Carpet fiber polymeric blend
View Patent ↗The invention provides carpet fibers prepared from a blend of polymeric components, said fiber exhibiting improved properties, such as improved spinnability and improved fire resistance. The carpet fibers particularly comprise a majority of polytrimethylene terephthalate (PTT) and a minority of polyethylene terephthalate (PET). The invention further provides yarns and carpets prepared from the inventive fibers, said yarns and carpets likewise exhibiting improved properties. The invention also provides methods of improving various physical properties (such as fire resistance, spinnability, and elongation) of a polymeric composition.
1. A carpet yarn comprised of bulk continuous filaments comprising a polymeric blend of polytrimethylene terephthalate polymer and about 1% by weight to about 15% by weight of a polyethylene terephthalate polymer, based on the overall weight of said carpet yarn, wherein the yarn exhibits an increase in elongation in comparison to a carpet yarn comprised of polytrimethylene terephthalate polymer having an identical composition with the exception that the comparison carpet yarn has no polyethylene terephthalate polymer, and wherein the polyethylene terephthalate polymer has an intrinsic viscosity of 0.80+/−0.02 dL/g.
2. The carpet yarn of claim 1 comprising about 3% by weight to about 15% by weight of said polyethylene terephthalate polymer, based on the overall weight of said yarn.
3. The carpet yarn of claim 1 comprising about 5% by weight to about 15% by weight of said polyethylene terephthalate polymer, based on the overall weight of said yarn.
4. The carpet yarn of claim 1 comprising about 10% by weight to about 15% by weight of said polyethylene terephthalate polymer, based on the overall weight of said yarn.
5. The carpet yarn of claim 1 , wherein said polyethylene terephthalate polymer is a copolymer comprising a content of 1,4-cyclohexane dimethanol comonomers.
6. A carpet comprising a carpet yarn according to claim 1 .
7. The carpet yam of claim 1 , wherein said yarn exhibits improved ignition characteristics according to ASTM D-2859 in relation to a like carpet yam consisting of a polytrimethylene terephthalate polymer without a polyethylene terephthalate polymer.
8. A method for increasing fire resistance of a carpet prepared using a polytrimethylene terephthalate yarn, said method comprising preparing the carpet using a yarn comprised of bulk continuous filaments comprising a melt blend of polytrimethylene terephthalate polymer and about 1% by weight to about 30% by weight of a polyethylene terephthalate copolymer including a content of 1,4-cyclohexane dimethanol comonomers, wherein said carpet exhibits increased fire resistance when tested according to ASTM D-2859 in relation to a like carpet prepared using a polytrimethylene terephthalate polymer without the polyethylene terephthalate copolymer, and wherein the yarn exhibits an increase in elongation in comparison to a carpet yarn comprised of polytrimethylene terephthalate polymer and having no polyethylene terephthalate polymer, and wherein the polyethylene terephthalate polymer has an intrinsic viscosity of 0.80+/−0.02 dL/g.
9. The carpet yarn of claim 8 comprising about 5% by weight to about 15% by weight of said polyethylene terephthalate copolymer, based on the overall weight of said yarn.
10. The carpet yarn of claim 8 comprising about 10% by weight to about 15% by weight of said polyethylene terephthalate copolymer, based on the overall weight of said yarn.
11. The carpet yarn of claim 8 , wherein said polyethylene terephthalate copolymer comprises up to about 30 mole % of 1,4-cyclohexane dimethanol comonomers.
12. The method of claim 8 , wherein said increased fire resistance comprises a pass rate of test ASTM D-2859 of greater than about 27%.
13. The method of claim 8 , wherein said increased fire resistance comprises a pass rate of test ASTM D-2859 of at least about 46%.
14. The carpet fiber of claim 1 , wherein the fibers have a tenacity of 2.08 grams/denier.
15. A carpet yarn comprised of bulk continuous filaments comprising a polymeric blend of polytrimethylene terephthalate polymer and about 1% by weight to about 15% by weight of a polyethylene terephthalate copolymer, based on the overall weight of said carpet yarn, wherein the yarn exhibits an increase in elongation in comparison to a carpet yarn comprised of polytrimethylene terephthalate polymer having an identical composition with the exception that the comparison carpet yarn has no polyethylene terephthalate polymer.
16. The carpet yarn of claim 15 , wherein the polyethylene terephthalate copolymer comprises ethylene terephthalate monomers and a 1,4-cyclohexane dimethanol (CHDM) comonomer.
17. The carpet yarn of claim 15 , wherein the polyethylene terephthalate copolymer comprises ethylene terephthalate monomers and comonomers comprised of diacids or diols.
18. The carpet yarn of claim 15 , wherein the polyethylene terephthalate copolymer comprises ethylene terephthalate monomers and comonomers selected from the group consisting of diethylene glycol, polyethylene glycol, butylene glycol, polystyrene, vinyltoluene, halostyrene, dihalostyrene, styrene-butadiene copolymers, styrene-acrylonitrile copolymers, styrene-acrylonitrile-butadiene terpolymers, styrene-butadiene-styrene terpolymers, styrene-isoprene copolymers, aromatic dicarboxylic acids, aliphatic dicarboxylic acids, glutaric acid, azelaic acid, sebacic acid and combinations thereof.
19. The carpet yarn of claim 15 , wherein the polyethylene terephthalate copolymer comprises recycled polyethylene terephthalate.
20. A carpet yarn comprised of bulk continuous filaments consisting of a polymeric blend of polytrimethylene terephthalate polymer and about 1% by weight to about 15% by weight of a polyethylene terephthalate copolymer, based on the overall weight of said carpet yarn, wherein said yarn exhibits improved ignition characteristics according to ASTM D-2859 in relation to a like carpet yarn consisting of a polytrimethylene terephthalate polymer without a polyethylene terephthalate copolymer.
21. The carpet yarn of claim 20 , wherein the polyethylene terephthalate copolymer comprises ethylene terephthalate monomers and a 1,4-cyclohexane dimethanol (CHDM) comonomer.
22. A carpet yarn comprised of bulk continuous filaments comprising a polymeric blend of polytrimethylene terephthalate polymer and about 1% by weight to about 15% by weight of a polyethylene terephthalate polymer, based on the overall weight of said carpet yarn, wherein the yarn exhibits an increase in elongation in comparison to a carpet yarn comprised of polytrimethylene terephthalate polymer having an identical composition with the exception that the comparison carpet yarn has no polyethylene terephthalate polymer.
23. The carpet yarn of claim 22 , comprising about 3% by weight to about 15% by weight of said polyethylene terephthalate polymer, based on the overall weight of said yarn.
24. The carpet yarn of claim 22 , wherein said yarn exhibits improved ignition characteristics according to ASTM D-2859 in relation to a like carpet yarn consisting of a polytrimethylene terephthalate polymer without a polyethylene terephthalate polymer.
25. The carpet yarn of claim 24 , wherein said improved ignition characteristics comprises a pass rate of test ASTM D-2859 of greater than about 27%.
26. The carpet yarn of claim 24 , wherein said improved ignition characteristics comprises a pass rate of test ASTM D-2859 of at least about 46%.