IP Library Granted Patent US 7,618,500
Granted Patent B2
US 7,618,500 · App. 11/595,676 · Granted Nov 17, 2009

Corrosion resistant amorphous metals and methods of forming corrosion resistant amorphous metals

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Quick Facts
Patent No.
US 7,618,500
App. No.
11/595,676
Granted
Nov 17, 2009
Kind
B2
Abstract

A system for coating a surface comprises providing a source of amorphous metal, providing ceramic particles, and applying the amorphous metal and the ceramic particles to the surface by a spray. The coating comprises a composite material made of amorphous metal that contains one or more of the following elements in the specified range of composition: yttrium (≧1 atomic %), chromium (14 to 18 atomic %), molybdenum (≧7 atomic %), tungsten (≧1 atomic %), boron (≦5 atomic %), or carbon (≧4 atomic %).

Claims (31)

1. A method of coating a surface, comprising the steps of:

providing a source of amorphous metal binding metal, wherein said amorphous metal includes yttrium ≧1 atomic %, chromium 14 to 18 atomic %, molybdenum ≧7 atomic %, tungsten ≧1 atomic %, boron ≦5 atomic %, and carbon ≧4 atomic %;

providing a source of particles, wherein said source of particles is a source of ceramic particles; and

applying said amorphous metal binding metal and said particles to the surface by a spray process thereby coating the surface with a coating of a composite material made of amorphous metal and ceramic particles.

2. The method of coating a surface of claim 1 wherein said step of providing a source of particles includes providing a source of amorphous metal particles and wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process applies said amorphous metal binding metal, said ceramic particles, and said amorphous metal particles to the surface thereby coating the surface with a coating of a composite material made of amorphous metal, ceramic particles, and amorphous metal particles.

3. The method of coating a surface of claim 1 wherein said ceramic particles have a size within the range of nanometers to microns.

4. The method of coating a surface of claim 1 wherein said ceramic particles have a size within the range of 5 nanometers to 5 microns.

5. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises flame spray processing.

6. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises plasma spray processing.

7. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises high-velocity oxy-fuel spray processing.

8. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises high-velocity air-spray processing.

9. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises detonation gun processing.

10. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray or deposition process comprises thermal spray processing.

11. The method of coating a surface of claim 1 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises cold spray processing.

12. A method of coating a surface consisting of the steps of:

providing a source of amorphous binding metal, wherein said amorphous metal includes yttrium ≧1 atomic %, chromium 14 to 18 atomic %, molybdenum ≧7 atomic %, tungsten ≧1 atomic %, boron ≦5 atomic %, and carbon ≧4 atomic %;

providing a source of particles, wherein said source of particles is a source of ceramic particles and amorphous metal particles; and

applying said amorphous metal binding metal and said particles to the surface by a spray process thereby coating the surface with a coating of a composite material, wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises spraying alternating layers to the surface wherein at least one of said alternating layers contains amorphous metal including yttrium ≧1 atomic %, chromium 14 to 18 atomic %, molybdenum ≧7 atomic %, tungsten ≧1 atomic %, boron ≦5 atomic %, and carbon ≧4 atomic % and ceramic particles having a size with the range of nanometers to microns, said ceramic particles, and said amorphous metal particles thereby coating the surface with a coating of a composite material made of amorphous metal, ceramic particles, and amorphous metal particles.

13. The method of coating a surface of claim 12 wherein said step of applying said amorphous metal binding metal and said particles to the surface by a spray process comprises applying amorphous metal, ceramic particles, and amorphous metal particles to the surface by a spray comprises spraying alternating layers to the surface wherein at least one of said alternating layers contains amorphous metal including yttrium, chromium, molybdenum, tungsten, boron, and carbon, each being present at any concentration, ceramic particles having a size with the range of nanometers to microns, and amorphous metal particles.

14. A method of coating a surface, comprising the steps of:

providing a source of binding metal, wherein said source of binding metal is a source of amorphous binding metal including yttrium ≧1 atomic %, chromium 14 to 18 atomic %, molybdenum ≧7 atomic %, tungsten ≧1 atomic %, boron ≦5 atomic %, and carbon ≧4 atomic %;

providing a source of particles, wherein said source of particles is a source of ceramic particles; and

applying said binding metal and said particles to the surface by a spray process thereby coating the surface with alternating layers of a coating of a composite material made of amorphous metal and ceramic particles.

15. The method of coating a surface of claim 14 wherein said ceramic particles have a size within the range of nanometers to microns.

16. The method of coating a surface of claim 14 wherein said ceramic particles have a size within the range of 5 nanometers to 5 microns.

17. The method of coating a surface of claim 14 wherein said source of particles includes a source of amorphous metal particles and wherein said step of applying said binding metal and said particles to the surface by a spray process applies said amorphous binding metal, said ceramic particles, and said amorphous metal particles to the surface thereby coating the surface with a coating of a composite material made of amorphous metal, ceramic particles, and amorphous metal particles.

18. The method of coating a surface of claim 14 wherein said source of binding metal is a source of amorphous binding metal including yttrium, chromium, molybdenum, tungsten, boron, and carbon.

19. The method of coating a surface of claim 14 wherein said spray process is a cold spray process.

20. The method of coating a surface of claim 14 wherein said spray process is a thermal spray process.

21. The method of coating a surface of claim 14 wherein said spray process is a flame spray process.

22. The method of coating a surface of claim 21 wherein said spray process is a high-velocity spray process.

Assignments (10)
CHANGE OF NAME Recorded Sep 26, 2018
From: SANDIA CORPORATION
To: NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA, LLC
Reel/Frame 047639/0437 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 27, 2014
From: YANG, NANCY
To: SANDIA CORPORATION
Reel/Frame 032969/0346 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2014
From: PEREPEZKO, JOHN
To: WISCONSIN ALUMNI RESEARCH FOUNDATION
Reel/Frame 032831/0316 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 28, 2014
From: GRAEVE, OLIVIA
To: BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION, ON BEHALF OF THE UNIVERSITY OF NEVADA, RENO
Reel/Frame 032771/0854 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 18, 2014
From: BAYLES, ROBERT
To: THE GOVERNMENT OF THE UNITED STATES OF AMERICA, AS REPRESENTED BY THE SECRETARY OF THE NAVY
Reel/Frame 032707/0065 →
50% UNDIVIDED INTEREST Recorded Nov 27, 2013
From: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 031736/0503 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 23, 2010
From: BLUE, CRAIG A.
To: UT-BATTELLE, LLC
Reel/Frame 025051/0894 →
CONFIRMATORY LICENSE Recorded Jun 10, 2008
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: ENERGY, U.S. DEPARTMENT OF
Reel/Frame 021071/0501 →
50% UNDIVIDED INTEREST Recorded Oct 4, 2007
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 020012/0178 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 13, 2006
From: FARMER, JOSEPH C.; WONG, FRANK M.G.; HASLAM, JEFFERY; LAVERNIA, ENRIQUE J.; SCHOENUNG, JULIE; AJDELSZTAJN, LEO
To: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
Reel/Frame 018630/0963 →