Heat treatable coated article with diamond-like carbon (DLC) and/or zirconium in coating
View Patent ↗In certain example embodiments, a coated article includes respective layers including diamond-like carbon (DLC) and zirconium nitride before heat treatment (HT). During HT, the hydrogenated DLC acts as a fuel which upon combustion with oxygen produces carbon dioxide and/or water. The high temperature developed during this combustion heats the zirconium nitride to a temperature(s) well above the heat treating temperature, thereby causing the zirconium nitride to be transformed into a new post-HT layer including zirconium oxide that is scratch resistant and durable.
1. A method of making a heat treated coated article, the method comprising:
providing a coating comprising a layer comprising zirconium nitride and a layer comprising carbon, the layer comprising carbon comprising diamond-like carbon;
heat treating the coating; and
wherein during said heat treating the layer comprising carbon is subject to combustion and/or burns off and the layer comprising zirconium nitride transforms into a heat treated layer comprising zirconium oxide in the heat treated coated article.
2. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide comprises a nanocrystalline cubic lattice structure.
3. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide comprises from about 30-80% oxygen.
4. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide comprises from about 20-60% Zr.
5. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide comprises from about 30-55% Zr.
6. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide comprises from about 30-45% Zr and from about 0-10% N.
7. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide includes Zr x O y , wherein y/x is from about 1.2 to 2.5.
8. The method of claim 1 , wherein the heat treated layer comprising zirconium oxide includes Zr x O y , wherein y/x is from about 1.4 to 2.1.
9. The method of claim 1 , wherein the layer comprising zirconium nitride and the layer comprising carbon are supported by a glass substrate.
10. The method of claim 9 , wherein the heat treating is part of a thermal tempering process.
11. A method of making a heat treated coated article, the method comprising:
providing a coating comprising a layer comprising metal nitride and a layer comprising diamond-like carbon (DLC);
heat treating the coating; and
wherein during said heat treating the layer comprising DLC is subject to combustion and/or burns off and the layer comprising metal nitride transforms into a heat treated layer comprising metal oxide in the heat treated coated article.
12. The method of claim 11 , wherein the heat treated layer comprising metal oxide comprises a nanocrystalline cubic lattice structure.
13. The method of claim 11 , wherein the heat treated layer comprising metal oxide comprises from about 30-80% oxygen.