IP Library Granted Patent US 7,704,333
Granted Patent B2
US 7,704,333 · App. 11/625,113 · Granted Apr 27, 2010

Al-Cu-Mg-Ag-Mn alloy for structural applications requiring high strength and high ductility

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Quick Facts
Patent No.
US 7,704,333
App. No.
11/625,113
Granted
Apr 27, 2010
Kind
B2
Abstract

An aluminum alloy having improved strength and ductility, comprising: Cu 3.5-5.8 wt. %, Mg 0.2-1.5 wt. % Mn 0.2-0.5 wt. % Ag 0.2-0.8 wt. % Ti 0.02-0.12 wt. % and optionally one or more selected from the group consisting of Cr 0.1-0.8 wt. %, Hf 0.1-1.0 wt. %, Sc 0.03-0.6 wt. %, and V 0.05-0.15 wt. %, balance aluminum and incidental elements and impurities, and wherein the alloy is substantially zirconium-free.

Claims (42)

1. An aluminum alloy wrought product having improved strength and ductility, consisting essentially of:

a) Cu 3.8-5.2 wt. %,

Mg 0.2-0.6 wt. %

Mn 0.2-0.5 wt. %

Ag 0.2-0.5 wt. %

Ti 0.02-0.12 wt. % and

optionally one or more selected from the group consisting of Cr 0.1-0.8 wt. %, Hf 0.1-1.0 wt. %, Sc 0.03-0.6 wt. %, and V 0.05-0.15 wt. %,

b) balance aluminum and normal and/or inevitable elements and impurities,

and wherein said alloy is substantially zirconium-free.

2. An aluminum alloy according to claim 1 , comprising Ti 0.05-0.12 wt. %.

3. An aluminum alloy according to claim 1 , comprising Sc 0.03-0.25 wt. %.

4. An aluminum alloy according to claim 1 , comprising Hf 0.1-1.0 wt. %.

5. An aluminum alloy according to claim 1 , comprising V 0.05-0.15 wt. %.

6. An aluminum alloy according to claim 1 , comprising Cr 0.1-0.8 wt. %.

7. An aluminum alloy wrought product having improved strength and ductility, consisting essentially of:

a) Cu 4.7-5.3 wt. %,

Mg 0.2-0.6 wt. %

Mn 0.2-0.5 wt. %

Ag 0.2-0.5 wt. %

Ti 0.05-0.12 wt. % and

optionally one or more selected from the group consisting of Cr 0.1-0.8 wt. %, Hf 0.1-1.0 wt. %, Sc 0.05-0.6 wt. %, and V 0.05-0.15 wt. %.

b) balance aluminum and normal and/or inevitable elements and impurities,

and wherein said alloy is substantially zirconium-free.

8. An aluminum alloy according to claim 1 , wherein Cu 4.70-5.20 wt. %.

9. An aluminum alloy according to claim 7 , wherein Cu 4.70-5.20 wt. %.

10. An aluminum alloy according to claim 1 , wherein Zr is less than 0.03 wt. %.

11. An aluminum alloy according to claim 7 , wherein Zr is less than 0.03 wt. %.

12. An aluminum alloy according to claim 1 , wherein Zr is less than 0.01 wt. %.

13. An aluminum alloy according to claim 10 , wherein Zr is less than 0.01 wt. %.

14. An aluminum alloy according to claim 1 , which has been solution heat treated, quenched, stress relieved and/or artificially aged.

15. An aluminum alloy of claim 8 that has been formed into a sheet product with a thickness comprised between about 5 and 25 mm having at least one mechanical property (L-direction) selected from the group consisting of

a) an elongation of at least about 13.5% and a UTS of at least about 69.5 ksi (479.2 MPa) and

b) an elongation of at least about 15.5% and a UTS of at least about 69 ksi (475.7 MPa).

16. A structural member suitable for use in aircraft construction comprising an aluminum alloy according to claim 1 .

17. A wrought product comprising an aluminum alloy according to claim 1 .

18. A method for producing an aircraft structural member comprising forming an alloy according to claim 1 into said structural member.

19. A sheet comprising an aluminum alloy that is substantially free of zirconium according to claim 1 , said sheet having a thickness ranging from about 2 mm to about 10 mm, and a fracture toughness K c , determined at room temperature from the R-curve measure on a 406 mm wide CCT panel in the L-T orientation, which equals or exceeds about 170 Mpa√m, and the fatigue crack propagation rate determined according to ASTM E 647 on a CCT-specimen having a width of 400 mm, at constant amplitude R=0.1 that is equal to or below about 3.0 10 −2 mm/cycle at ΔK=60 Mpa√m.

20. A sheet comprising an aluminum alloy that is substantially free of zirconium according to claim 1 , said sheet having a thickness ranging from about 5 mm to about 25 mm and an elongation of at least about 13.5% and a UTS of at least about 69.5 ksi (479.2 MPa), and/or an elongation of at least about 15.5% and a UTS of at least about 69 ksi (475.7 MPa).

21. A wrought product comprising a sheet according to claim 20 .

22. An aircraft structural member comprising a sheet according to claim 20 .

23. A wrought product comprising a sheet according to claim 19 .

24. An aircraft structural member comprising a sheet according to claim 19 .

Assignments (11)
RELEASE OF SECURITY INTEREST Recorded Feb 15, 2019
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
Reel/Frame 048343/0465 →
SECURITY INTEREST Recorded Jun 23, 2017
From: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 042797/0039 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL (RELEASES RF 029036/0595) Recorded Jun 22, 2017
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
Reel/Frame 042961/0677 →
CHANGE OF NAME Recorded Oct 21, 2016
From: CONSTELLIUM FRANCE
To: CONSTELLIUM ISSOIRE
Reel/Frame 040462/0591 →
SECURITY AGREEMENT Recorded Jun 9, 2016
From: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 038931/0600 →
RELEASE OF SECURITY INTEREST Recorded May 8, 2014
From: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
To: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
Reel/Frame 032848/0714 →
ASSIGNMENT AND ASSUMPTION OF PATENT SECURITY AGREEMENT RECORDED AT R/F 029036/0569 Recorded Apr 12, 2013
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS EXISTING ADMINISTRATIVE AGENT
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 030205/0902 →
PATENT SECURITY AGREEMENT (TERM LOAN) Recorded Sep 25, 2012
From: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 029036/0569 →
PATENT SECURITY AGREEMENT (ABL) Recorded Sep 25, 2012
From: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 029036/0595 →
CHANGE OF NAME Recorded Jan 5, 2012
From: ALCAN ROLLED PRODUCTS - RAVENSWOOD, LLC
To: CONSTELLIUM ROLLED PRODUCTS RAVENSWOOD, LLC
Reel/Frame 027489/0090 →
CHANGE OF NAME Recorded Jan 5, 2012
From: ALCAN RHENALU
To: CONSTELLIUM FRANCE
Reel/Frame 027489/0240 →