Optimizing performance parameters for switchable polymer dispersed liquid crystal optical elements
View Patent ↗Described herein are the materials, mechanisms and procedures for optimizing various performance parameters of HPDLC optical devices in order to meet differing performance requirements. These optimization tailoring techniques include control and independent optimization of switchable HPDLC optical devices to meet the demanding requirements of anticipated applications for, inter alia, the telecommunications and display industries. These techniques include optimization of diffraction efficiency, i.e., index modulation, polarization dependence control, haze, cosmetic quality, control of response and relaxation time, voltage driving for on and off switching, and material uniformity. This control and independent optimization tailors properties of switchable HPDLC optical devices according to the specific requirements of the application of the switchable HPDLC optical device. The invention disclosed herein retains the desirable attributes of the multi-functional acrylate system for forming HPDLC optical devices, but adds new materials to the acrylate system and/or new process control to the recording to optimize performance parameters as may be needed for specific applications. This results in high optical quality switchable holograms with good diffraction efficiency and low, stable switching voltage.
1. A method for forming a holographically polymerized polymer dispersed liquid crystal optical element with reduced haze comprising:
adding a pre-polymerized polymer dispersed liquid crystal material to a pre-existing loosely gelled network;
placing the pre-existing loosely gelled network containing the pre-polymerized polymer dispersed liquid crystal material between first and second transparent substrates; and
interfering a first beam and a second beam within the pre-existing loosely gelled network containing the pre-polymerized polymer dispersed liquid crystal material to form the holographically polymerized polymer dispersed liquid crystal optical element with reduced haze.
2. The method according to claim 1 , wherein the pre-existing loosely gelled network is an aerogel.
3. A method for forming a holographically polymerized polymer dispersed liquid crystal optical element with reduced haze comprising:
forming a loosely gelled network within a pre-polymerized polymer dispersed liquid crystal material;
placing the loosely gelled network containing the pre-polymerized polymer dispersed liquid crystal material between first and second transparent substrates; and
directing a first beam and a second beam at the pre-existing loosely gelled network containing the pre-polymerized polymer dispersed liquid crystal material; and
holographically polymerizing the polymer dispersed liquid crystal material, including the loosely gelled network, to form the polymer dispersed liquid crystal optical element with decreased haze.
4. The method of claim 3 , wherein the loosely gelled network is an aerogel.
5. The method of claim 3 , wherein the first and second transparent substrates are glass plates.
6. The method of claim 5 , wherein the glass plates are coated with indium tin oxide.
7. The method of claim 3 , wherein the substrates are conductive.
8. The method of claim 3 , further comprising a transparent tank.
9. The method of claim 8 , wherein the transparent tank further comprises at least one prism or glass block.
10. The method of claim 8 , wherein the transparent tank further comprises at least one neutral density filter.
11. The method of claim 9 , wherein the transparent tank comprises at least one BK-7 block.
12. The method of claim 9 , wherein the at least one prism or glass block comprises substantially the same refractive index as the polymer dispersed liquid crystal optical element.
13. The method of claim 3 , further comprising the step of blocking the first beam and allowing the second beam to interact with the pre-polymer liquid crystal material for a predetermined amount of time, wherein the interaction converts the pre-polymer liquid crystal material into the loosely gelled network.
14. The method of claim 13 , wherein holographically polymerizing the polymer dispersed liquid crystal material comprises unlocking the first beam, such that both the first and second beams interact within the loosely gelled network to form the polymer dispersed liquid crystal optical element.
15. The method according to claim 13 , wherein the predetermined amount of time is approximately 2 to 5 seconds.
16. The method according to claim 13 , wherein the pre-polymer liquid crystal material contains a photoinitiator that is responsive to the wavelength of the second beam, but is not responsive to the wavelength of the first beam.