Nano-composite IR window and method for making same
View Patent ↗A transparent, nano-composite material and methods for making structures from this material are provided. In one embodiment, the material is made from a polycrystalline matrix containing dispersed particles of a harder material. The particles are less then about 100 nm. In other embodiments, methods for making structures from the material are provided. In one aspect, the methods include blending precursor powders for the matrix and reinforcing phases prior to forming and sintering to make a final structure. In other aspects, a precursor powder for the matrix is pressed into a green shape, which is partially sintered and exposed to a solution containing a precursor for the reinforcing phase, prior to be sintered into the final material. In another aspect, the precursor powder for the matrix is coated with a sol-gel precursor for the reinforcing material, then pressed into a green shape and sintered to form the final structure.
1. A structure, comprising:
a nano-composite material capable of transmitting infrared light, the nano-composite comprising:
a sintered matrix material comprising polycrystalline grains; and
particles of a nano-dispersoid disposed within the grains, between the grains, or a combination thereof, wherein the largest dimension of the particles of the nano-dispersoid is about 100 nm across the direction of light transmission; and
wherein the structure is substantially transparent to infrared light and is substantially non-porous.
2. The structure of claim 1 , wherein the particles of the nano-dispersoid are generally spherical, ellipsoidal, cylindrical, or a combination thereof.
3. The structure of claim 1 , wherein the largest dimension of the particles of the nano-dispersoid is about 60 nm across the direction of light transmission.
4. The structure of claim 1 , wherein the sintered matrix material is selected from the group consisting of MgAl 2 O 4 , Y 3 Al 5 Ol 2 , cubic-ZrO 2 , Y 2 O 3 , MgO, and combinations thereof.
5. The structure of claim 1 , wherein the particles of the nano-dispersoid are selected from the group consisting of cubic-BN, SiC, Si 3 N 4 , and combinations thereof.
6. The structure of claim 1 , wherein the structure is a nose cone.
7. The structure of claim 1 , wherein the structure is a window.
8. The structure of claim 1 , wherein the structure is a lens.
9. The structure of claim 1 , wherein the sintered matrix material comprises an optically isotropic structure.
10. The structure of claim 1 , wherein the sintered matrix material comprises a cubic structure.
11. A nano-composite material capable of transmitting infrared light, comprising:
a sintered matrix material comprising polycrystalline grains; and
particles of a nano-dispersoid disposed within the grains, between the grains, or a combination thereof, wherein the largest dimension of the particles of the nano-dispersoid is about 100 nm across the direction of light transmission; and
wherein the nano-composite material is substantially transparent to infrared light and is substantially non-porous.
12. The nano-composite material of claim 11 , wherein the particles of the nano-dispersoid are generally spherical, ellipsoidal, cylindrical, or a combination thereof.
13. The nano-composite material of claim 11 , wherein the largest dimension of the particles of the nano-dispersoid is about 60 nm across the direction of light transmission.
14. The nano-composite material of claim 11 , wherein the sintered matrix material is selected from the group consisting of MgAl 2 O 4 , Y 3 Al 5 O 12 , cubic-ZrO 2 , Y 2 O 3 , MgO, and combinations thereof.
15. The nano-composite material of claim 11 , wherein the particles of the nano-dispersoid are selected from the group consisting of cubic-BN, SiC, Si 3 N 4 , and combinations thereof.
16. The nano-composite material of claim 11 , wherein the sintered matrix material comprises an optically isotropic structure.
17. The nano-composite material of claim 11 , wherein the sintered matrix material comprises a cubic structure.
18. The nano-composite material of claim 11 , wherein the nano-composite material is substantially free of light scattering.