Compositions comprising ammonium nitrate double salts
View Patent ↗Preferred aspects of the present invention provide ammonium nitrate compositions comprising ammonium nitrate and at least a second compound, said second compound being present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition and/or to otherwise improve a desired property of the composition. In certain embodiments, the second compound is selected from the group consisting of ammonium sulfate, ammonium phosphate, calcium nitrate, potassium nitrate, magnesium nitrate, ammonium molybdenate, ammonium hexaflouralsilicate, neodymium hydroxynitrate, and combinations of two or more of these. In preferred embodiments, at least a substantial portion of the ammonium nitrate in the composition is in the form of a double salt with one or more of said second compounds. In highly preferred embodiments, the present compositions consist essentially of one or more double salts of ammonium nitrate and a second compound as described herein.
1. A fertilizer composition consisting essentially of one or more double salts of ammonium nitrate, the double salt of ammonium nitrate including ammonium nitrate and at least a second compound, said second compound being present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition relative to ammonium nitrate, said second compound being selected from the group consisting of ammonium phosphate, calcium nitrate, potassium nitrate, magnesium nitrate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof, the fertilizer composition having single salt ammonium nitrate in an amount from about 0 wt. % to about 1 wt. % of the total weight of the composition.
2. The fertilizer composition of claim 1 , wherein the second compound of the double salt is selected from the group consisting of ammonium phosphate, magnesium nitrate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof.
3. The fertilizer composition of claim 1 , wherein the second compound of the double salt is selected from the group consisting of ammonium phosphate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof.
4. A method for reducing the sensitivity to detonation of fertilizer compositions containing ammonium nitrate, the method comprising the step of:
providing a fertilizer composition consisting essentially of at least one double salt of ammonium nitrate, the double salt of ammonium nitrate including ammonium nitrate and at least a second compound selected from the group consisting of ammonium phosphate, potassium nitrate, magnesium nitrate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof, said second compound being present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition relative to ammonium nitrate, the fertilizer composition having single salt ammonium nitrate in an amount from about 0 wt. % to about 1 wt. % of the total weight of the composition.
5. The method of claim 4 , wherein the second compound of the double salt is selected from the group consisting of ammonium phosphate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof.
6. A method of handling fertilizer compositions, the method comprising the steps of:
providing a substantially non-detonatable fertilizer composition consisting essentially of one or more double salts of ammonium nitrate, the double salt of ammonium nitrate including ammonium nitrate and at least a second compound selected from the group consisting of ammonium phosphate, potassium nitrate, magnesium nitrate, ammonium molybdenate, ammonium hexafluorosilicate, neodymium hydroxynitrate, and combinations of two or more thereof, said second compound being present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition relative to ammonium nitrate, the fertilizer composition having single salt ammonium nitrate in an amount from about 0 wt. % to about 1 wt. % of the total weight of the composition; and
handling the fertilizer composition by transporting the fertilizer composition, storing the fertilizer composition or applying the fertilizer composition to a growing material.
7. The method of claim 6 , wherein the second compound of the double salt is selected from the group consisting of ammonium phosphate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof.
8. A fertilizer composition consisting essentially of one or more double salts of the formula (I):
(M). n (NH 4 NO 3 ). m (H 2 O) (I)
where
M is a cation-anion pair selected from the group consisting of ammonium phosphate, potassium nitrate, magnesium nitrate, ammonium molybdenate, and ammonium hexafluorosilicate, wherein M is present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition relative to ammonium nitrate,
n is from about 0.2 to about 3, and
m is from about 0 to about 10,
the fertilizer composition having single salt ammonium nitrate in an amount from about 0 wt. % to about 1 wt. % of the total weight of the composition.
9. The fertilizer composition of claim 8 , said one or more double salts having a reaction exotherm at about 600° K greater than about −0.5 kcal/gm.
10. The fertilizer composition of claim 9 , wherein said reaction exotherm at about 600° K is greater that about −0.2 kcal/gm.
11. The fertilizer composition of claim 8 , said one or more double salts having a cohesive stability temperature of at least about 500° K.
12. The fertilizer composition of claim 10 wherein said one or more double salts having a cohesion exotherm greater than about −0.25 kcal/gm.
13. The fertilizer composition of claim 10 wherein said one or more double salts having a cohesion exotherm greater that about −0.1 kcal/gm.
14. The fertilizer composition of claim 8 , wherein M is a cation-anion pair selected from the group consisting of: ammonium phosphate, ammonium molybdenate, and ammonium hexafluorosilicate.
15. A fertilizer composition consisting essentially of one or more double salts of ammonium nitrate, the double salt of ammonium nitrate including ammonium nitrate and at least a second compound, said second compound being present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition relative to 2:1 ammonium sulfate nitrate double salt, said second compound being selected from the group consisting of ammonium phosphate, potassium nitrate, magnesium nitrate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof, the fertilizer composition having single salt ammonium nitrate in an amount from about 0 wt. % to about 1 wt. % of the total weight of the composition.
16. The fertilizer composition of claim 15 wherein said fertilizer composition has an onset temperature greater than the value of an onset temperature exhibited by ammonium sulfate nitrate 2:1 double salt.
17. The fertilizer composition of claim 15 having an onset temperature of at least about 1° C. higher than the value of same exhibited by ammonium sulfate nitrate 2:1 double salt.
18. The fertilizer composition of claim 15 having a peak drop in heating rate greater than the value of same exhibited by ammonium sulfate nitrate 2:1 double salt.
19. The fertilizer composition of claim 15 having a peak drop in heating rate (PDHR) at least about 50% greater than the value of same exhibited by ammonium sulfate nitrate 2:1 double salt.
20. The fertilizer composition of claim 15 , wherein the second compound of the double salt is selected from the group consisting of ammonium phosphate, ammonium molybdenate, ammonium hexafluorosilicate, and combinations of two or more thereof.