IP Library Granted Patent US 8,772,359
Granted Patent B2
US 8,772,359 · App. 11/611,492 · Granted Jul 8, 2014

Surfactant thickened systems comprising microfibrous cellulose and methods of making same

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Quick Facts
Patent No.
US 8,772,359
App. No.
11/611,492
Granted
Jul 8, 2014
Kind
B2
Abstract

Surfactant systems are provided using microfibrous cellulose to suspend particulates. In one embodiment the surfactant system includes a microfibrous cellulose at a concentration from about 0.05% to about 1.0% (w/w), a surfactant at a concentration of about 51% to about 99% (w/w active surfactant), and a suspended particulate. Also provided herein are methods for preparing surfactant systems including microfibrous cellulose.

Claims (30)

1. An aqueous composition comprising a high surfactant system consisting essentially of water, a microfibrous cellulose present in the aqueous composition at a concentration from about 0.05% to about 0.155% (w/w), a surfactant present in the aqueous composition at a concentration from about 51% to about 99% (w/w active surfactant), and a suspended particulate, wherein the aqueous composition is clear.

2. The aqueous composition according to claim 1 , wherein the microfibrous cellulose is present in the aqueous composition at a concentration from about 0.06% to about 0.125%.

3. The aqueous composition according to claim 2 , wherein the surfactant is present in the aqueous composition at a concentration from about 80% (w/w active surfactant) to about 99%.

4. The aqueous composition according to claim 3 , wherein the suspended particulate comprises air bubbles.

5. The aqueous composition of claim 3 , wherein the pH is from about 3 to about 11.

6. The aqueous composition according to claim 1 , wherein the microfibrous cellulose is present in the aqueous composition at a concentration from about 0.075% to about 0.125%.

7. The aqueous composition according to claim 1 , wherein the microfibrous cellulose is present in the aqueous composition at a concentration of about 0.125%.

8. The aqueous composition of claim 1 , wherein the surfactant comprises a non-ionic surfactant, an anionic surfactant, or a combination thereof.

9. The aqueous composition of claim 1 , wherein the microfibrous cellulose comprises a blend of a microfibrous cellulose, xanthan gum, and carboxymethylcellulose in a ratio of 6:3:1.

10. The aqueous composition of claim 1 , wherein the microfibrous cellulose comprises a blend of a microfibrous cellulose, guar gum, and carboxymethylcellulose in a ratio of 3:1:1.

11. A surfactant system comprising a microfibrous cellulose, a surfactant, and a suspended particulate, wherein the microfibrous cellulose is present at a concentration of about 0.125% and the surfactant is present at a concentration of about 99% (w/w active surfactant).

12. The surfactant system of claim 11 , wherein the pH is from about 3 to about 11.

13. Method of preparing a surfactant system comprising:

combining a microfibrous cellulose with water and mixing with high shear,

adding a surfactant and then mixing, and

adding particulates followed by mixing,

wherein the microfibrous cellulose is present at a concentration from about 0.05% to about 0.15% (w/w), the surfactant is present at a concentration from about 51% to about 99% (w/w active surfactant), and the resulting system is clear and the particulates are suspended therein.

14. The method of claim 13 wherein the microfibrous cellulose is present at a concentration from about 0.06% to about 0.125%.

15. The method of claim 13 , wherein the microfibrous cellulose is present at a concentration from about 0.075% to about 0.125%.

16. The method of claim 13 , wherein the microfibrous cellulose is present at a concentration of about 0.125%.

17. The method of claim 13 , wherein the surfactant is present at a concentration from about 80% (w/w active surfactant) to about 99%.

18. The method of claim 13 , wherein the surfactant comprises a non-ionic surfactant, an anionic surfactant, or a combination thereof.

19. The method of claim 13 , wherein the microfibrous cellulose comprises a blend of a microfibrous cellulose, xanthan gum, and carboxymethylcellulose in a ratio of 6:3:1.

20. The method of claim 13 , wherein the microfibrous cellulose comprises a blend of a microfibrous cellulose, guar gum, and carboxymethylcellulose in a ratio of 3:1:1.

21. Method of preparing a surfactant system comprising a microfibrous cellulose, a surfactant, and particulates comprising:

combining a microfibrous cellulose with water and mixing,

adding a surfactant and then mixing, and

adding particulates followed by mixing,

wherein the microfibrous cellulose is present at a concentration of about 0.05% to about 1.0% (w/w) and the surfactant is present at a concentration of about 99% (w/w active surfactant); and

wherein the resulting system is clear and the particulates are suspended therein.

Assignments (3)
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jun 27, 2014
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: J.M. HUBER CORPORATION; CP KELCO U.S., INC.; HUBER ENGINEERED WOODS LLC
Reel/Frame 033247/0705 →
RELEASE OF SECURITY INTEREST Recorded Nov 1, 2011
From: BANK OF AMERICA, N.A.
To: J.M. HUBER CORPORATION; 333 ASSOCIATES LLC; 333 PARTNERS LLC; CELTEGAN LLC; CP KELCO U.S., INC.; HUBER CST COMPANY; HUBER CST CORPORATION; HUBER ENERGY L.P.; HUBER ENERGY LLC; HUBER ENGINEERED WOODS LLC; HUBER EQUITY CORPORATION; HUBER INTERNATIONAL CORP.; HUBER RESOURCES CORP.; HUBER SOUTH TEXAS GP, LLC; HUBER SOUTH TEXAS LP, LLC; HUBER TIMBER INVESTMENTS LLC; HUBER TIMBER LLC; J.M. HUBER MICROPOWDERS INC.; JMH PARTNERS CORP.; KELCO COMPANY; ST. PAMPHILE TIMBER LLC; TABSUM, INC.; TARA INSURANCE GLOBAL LIMITED; QUINCY WAREHOUSES, INC. (FORMERLY UNDERGROUND WAREHOUSES, INC.
Reel/Frame 027158/0142 →
SECURITY AGREEMENT Recorded Mar 29, 2011
From: J.M. HUBER CORPORATION; 333 ASSOCIATES LLC; 333 PARTNERS LLC; CELTEGAN LLC; CP KELCO U.S., INC.; HUBER CST COMPANY; HUBER CST CORPORATION; HUBER ENERGY L.P.; HUBER ENERGY LLC; HUBER ENGINEERED WOODS LLC; HUBER EQUITY CORPORATION; HUBER INTERNATIONAL CORP.; HUBER RESOURCES CORP.; HUBER SOUTH TEXAS GP, LLC; HUBER SOUTH TEXAS LP, LLC; HUBER TIMBER INVESTMENTS LLC; HUBER TIMBER LLC; J.M. HUBER MICROPOWDERS INC.; JMH PARTNERS CORP.; KELCO COMPANY; ST. PAMPHILE TIMBER LLC; TABSUM, INC.; TARA INSURANCE GLOBAL LIMITED; UNDERGROUND WAREHOUSES, INC.
To: BANK OF AMERICA, N.A.
Reel/Frame 026042/0063 →