Photosensitive original printing plate for relief printing, method for producing relief printing plate, and light-shielding ink for performing the method
View Patent ↗Provided are an original printing plate for relief printing that solves both the problems of the prior-art negative film or its alternatives, and problems of mask pattern formation directly on the surface of the photosensitive resin layer by an ink composition, as well as a method for forming an relief printing plate using the same. Employing a photosensitive original printing plate for relief printing including a support substrate (A); a photosensitive resin layer (B) provided thereon and having a photosensitivity to light in a predetermined wavelength region; and an ink holding layer (C) provided thereon; wherein the layer (C) is capable of retaining a light-shielding ink, and capable of constituting a light-shielding pattern inside the layer (C), the light-shielding pattern being formed by applying the light-shielding ink to the (C) in accordance with the pattern; and wherein the (C) at the area to which the light-shielding ink is not applied is substantially transparent to the light in the predetermined wavelength region.
1. A photosensitive laminate for relief printing comprising:
a support substrate (A);
a photosensitive resin layer (B) provided on said support substrate (A), said photosensitive resin layer (B) having a photosensitivity to light in a wavelength region of 300 nm to 400 nm; and
an ink holding layer (C) provided directly on said photosensitive resin layer (B) and formed from a water-soluble composition,
a light-shielding pattern diffused inside said layer (C), said light-shielding pattern comprising a light-shielding ink containing a water-soluble dye
wherein said light-shielding ink is present only in said ink holding layer (C), and is formed into the pattern of the light-shielding pattern,
wherein said light-shielding ink absorbs light in the wavelength region of 300 nm to 400 nm, and
wherein an integral value of light absorbance (light path length of 10 mm) of said light-shielding ink in a wavelength region of 300 nm to 400 nm is 45 nm times Abs, or more, when said light-shielding ink has been diluted 5,000 times with water.
2. The photosensitive laminate for relief printing according to claim 1 wherein said ink holding layer (C) is formed into a thickness of 0.5 to 15 μm.
3. The photosensitive laminate for relief printing according to claim 1 wherein said water-soluble composition contains a resin which has at least one of the following properties selected from the group consisting of being soluble in water-soluble solvent, soluble in a water-soluble organic solvent, swellable with a water-soluble solvent, swellable with a water-soluble organic solvent, dispersible in a water-soluble solvent, and dispersible in a water-soluble organic solvent.
4. The photosensitive laminate for relief printing according to claim 1 wherein a solubility of said water-soluble dye in water is 7% by weight or more when the pH of said water is in a neutral to alkali range.
5. A method for producing a relief printing plate comprising the steps of:
irradiating a photosensitive resin layer (B) with a light in a wavelength region of 300 nm to 400 nm using a light-shielding pattern formed on an ink holding layer (C) of the photosensitive laminate for relief printing according to claim 1 as a mask; and
removing using a developing solution a non-irradiated part of said photosensitive resin layer (B) that remains uncured by not being irradiated with said light in a wavelength region of 300 nm to 400 nm, to form a resin layer having a convex pattern on a support (A) for printing.
6. The method for producing the relief printing plate according to claim 5 , wherein said light-shielding pattern is printed onto said ink holding layer using an inkjet recording apparatus.
7. The photosensitive laminate for relief printing according to claim 1 wherein said ink holding layer (C) comprises polyvinyl butyral or polyvinyl pyrrolidone.
8. The method for producing the relief printing plate according to claim 5 wherein said ink holding layer (C) comprises polyvinyl butyral or polyvinyl pyrrolidone.
9. A method of making a photosensitive laminate for relief printing according to claim 1 comprising:
providing said photosensitive resin layer (B) on the support substrate (A);
providing the ink holding layer (C) directly on the photosensitive resin layer (B);
permeating the light-shielding ink containing the water-soluble dye into said layer (C) to form a light-shielding pattern in said layer (C).