IP Library › Granted Patent US 8,114,822
Granted Patent B2
US 8,114,822 · App. 11/586,195 · Granted Feb 14, 2012

Soluble oil containing overbased sulfonate additives

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Quick Facts
Patent No.
US 8,114,822
App. No.
11/586,195
Granted
Feb 14, 2012
Kind
B2
Abstract

The present invention is directed to a soluble oil composition capable of forming stable emulsions exhibiting superior performance and possessing excellent utility as cutting oil for machines. The composition comprises an overbased alkaline earth metal sulfonate possessing anti-wear properties.

Claims (18)

1. A soluble oil composition which consists essentially of:

a) a base oil selected from the group consisting of naphthenic oil; hydrogenated polyolefin oils; poly-alpha-olefins; alkyl esters of dicarboxylic acids; complex esters of dicarboxylic acids; polyglycol and alcohol; alkyl esters of carbonic or phosphoric acids; polysilicones; fluorohydrocarbon oils; homo- and inter-polymers of C 2 -C 12 olefins; carboxylic acid esters of both monoalcohols and polyols; polyethers; silicones; polyglycols; silicates, alkylated aromatics; carbonates; thiocarbonates; orthoformates; phosphates; phosphites; borates; and halogenated hydrocarbons

b) an emulsion stabilizing amount of a neutralized carboxylic acid obtained from tall oil and/or component thereof; and

c) from 1 to 10 weight percent of at least one overbased calcium sulfonate; and, optionally,

d) at least one additive selected from the group consisting of extreme pressure agent, anti-wear agent, emulsifying agent, rust preventive, corrosion inhibitor, anti-foaming agent, anti-oxidant additives, surface active agents, friction modifier, stabilizing agents, and mixtures thereof.

2. The soluble oil composition of claim 1 wherein the base oil is at least one selected from the group consisting of esters of dicarboxylic acids, dibutyl adipate, di(2-ethylhexyl)adipate, didodecyl adipate, di(tridecyl)adipate, di(2-ethylhexyl)sebacate, dilauryl sebacate, di-n-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecyl azelate, dioctyl phthalate, didecyl phthalate, di(eicosyl)sebacate, and the 2-ethylhexyl diester of linoleic acid dimer.

3. The soluble oil composition of claim 1 wherein the neutralized carboxylic acid is at least one obtained from the group consisting of tall oil fatty acids, tall oil fatty acids containing less than about 2% rosin and tall oil rosin.

4. The soluble oil composition of claim 1 wherein the amount of neutralized carboxylic acid ranges from about 5 weight percent to about 23 weight percent of the soluble oil composition.

5. The soluble oil composition of claim 1 wherein the amount of neutralized carboxylic acid ranges from about 12 to about 15 weight percent of the soluble oil composition.

6. The soluble oil composition of claim 1 wherein the amount of neutralized tall oil ranges from about 5 to about 23 weight percent of the soluble oil composition.

7. The soluble oil composition of claim 6 wherein the amount of neutralized tall oil ranges from about 12 to about 15 weight percent of the soluble oil composition.

8. The soluble oil composition of claim 1 wherein the amount of overbased calcium sulfonate ranges from about 2 to about 5 weight percent of the soluble oil composition.

9. The soluble oil composition of claim 1 wherein the total base number of the overbased calcium sulfonate is at least about 400.

10. The soluble oil composition of claim 1 wherein the total base number of the overbased calcium sulfonate is from about 200 to about 400.

11. The soluble oil composition of claim 1 wherein the total base number of the overbased calcium sulfonate is from about 250 to about 350.

12. The soluble oil composition of claim 1 wherein the friction modifier is at least one selected from the group consisting of glycerol monoesters, overbased carboxylates, overbased tall oil fatty acids, triethanolamine, diethanolamine, glycol, oleic acid, ricinoleic acid, isostearic acid, erucic acid, tall oil fatty acid (TOFA), mixed oleic/stearic acids, and iso-oleic acid.

13. The soluble oil composition of claim 1 wherein the anti-wear agent is sulfurized olefin.

14. The soluble oil composition of claim 1 wherein the at least one additive is a phenolic compound.

Assignments (12)
RELEASE OF AMENDED AND RESTATED SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded May 12, 2017
From: BANK OF AMERICA, N.A.
To: CHEMTURA CORPORATION; CROMPTON COLORS INCORPORATED; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION
Reel/Frame 042452/0759 →
RELEASE OF THIRD LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded May 12, 2017
From: BANK OF AMERICA, N.A.
To: CHEMTURA CORPORATION; CROMPTON COLORS INCORPORATED; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION
Reel/Frame 042452/0894 →
RELEASE OF FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded May 11, 2017
From: BANK OF AMERICA, N.A.
To: CHEMTURA CORPORATION; BIOLAB FRANCHISE COMPANY, LLC; BIO-LAB, INC.; CROMPTON COLORS INCORPORATED; CROMPTON HOLDING CORPORATION; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GREAT LAKES CHEMICAL GLOBAL, INC.; GT SEED TREATMENT, INC.; HOMECARE LABS, INC.; LAUREL INDUSTRIES HOLDINGS, INC.; RECREATIONAL WATER PRODUCTS, INC.; WEBER CITY ROAD LLC
Reel/Frame 042447/0508 →
RELEASE OF SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded May 11, 2017
From: BANK OF AMERICA, N.A.
To: CHEMTURA CORPORATION; BIOLAB FRANCHISE COMPANY, LLC; BIO-LAB, INC.; CROMPTON COLORS INCORPORATED; CROMPTON HOLDING CORPORATION; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GREAT LAKES CHEMICAL GLOBAL, INC.; GT SEED TREATMENT, INC.; HOMECARE LABS, INC.; LAUREL INDUSTRIES HOLDINGS, INC.; RECREATIONAL WATER PRODUCTS, INC.; WEBER CITY ROAD LLC
Reel/Frame 042449/0001 →
AMENDED AND RESTATED SECOND LIEN INTELLECTUAL PROPERY SECURITY AGREEMENT Recorded Jul 18, 2014
From: CHEMTURA CORPORATION; CROMPTON COLORS INCORPORATED; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 033360/0225 →
THIRD LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 18, 2014
From: CHEMTURA CORPORATION; CROMPTON COLORS INCORPORATED; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 033360/0325 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT. Recorded Mar 21, 2011
From: CHEMTURA CORPORATION; BIOLAB FRANCHISE COMPANY, LLC; BIO-LAB, INC.; CROMPTON COLORS INCORPORATED; CROMPTON HOLDING CORPORATION; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GREAT LAKES CHEMICAL GLOBAL, INC.; GT SEED TREATMENT, INC.; HOMECARE LABS, INC.; LAUREL INDUSTRIES HOLDINGS, INC.; RECREATIONAL WATER PRODUCTS, INC.; WEBER CITY ROAD LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 026028/0622 →
INTELLECTUAL PROPERTY SECURITY RELEASE AGREEMENT Recorded Mar 21, 2011
From: CITIBANK, N.A.
To: CHEMTURA CORPORATION; A & M CLEANING PRODUCTS, LLC; ASCK, INC; BIOLAB COMPANY STORE, LLC; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIOLAB TEXTILES ADDITIVES, LLC; BIOLAB, INC.; CROMPTON COLORS INCORPORATED; CROMPTON MONOCHEM, INC.; CNK CHEMICAL REALTY CORPORATION; CROMPTON HOLDING CORPORATION; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GT SEED TREATMENT, INC.; ISCI, INC; GREAT LAKES CHEMICAL GLOBAL, INC.; HOMECARE LABS, INC.; KEM MANUFACTURING CORPORATION; LAUREL INDUSTRIES HOLDINGS, INC.; NAUGATUCK TREATMENT COMPANY; UNIROYAL CHEMICAL COMPANY LIMITED (DELAWARE); MONOCHEM, INC.; RECREATIONAL WATER PRODUCTS, INC.; WEBER CITY ROAD LLC; WRL OF INDIANA, INC.; BIOLAB FRANCHISE COMPANY, LLC
Reel/Frame 026039/0142 →
SECDOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 21, 2011
From: CHEMTURA CORPORATION; BIOLAB FRANCHISE COMPANY, LLC; BIO-LAB, INC.; CROMPTON COLORS INCORORATED; CROMPTON HOLDING CORPORATION; CLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GREAT LAKES CHEMICAL GLOBAL, INC.; GT SEED TREATMENT, INC.; HOMECARE LABS, INC.; HAOMECARE LABS, INC.; LAUREL INDUSTRIES HOLDINGS, INC.; RECREATIONAL WATER PRODUCTS, INC.; WEBER CITY ROAD LLC
To: BANK OF AMERICA, N. A.
Reel/Frame 027881/0347 →
AMENDED AND RESTATED INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Feb 22, 2010
From: CHEMTURA CORPORATION; A & M CLEANING PRODUCTS, LLC; AQUA CLEAR INDUSTRIES, LLC; ASCK, INC.; ASEPSIS, INC.; BIOLAB COMPANY STORE, LLC; BIOLAB FRANCHISE COMPANY, LLC; BIOLAB TEXTILE ADDITIVES, LLC; BIO-LAB, INC.; CNK CHEMICAL REALTY CORPORATION; CROMPTON COLORS INCORPORATED; CROMPTON HOLDING CORPORATION; CROMPTON MONOCHEM, INC.; GLCC LAUREL, LLC; GREAT LAKES CHEMICAL CORPORATION; GREAT LAKES CHEMICAL GLOBAL, INC.; GT SEED TREATMENT, INC.; HOMECARE LABS, INC.; ISCI, INC.; KEM MANUFACTURING CORPORATION; LAUREL INDUSTRIES HOLDINGS, INC.; MONOCHEM, INC.; NAUGATUCK TREATMENT COMPANY; RECREATIONAL WATER PRODUCTS, INC.; UNIROYAL CHEMICAL COMPANY LIMITED (DELAWARE); WEBER CITY ROAD LLC; WRL OF INDIANA, INC.
To: CITIBANK, N.A.
Reel/Frame 023998/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2006
From: COSTELLO, MICHAEL T.; RIFF, IGOR
To: CHEMTURA CORPORATION
Reel/Frame 018514/0242 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2006
From: MA, QINGGAO
To: CHEMTURA CORPORATION
Reel/Frame 018510/0824 →