , wherein an average particle size of the active mass particles is from 0.1 to 25 μm.

10. The separator-electrode assembly according to claim 1 , wherein

when the electrode is a positive electrode, the active mass particles comprise at least one of the elements Co, Ni, Mn, V, Fe or P, and

when the electrode is a negative electrode, the active mass particles comprise at least one of the elements C, Si, Nb, Ti, Mo or W.

11. The separator-electrode assembly according to claim 10 , wherein

the positive electrode comprises active mass particles selected from the group consisting of LiNi 1−y COyO 2 where y=0 to 1, LiMn 2 O 4 , LiMnO 2 , LiFePO 4 , LiVOPO 4 and LiNiVO 4 , and

the negative electrode comprises active mass particles selected from the group consisting of graphite, silicon, graphite-silicon mixtures, lithium-silicon and lithium-tin containing alloys.

12. The separator-electrode assembly according to claim 1 , wherein the porous electrode comprises active mass particles adhered by an inorganic, electroconductive adhesive comprising particles having an average particle size in the range from 1 to 100 nm.

13. The separator-electrode assembly according to claim 12 , wherein

when the porous electrode is positive, the particles of the inorganic, electroconductive adhesive comprises at least one selected from the group of particles of active mass for electrodes consisting of the elements Co, Ni, Mn, V, Fe and P, and

when the porous electrode is negative the particles of the inorganic, electroconductive adhesive comprises at least one selected from the group of elements consisting of C, Si, Nb, Ti, Mo or W, or from particles of compounds selected from the group consisting of titanium suboxide, titanium nitride, titanium carbide, doped or undoped tin oxide, indium-tin oxide (ITO) and doped or undoped zinc oxide.

14. The separator-electrode assembly according to claim 1 , wherein the assembly is bendable down to a radius down to 1 cm without damage.

15. A lithium battery comprising the separator-electrode assembly according to claim 1 .