Process for the production of moldings
View Patent ↗The present invention relates to a polymer powder which comprises nylon-11, and to the use of this powder for shaping processes, and also to moldings produced from this polymer powder. The shaping processes are layer-by-layer processes which use powders, where regions of the respective layer are selectively melted via introduction of electromagnetic energy. The selectivity may—with no intention of restricting the invention thereto—be achieved via masks, application of inhibitors, of absorbers, or of susceptors, or via focusing of the energy introduced. After cooling, the regions then solidified can be removed in the form of moldings from the powder bed. Compared with moldings composed of conventional powders, the moldings constructed using the inventive powder by one of the inventive processes exhibit marked advantages in terms of component properties, particularly surface finish. There are also improvements here in processing and in recycling capability when comparison is made with conventional polyamide powders.
1. A process for the production of moldings via a layer-by-layer process comprising selectively melting regions of a pulverulent layer of a polymer powder via introduction of electromagnetic energy, wherein the selectivity is obtained via the application of susceptors, inhibitors, or absorbers, or via masks, and wherein the polymer powder comprises at least one nylon-11 having an enthalpy of fusion of at least 125 J/g and having a recrystallization temperature of at least 148° C.
wherein a BET surface area of the powder is less than 6 m 2 /g and a median particle diameter of the powder is from 40 to 120 μm.
2. A process for the production of moldings via a layer-by-layer process comprising selectively melting regions of a pulverulent layer of a polymer powder via introduction of electromagnetic energy, wherein the selectivity is achieved via the focusing of a laser beam, and the polymer powder comprises at least one nylon-11 having an enthalpy of fusion of at least 125 J/g and having a recrystallization temperature of at least 148° C.
wherein a BET surface area of the powder is less than 6 m 2 /g and a median particle diameter of the powder is from 40 to 120 μm.
3. A process for the production of moldings comprising selectively laser sintering a polymer powder comprising at least one nylon-11 having an enthalpy of fusion of at least 125 J/g and having a recrystallization temperature of at least 148° C.
wherein a BET surface area of the powder is less than 6 m 2 /g and a median particle diameter of the powder is from 40 to 120 μm.
4. The process according to claim 1 , wherein the at least one nylon-11 has a melting point of at least 191° C.
5. The process according to claim 2 , wherein the at least one nylon-11 has a melting point of at least 191° C.
6. The process according to claim 3 , wherein the at least one nylon-11 has a melting point of at least 191° C.
7. The process according to claim 1 , wherein the at least one nylon-11 has an enthalpy of fusion of at least 130 J/g and a recrystallization temperature of at least 150° C.
8. The process according to claim 2 , wherein the at least one nylon-11 has an enthalpy of fusion of at least 130 J/g and a recrystallization temperature of at least 150° C.
9. The process according to claim 3 , wherein the at least one nylon-11 has an enthalpy of fusion of at least 130 J/g and a recrystallization temperature of at least 150° C.