Method for producing non-aqueous electrolyte secondary battery
View Patent ↗A non-aqueous electrolyte secondary battery having both high capacity and long-life is provided by solving the problem of the large irreversible capacity of a negative electrode active material. The non-aqueous electrolyte secondary battery is produced by a method including the steps of: reacting lithium with a negative electrode active material by bringing a metal film that is composed mainly of lithium into contact with a surface of a negative electrode active material layer; and thereafter combining the negative electrode with a positive electrode to form an electrode assembly. The metal film composed mainly of lithium is preferably formed on a carrier that does not chemically react with lithium, and the metal film on the carrier is preferably brought into contact with the negative electrode active material layer while heating and applying a pressure thereto.
1. A method for producing a non-aqueous electrolyte secondary battery that comprises:
a positive electrode capable of electrochemically absorbing and desorbing lithium;
a negative electrode capable of electrochemically absorbing and desorbing lithium, said negative electrode including an active material layer that comprises an active material represented by SiO x (0<x≦1.0), said active material layer being carried on a current collector; and
a non-aqueous electrolyte,
said method comprising the steps of
depositing the active material by sputtering, vacuum evaporation, thermal spraying, or CVD on the current collector to form the active material layer;
reacting lithium with the active material of the negative electrode by bringing a metal film that is composed mainly of lithium into contact with a surface of said active material layer of the negative electrode to form a precursor and heating the precursor in an air atmosphere with a dew point of −40° C. or less or a dehydrated inert gas atmosphere at 130° C. or more and 170° C. or less; and
thereafter combining the negative electrode with the positive electrode to form an electrode assembly.
2. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 1 , wherein said heating is conducted while applying a pressure to the precursor.
3. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 1 , wherein said air atmosphere or said dehydrated inert gas atmosphere is an atmosphere with a reduced pressure of 50 Pa or less.
4. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 1 , wherein said metal film composed mainly of lithium is formed on a carrier that does not chemically react with lithium, and said step of reacting lithium with the active material of the negative electrode comprises bringing said metal film on said carrier into contact with said active material layer of the negative electrode to form the precursor and heating the precursor while and applying a pressure thereto.
5. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 4 , wherein said metal film is formed on said carrier by vacuum evaporation.
6. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 4 , wherein said carrier comprises a metal foil composed mainly of a transition element.
7. The method for producing a non-aqueous electrolyte secondary battery in accordance with claim 4 , wherein said carrier comprises an organic polymer film.