Two-component adhesive/sealant
A two part adhesive/sealant composition is provided, wherein component A contains at least one silane-terminated prepolymer, at least one silane crosslinking catalyst, and at least one low molecular weight organofunctional silane and component B contains at least one silane-terminated prepolymer, water and at least one water-dissolving and/or water-adsorbing agent such as an organic or inorganic thickener. Such compositions are exceptionally insensitive to mixing and dosing errors in use and are useful for forming elastic bonds between substrates.
1 . An adhesive/sealant composition comprising:
a) a component A comprising at least one silane-terminated prepolymer, at least one silane crosslinking catalyst, and at least one low molecular weight organofunctional silane; and
b) a component B comprising at least one silane-terminated prepolymer, water and at least one water-dissolving and/or water-adsorbing agent.
2 . An adhesive/sealant composition as claimed in claim 1 , wherein at least one of component A or component B is additionally comprised of at least one auxiliary selected from the group consisting of fillers, plasticizers, antiagers, and rheology aids.
3 . An adhesive/sealant composition as claim 1 , wherein component B is a paste-like, stable mixture of at least one silane-terminated prepolymer, at least one plasticizer, water, and at least one thickener.
4 . An adhesive/sealant composition as claimed in claim 1 , wherein at least one inorganic thickener selected from the group consisting of polysilicic acids, highly disperse pyrogenic silicas, aluminum hydroxide, aluminum oxide hydrate, talcum, quartz minerals, magnesium hydroxide, and clay minerals is present as water-dissolving and/or water-absorbing agent in component B.
5 . An adhesive/sealant composition as claimed in claim 1 , wherein at least one organic thickener selected from the group consisting of agar agar, carrageen, tragacanth, gum arabic, alginates, pectins, polyoses, guar gum, starch, dextrins, gelatine, casein, carboxymethyl cellulose, cellulose ethers, hydroxyethyl cellulose, hydroxypropyl cellulose, poly(meth)acrylic acid derivatives, polyvinyl ether, polyvinyl alcohol, polyamides, and polyimines is present as water-dissolving and/or water-absorbing agent in component B.
6 . An adhesive/sealant composition as claimed in claim 1 , wherein at least one organotin compound is used as a silane crosslinking catalyst.
7 . An adhesive/sealant composition as claimed in claim 1 , wherein the low molecular weight organofunctional silane is selected from the group consisting of 3-glycidyloxypropyl trialkoxysilanes, 3-acryloxypropyl trialkoxysilanes, 3-aminopropyl trialkoxysilanes, vinyl trialkoxysilanes, phenylaminopropyl trialkoxysilanes, aminoalkyl trialkoxysilanes, N-(2-aminoethyl)-3-aminopropyl trialkoxysilanes, 3-glycidyloxypropylalkyl dialkoxysilanes, 3-acryloxypropylalkyl dialkoxysilanes, 3-aminopropylalkyl dialkoxysilanes, vinylalkyl dialkoxysilanes, phenylaminopropylalkyl dialkoxysilanes, aminoalkylalkyl dialkoxydisilanes, N-(2-aminoethyl)-3-aminopropylalkyl dialkoxysilanes, i-butyl methoxysilane and mixtures thereof.
8 . An adhesive/sealant composition as claimed in claim 1 , wherein component B contains 1 to 20% by weight water, based on the total weight of component B.
9 . An adhesive/sealant composition as claimed in claim 1 , wherein component B contains 3 to 15% by weight water, based on the total weight of component B.
10 . An adhesive/sealant composition as claimed in claim 1 , wherein component A and component B are mixed in a ratio of 1:5 to 5:1 parts by weight.
11 . An adhesive/sealant composition as claimed in claim 1 , wherein component A and component B are mixed in a ratio of 1:2 to 2:1 parts by weight.
12 . An adhesive/sealant composition as claimed in claim 1 , wherein component A and component B are mixed in a ratio of 1:1 parts by weight.
13 . An adhesive/sealant composition as claimed in claim 1 , wherein said at least one silane-terminated prepolymer in component A and said at least one silane-terminated prepolymer in component B are selected from the group consisting of silane-terminated prepolymers with polyether backbones.
14 . A method for bonding a first substrate and a second substrate using an adhesive, wherein said first substrate and said second substrate are the same or different, said method comprising using an adhesive/sealant composition as claimed in claim 1 as said adhesive.
15 . A process for the primeness bonding of a first substrate and a second substrate, said first substrate and said second substrate being the same or different, said process comprising:
a) applying an adhesive/sealant composition as claimed in claim 1 to a surface of said first substrate;
b) placing said second substrate on said surface of said first substrate having said adhesive/sealant composition applied thereto; and
c) establishing a bond between said first substrate and said second substrate, wherein said bond can be rapidly further processed and/or transported without further mechanical fixing.
16 . A process as claimed in claim 15 , wherein component A and component B are mixed in a ratio of 1:5 to 5:1 parts by weight before step a).
17 . A process as claimed in claim 15 , wherein component A and component B are mixed in a ratio of 1:2 to 2:1 parts by weight before step a).
18 . A process as claimed in claim 15 , wherein component A and component B are mixed in a ratio of 1:1 parts by weight before step a).
19 . A process as claimed in claim 15 , wherein said first substrate and said second substrate are structural elements comprised of one or more materials selected from the group consisting of metals, painted metals, pretreated metals, glass, wood and plastics.
20 . An adhesive/sealant composition comprising:
a) a component A comprising at least one silane-terminated prepolymer having a polyether backbone, at least one silane crosslinking catalyst selected from the group consisting of organotin compounds, and at least one low molecular weight organofunctional silane selected from the group consisting of 3-glycidyloxypropyl trialkoxysilanes, 3-acryloxypropyl trialkoxysilanes, 3-aminopropyl trialkoxysilanes, vinyl trialkoxysilanes, phenylaminopropyl trialkoxysilanes, aminoalkyl trialkoxysilanes, N-(2-aminoethyl)-3-aminopropyl trialkoxysilanes, 3-glycidyloxypropylalkyl dialkoxysilanes, 3-acryloxypropylalkyl dialkoxysilanes, 3-aminopropylalkyl dialkoxysilanes, vinylalkyl dialkoxysilanes, phenylaminopropylalkyl dialkoxysilanes, aminoalkylalkyl dialkoxydisilanes, N-(2-aminoethyl)-3-aminopropylalkyl dialkoxysilanes, and i-butyl methoxysilane; and
b) a component B comprising at least one silane-terminated prepolymer having a polyether backbone, 1 to 20 weight % water and at least one inorganic thickener selected from the group consisting of polysilicic acids, highly disperse pyrogenic silicas, aluminum hydroxide, aluminum oxide hydrate, talcum, quartz minerals, magnesium hydroxide, and clay minerals.