Organic electroluminescent materials and organic electroluminescent device using the same
View Patent ↗An organic electroluminescent material having the formula and an organic electroluminescent material used for electroluminescent devices is characterized by emission with a high luminance, high illuminant efficiency, low drive voltage, favorable color purity and high thermal steadiness. The hydrogen atom, halogen atom, cyanide group, alkyl group, alkylidene group, cycloalkane group, alkoxy group, amino group, aromatic hydroxy group, alkylaryl group as a substitutive group are used. Not only may it increase the material's glass transition temperature and inhibit the phenomenon of molecular split but also cause this organic electroluminescent device to show a high level of steadiness.
1. An organic electroluminescent material, in which the structure is:
wherein, n=1-3; R 1 represents a hydrogen atom or a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group or a group which is optionally chosen from a combination thereof; R 2 represents a hydrogen atom, a halogen atom, a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group, an aromatic hydroxyl group, or a group is optionally chosen from a combination thereof; R 3 , R 4 , R 5 , R 6 and R 7 represent a hydrogen atom, a halogen atom, a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group, an aromatic hydroxy group, an alkylaryl group, or a group which is optionally chosen from a combination thereof; wherein M=one of either Os, Ir, Pt, Ru, Rh or Pd; wherein L 1 and L 2 are a monodentate ligand or a bidentate ligand; wherein x=value ranging from 0-2; and wherein y=value ranging from 0-1.
2. The organic electroluminescent material according to claim 1 , wherein the R 1 represents a hydrogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms or a group which is optionally chosen from a combination thereof.
3. The organic electroluminescent material according to claim 1 , wherein the R 2 represents a hydrogen atom, a halogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydroxy group having 6 to 30 carbon atoms, or the group which is optionally chosen from a combination thereof.
4. The organic electroluminescent material according to claim 1 , wherein the R 3 , R 4 , R 5 , R 6 and R 7 represents a hydrogen atom, a halogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydroxy group having 6 to 30 carbon atoms, or a group which is optionally chosen from a combination thereof.
5. The organic electroluminescent material according to claim 1 , wherein the alkyl group is C n F 2n+1 .
6. The organic electroluminescent material according to claim 1 , wherein the alkoxy group is OC n F 2n+1 .
7. The organic electroluminescent material according to claim 1 , wherein when n=2, x=y=1, L 1 and L 2 act as a monodentate ligand, M=Os, Ir, Ru, Rh; when n=2, x=2, y=0, L 1 acts as a monodentate ligand, M=Os, Ir, Ru, Rh; when n=2, x=1, y=0, L 1 acts as a bidentate ligand, M=Os, Ir, Ru, Rh; when n=2, x=y=0, M=Pt and Pd; when n=3, x=y=0, M=Os, Ir, Ru, Rh; when n=1, x=y=1, L 1 and L 2 each act as a monodentate ligand, M=Pt and Pd; when n=1, x=2, y=0, L 1 acts as a bidentate ligand, M=Pt and Pd; when n=1, x=1, y=0, L 1 acts as a bidentate ligand, M=Pt and Pd.
8. An electroluminescent device, comprises two electrodes and an organic electroluminescent layer which is located between the two opposing electrodes, the organic electroluminescent layer comprising a material having a structure as follows:
wherein, n=1-3; R 1 represents a hydrogen atom or a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group or a group which is optionally chosen from a combination thereof; R 2 represents a hydrogen atom, a halogen atom, a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group, an aromatic hydroxyl group, or a group which is optionally chosen from a combination thereof; R 3 , R 4 , R 5 , R 6 and R 7 represent a hydrogen atom, a halogen atom, a cyanide group, an alkyl group, an alkylidene group, a cycloalkane group, an alkoxy group, an amino group, an aromatic hydroxy group, an alkylaryl group, or a group which is optionally chosen from a combination thereof; wherein M=one of either Os, Ir, Pt, Ru, Rh or Pd; wherein L 1 and L 2 are a monodentate ligand or a bidentate ligand; wherein x=value ranging from 0-2; and wherein y=value ranging from 0-1.
9. The electroluminescent device according to claim 8 , wherein the R 1 represents a hydrogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms or a group which is optionally chosen from a combination thereof.
10. The electroluminescent device according to claim 8 , wherein the R 2 represents a hydrogen atom, a halogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydroxy group having 6 to 30 carbon atoms, or a group which is optionally chosen from a combination thereof.
11. The electroluminescent device according to claim 8 , wherein the R 3 , R 4 , R 5 , R 6 and R 7 represents a hydrogen atom, a halogen atom, a cyanide group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkylidene having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkane group having 1 to 10 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted amino group having 1 to 10 carbon atoms, a substituted or unsubstituted aromatic hydroxy group having 6 to 30 carbon atoms, or a group which is optionally chosen from a combination thereof.
12. The electroluminescent device according to claim 8 , wherein the alkyl group is C n F 2n+1 , the alkoxy group is OC n F 2n+1 .
13. The electroluminescent device according to claim 8 , wherein when n=2, x=y=1, L 1 and L 2 each act as a monodentate ligand, M=Os, Ir, Ru, or Rh; when n=2, x=2, y=0, L 1 acts as a monodentate ligand, M =Os, Ir, Ru, or Rh; when n=2, x=1, y=0, L 1 acts as a bidentate ligand, M=Os, Ir, Ru, or Rh; when n=2, x=y=0, M=Pt and Pd; when n=3, x=y=0, M=Os, Ir, Ru, or Rh; when n=1, x=y=1, L 1 and L 2 each act as a monodentate ligand, M=Pt and Pd; when n=1, x=2, y=0, L 1 acts as a monodentate ligand, M=Pt and Pd; when n=1, x=1, y=0, L 1 acts as a bidentate ligand, M=Pt and Pd.
14. The electroluminescent device according to claim 8 , wherein the organic electroluminescent layer includes an aromatic amine compound, an aromatic diamine compound or an aromatic triamine compound.
15. The electroluminescent device according to claim 14 , wherein the aromatic amine compound has an aromatic hydroxyl substitutive group.
16. The electroluminescent device according to claim 14 , wherein the aromatic diamine compound has an aromatic hydroxyl substitutive group.
17. The organic electroluminescent device according to claim 14 , wherein the aromatic triamine compound has an aromatic hydroxyl substitutive group.
18. The organic electroluminescent device according to claim 9 , wherein the organic electroluminescent material is a doped material of the organic electroluminescent layer, and a weight percentage is 0.1˜50% by weight for the doping density of the organic electroluminescent material.