Coaxial Cable With Foamed Insulation
The present invention is directed to a coaxial cable comprising (a) an inner conductor, (b) an outer conductor, and (c) a foamed insulation, surrounding the inner conductor. The foamed insulation is prepared from an insulation composition comprising a foamable polymer, a foaming agent, and a particulate, non-halogenated, nonheterocyclic polyolefinic nucleating agent. The invention is also related to methods and compositions for making the foamed insulation.
1 . A coaxial cable comprising:
(a) an inner conductor,
(b) an outer conductor, and
(c) a foamed insulation, surrounding the inner conductor, prepared from an insulation composition comprising
(i) a foamable polymer,
(ii) a foaming agent, and
(iii) a particulate, non-halogenated, non-heterocyclic polyolefinic nucleating agent having a particle size and a surface tension which are effective for foaming the foamable polyolefin polymer at an expansion rate of at least about 70 percent.
2 . The coaxial cable of claim 1 , wherein the nucleating agent is effective for providing an expansion rate of greater than about 80 percent.
3 . The coaxial cable of claim 1 , wherein the nucleating agent has an average particle size in the range from 0.1 μm to 100 μm.
4 . The coaxial cable of claim 1 , wherein the nucleating agent has a surface tension of less than about 30 dynes/cm.
5 . The coaxial cable of claim 1 , wherein the nucleating agent being added in an amount from 0.01 to 1.0 weight percent based on the weight of the insulation composition.
6 . The coaxial cable of claim 1 , wherein the nucleating agent has a melting point in the range between 130 degrees Celsius to 240 degrees Celsius.
7 . The coaxial cable of claim 1 , wherein the nucleating agent has a melting point at least 15 degrees Celsius higher than the melting point of the foamable polymer.
8 . The coaxial cable of claim 1 , wherein the nucleating agent is selected from the group consisting of poly 4-methylpentene-1, poly 4-methylhexene-1, poly 5-methylhexene-1, poly 4-methylheptene-1, poly 5-methylheptene-1, poly 6-methylheptene-1, and mixtures thereof.
9 . An insulation composition comprising:
(a) a foamable polymer,
(b) a foaming agent, and
(c) a particulate, non-halogenated, non-heterocyclic polyolefinic nucleating agent having a particle size and a surface tension which are effective for foaming the foamable polyolefin polymer at an expansion rate of at least about 70 percent.
10 . The insulation composition of claim 9 , wherein the nucleating agent is effective for providing an expansion rate of greater than about 80 percent.
11 . The insulation composition of claim 9 , wherein the nucleating agent has an average particle size in the range from 0.1 μm to 100 μm.
12 . The insulation composition of claim 9 , wherein the nucleating agent has a surface tension of less than about 30 dynes/cm.
13 . The insulation composition of claim 9 , the nucleating agent being added in an amount from 0.01 to 1.0 weight percent based on the weight of the insulation composition.
14 . The insulation composition of claim 9 , wherein the nucleating agent has a melting point in the range between 130 degrees Celsius to 240 degrees Celsius.
15 . The insulation composition of claim 9 , wherein the nucleating agent has a melting point at least 15 degrees Celsius higher than the melting point of the foamable polymer.
16 . The insulation composition of claim 9 , wherein the nucleating agent is selected from the group consisting of poly 4-methylpentene-1, poly 4-methylhexene-1, poly 5-methylhexene-1, poly 4-methylheptene-1, poly 5-methylheptene-1, poly 6-methylheptene-1, and mixtures thereof.