Granted Patent B2

US 7,838,602 · App. 11/627,828 · Granted Nov 23, 2010

Abstract

Claims (51)

1. A multilayer article comprising:

a substrate layer, and

a coating layer in contiguous superposed contact with the substrate layer, the coating layer comprising a thermostable, weatherable polymer consisting essentially of structural units derived from at least one 1,3-dihydroxybenzene moiety, at least one aromatic dicarboxylic acid moiety, at least one bisphenol moiety, and at least one soft-block moiety derived from a siloxane oligomer of repeating diorganosiloxane units of Formula (XVIII):

wherein each occurrence of R 3 is independently a C 1-12 hydrocarbyl, and

wherein the multilayer article comprise the substrate layer and the coating layer, or the substrate layer with coating layers on each side of the substrate layer.

2. The multilayer article of claim 1 , wherein the thermostable, weatherable polymer is at least one resorcinol ester polycarbonate polymer comprising:

an arylate-containing unit of the Formula IV, comprising arylate blocks substantially free of anhydride linkages, and carbonate blocks,

wherein R y is at least one of C 1-12 alkyl or halogen, n is 0-3, m is at least about 4, p is one or more, R x comprises a divalent organic radical derived from a bisphenol, and

the soft-block moiety comprising a residue derived from:

a.) a siloxane oligomer of Formula XII:

wherein q is 1-99, or

b.) a siloxane oligomer of Formula XVI:

wherein the moiety Ar is derived from a dihydroxy-substituted aromatic hydrocarbon and x has a value of about 10 to about 100, and

wherein the resorcinol arylate polycarbonate polymer comprises 0.1-25% by weight of the soft-block moiety.

3. The multilayer article of claim 2 wherein the resorcinol arylate polycarbonate polymer comprises 1-20 wt % of the soft block moiety.

4. The multilayer article of claim 2 wherein the siloxane oligomer of Formula XII or Formula XVI are substituted for a portion of a resorcinol in the resorcinol arylate polycarbonate polymer by reaction with aromatic dicarboxylic acid dichloride.

5. The multilayer article of claim 2 , wherein q has a value of 1-20.

6. The multilayer article of claim 2 , wherein q has a value of 10-20.

7. The multilayer article of claim 2 , wherein q has a value of 20-60.

8. The multilayer article of claim 2 , wherein the siloxane oligomer comprises α,ω(3-(4-hydroxy-3-methoxyphenyl)-propyl)-deca(dimethylsiloxane) (ED10E) or 1,3(bis-3-(4-hydroxy-3-methoxyphenyl)-propyl)-1,1,3,3,-tetramethyl disiloxane (EMME).

9. The multilayer article of claim 2 , wherein the bisphenol is of Formula VIII:

wherein R 3 —R 10 are independently a hydrogen atom, halogen atom, nitro group, cyano group, C 1 -C 30 alkyl group, C 4 -C 30 cycloalkyl group, or C 6 -C 30 aryl group, a C 1 -C 30 alkoxy, C 4 -C 30 cycloalkoxy or C 6 -C 30 aryloxy; W is a direct bond, or an oxygen atom, sulfur atom, C═O group, SO 2 group, C 1 -C 20 aliphatic radical, C 6 -C 20 aromatic radical, C 6 -C 20 cycloaliphatic radical, or the group,

wherein R 11 and R 12 are independently a hydrogen atom, C 1 -C 20 alkyl group, C 4 -C 20 cycloalkyl group, or C 4 -C 20 aryl group; or R 11 and R 12 together form a C 4 -C 20 cycloaliphatic ring which is optionally substituted by one or more C 1 -C 20 alkyl, C 6 -C 20 aryl, C 5 -C 21 arylalkyl, C 5 -C 20 cycloalkyl groups or a combination thereof.

10. The multilayer article of claim 2 wherein Ar comprises m-phenylene, p-phenylene, 4,4′-biphenylene, 4,4′-bi(3,5-dimethyl)-phenylene, 2,2-bis(4-phenylene)propane, or 6,6′-(3,3,3′,3′-tetramethyl-1,1′-spirobi[1H-indan]).

11. The multilayer article of claim 2 , wherein the dihydroxy-substituted aromatic hydrocarbon from which Ar is derived is bisphenol A.

12. The multilayer article of claim 2 wherein the arylate blocks have a degree of polymerization (DP), represented by m, of at least about 8, wherein the DP of the carbonate blocks, represented by p, is at least about 10, and wherein the content of arylate blocks is about 10-95% by weight based on the total weight of arylate blocks and carbonate blocks in the resorcinol arylate polycarbonate polymer.

13. The multilayer article of claim 1 , wherein the thermostable, weatherable polymer further comprises a blend with at least one other additional polymer comprising a polycarbonate homopolymer, a copolycarbonate, a polyarylate, a copolyarylate, polyarylate-polycarbonate, a polysiloxane-polycarbonate, a polysiloxane-polyarylate, a polysiloxane-polyarylate-polycarbonate, a polyester, a copolyestercarbonate, a polyetherimide, a polyphenylene ether, an addition polymer, or a combination comprising at least one of the foregoing additional polymers.

14. The multilayer article of claim 1 , wherein the thermostable, weatherable polymer further comprises an additive comprising an impact modifier, a filler, a reinforcing agent, a thermal stabilizer, an antioxidant, a light stabilizer, a stabilizer additive, a plasticizer, a colorant, an antistatic agent, a lubricant, a mold release agent, an anti-drip agent, or a combination comprising one or more of the foregoing additives.

15. The multilayer article of claim 14 , wherein the stabilizer additive comprises at least one auxiliary color stabilizer additive, at least one auxiliary light stabilizer additive, at least one auxiliary UV absorber as stabilizer additive, or a combination thereof.

16. The multilayer article of claim 1 , wherein the substrate layer comprises at least one of a thermoplastic polymer, a thermoset polymer, a cellulosic material, glass, ceramic, or metal.

17. The multilayer article of claim 16 , wherein in the substrate layer the thermoplastic polymer comprises polycarbonates including aromatic polycarbonates, polyacetals, polyarylene ethers, polyphenylene ethers, polyarylene sulfides, polyphenylene sulfides, polyimides, polyamideimides, polyetherimides, polyetherketones, polyaryletherketones, polyetheretherketones, polyetherketoneketones, polyamides, polyesters, liquid crystalline polyesters, polyetheresters, polyetheramides, polyesteramides, or polyestercarbonates; or blends comprising PC/ABS, PC/ASA, PC/PBT, PC/PET, PC/polyetherimide, PC/polysulfone, polyester/polyetherimide, PMMA/acrylic rubber, polyphenylene ether-polystyrene, polyphenylene ether-polyamide or polyphenylene ether-polyester, where the thermoplastic polymer is other than that employed for the coating layer.

18. The multilayer article of claim 1 wherein the substrate layer additionally contains additives including colorants, pigments, dyes, impact modifiers, stabilizers, color stabilizers, heat stabilizers, UV screeners, UV absorbers, flame retardants, fillers, flow aids, ester interchange inhibitors, and mold release agents.

19. The multilayer article of claim 1 , wherein the multilayer article further comprises an interlayer between the substrate layer and the coating layer, wherein the interlayer is transparent, translucent, or opaque, and where the interlayer optionally contains an additive comprising a colorant, metal flake, or combination thereof.

20. The multilayer article of claim 18 , wherein the interlayer is an adhesive interlayer.

21. The multilayer article of claim 1 , further comprising an overlayer included over the coating layer, wherein the overlayer provides abrasion or scratch resistance, and wherein the substrate layer, coating layer, and any interlayers or overcoating layers are in contiguous superposed contact with one another.

22. The multilayer article of claim 1 wherein the multilayer article has one or both of lower initial color or additional resistance to weathering, as measured by initial yellowness index (YI), or by resistance to yellowing and change in color, when compared to a similar coating without at least one stabilizer additive.

23. The multilayer article of claim 2 , wherein the resorcinol arylate polycarbonate copolymer consists of the siloxane block of Formula XII or Formula XVI, and the arylate block unit of Formula IV.

24. A multilayer article comprising:

a substrate layer, and

a coating layer in contiguous superposed contact with the substrate layer, the coating layer comprising at least one resorcinol ester polycarbonate polymer consisting essentially of

an arylate-containing unit of the Formula IV, comprising arylate blocks substantially free of anhydride linkages, and carbonate blocks,

wherein R y is at least one of C 1-12 alkyl or halogen, n is 0-3, m is at least about 4, p is one or more, R x comprises a divalent organic radical derived from a bisphenol, and

the soft-block moiety comprising a residue derived from:

a.) a siloxane oligomer of Formula XII:

wherein q is 1-99, or

b.) a siloxane oligomer of Formula XVI:

wherein the moiety Ar is derived from a dihydroxy-substituted aromatic hydrocarbon and x has a value of about 10 to about 100, and

wherein the resorcinol arylate polycarbonate polymer comprises 0.1-25% by weight of the soft-block moiety, and

wherein the multilayer article comprises the substrate layer and the coating layer, or the substrate layer with coating layers on each side of the substrate layer.

25. The multilayer article of claim 24 , where the coating layer is applied to the substrate layer by solvent-casting, by fabrication of a separate sheet of the coating layer followed by application to the substrate layer, or by simultaneous production of both layers in a melt process.

26. The multilayer article of claim 25 , comprising thermoforming, compression molding, co-injection molding, coextrusion, overmolding, blow molding, multi-shot injection molding, or placement of a film of the coating layer material on the surface of the substrate layer followed by adhesion of the two layers.

Assignments (6)