Wholly aromatic liquid crystal polyester resin composition and optical pickup lens holder
View Patent ↗An optical pickup lens holder which comprises a wholly aromatic liquid crystalline polyester resin composition comprising 97 to 45 mass percent of a wholly aromatic liquid crystalline polyester having a melting point of 320° C. or higher, 3 to 50 mass percent of an inorganic spherical hollow material having an aspect ratio of 2 or less and 0 to 30 mass percent of an inorganic filler having as aspect ratio of 4 or more, wherein the percentages are made to 100 mass percent in total, and having a specific gravity in the range of 1.00 to 1.35. The lens holder exhibits excellent characteristics, while retaining good heat resistance in soldering and good processability inherent in a liquid crystalline polyester, exhibits high injection processability and high adaptability to a soldering process even in a sheet form lens holder having a thin part and an opening port.
1. A wholly aromatic liquid crystal polyester resin composition injection molded to form an optical pickup lens holder, the optical pickup lens holder having a specific gravity in a range of 1.00 to 1.35, and having a part and an opening portion holding a lens, said part having a thickness of 0.3 mm or less, the composition comprising (a) 97 to 45 percent by mass of a wholly aromatic liquid crystal polyester having a melting point of 320° C. or higher and an apparent viscosity at 20° C. above the melting point of 5,000 poise or less, (b) 3 to 50 percent by mass of an inorganic spherical hollow material having an aspect ratio of 2 or less, and (c) 0 percent by mass of an inorganic filler having an aspect ratio of 4 or more.
2. The wholly aromatic liquid crystal polyester resin composition according to claim 1 , wherein said wholly aromatic liquid crystal polyester is prepared by the polycondensation of I, II, III, and IV, wherein I is p-hydroxybenzoic acid or a p-hydroxybenzoic acid derivative having repeating structural units represented by the following formula, wherein X 1 is selected from the group consisting of halogen atoms and alkyl groups:
wherein II is terephthalic acid or a terephthalic acid derivative having repeating structural units represented by the following formula, wherein X 2 is selected from the group consisting of halogen atoms, alkyl groups and aryl groups:
wherein III is 4,4′ dihydroxydiphenyl or a 4,4′-dihydroxydiphenyl derivative having repeating structural units represented by the following formula:
wherein IV is one or more other aromatic compounds capable of conducting a polycondensation reaction with any one of I, II, or III, and selected from the group consisting of aromatic diols, aromatic hydroxycarboxylic acids and aromatic dicarboxylic acids, and wherein the total of I, II, and III is 80 to 100 percent by mole, the total of I and II is more than 60 percent by mole, and IV is 0 to 20 percent by mole.
3. The wholly aromatic liquid crystal polyester resin composition according to claim 1 , wherein the inorganic spherical hollow material having an aspect ratio of 2 or less has an average particle diameter of 5 to 200 μm, and a rate of volume hollowness of 50 percent or more.
4. An optical pickup lens holder in a sheet form driven by a focusing coil and a tracking coil, comprising an injection molded product, the injection molded product having a specific gravity in a range of 1.00 to 1.35, obtained from a wholly aromatic liquid crystal polyester resin composition, comprising 97 to 45 percent by mass of a wholly aromatic liquid crystal polyester having a melting point of 320° C. or higher and an apparent viscosity at 20° C. above the melting point of 5,000 poise or less, 3 to 50 percent by mass of the inorganic spherical hollow material having an aspect ratio of 2 or less, and 0 percent by mass of the inorganic filler having an aspect ratio of 4 or more, wherein said optical pickup lens holder comprises a part with thickness of 0.3 mm or less, and said part has a flexural modulus of 10 GPa or more.
5. The optical pickup lens holder according to claim 4 , wherein said optical pickup lens holder comprises an opening portion to hold a coil bobbin for the focusing coil or the tracking coil.
6. The wholly aromatic liquid crystal polyester resin composition according to claim 2 , wherein:
the inorganic spherical hollow material having an aspect ratio of 2 or less has an average particle diameter of 5 to 200 μm, and a rate of volume hollowness of 50 percent or more.
7. The optical pickup lens holder according to claim 4 , wherein the wholly aromatic liquid crystal polyester is prepared by the polycondensation of I, II, III, and IV, wherein I is p-hydroxybenzoic acid or a p-hydroxybenzoic acid derivative having repeating structural units represented by the following formula, wherein X 1 is selected from the group consisting of halogen atoms and alkyl groups:
wherein II is terephthalic acid or a terephthalic acid derivative having repeating structural units represented by the following formula, wherein X 2 is selected from the group consisting of halogen atoms, alkyl groups and aryl groups:
wherein III is 4,4′ dihydroxydiphenyl or a 4,4′-dihydroxydiphenyl derivative having repeating structural units represented by the following formula:
wherein IV is one or more other aromatic compounds capable of conducting a polycondensation reaction with any one of I, II, or III, and selected from the group consisting of aromatic diols, aromatic hydroxycarboxylic acids and aromatic dicarboxylic acids, and wherein the total of I, II, and III is 80 to 100 percent by mole, the total of I and II is more than 60 percent by mole, and IV is 0 to 20 percent by mole.